Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 9 of 9

Full-Text Articles in Physical Sciences and Mathematics

Synthesis And Optimization Of Fluorine-Free Y And Cu Precursor Solution For Mod Processing Of Ybco Coated Conductor, Jaimoo Yoo, Young-Kuk Kim, Kookchae Chung, Jaewoong Ko, Xiaolin Wang, S X. Dou Jun 2013

Synthesis And Optimization Of Fluorine-Free Y And Cu Precursor Solution For Mod Processing Of Ybco Coated Conductor, Jaimoo Yoo, Young-Kuk Kim, Kookchae Chung, Jaewoong Ko, Xiaolin Wang, S X. Dou

Shi Xue Dou

MOD solutions for YBCO coated conductors were synthesized with fluorine-free Y & Cu precursor. The fluorine content in the precursor solution was significantly reduced and a fast calcination profile was realized. A crack-free & thick precursor film was successfully obtained just after less than 2 hours of calcination in wet O2 atmosphere. Optimization of the precursor solution with Sm addition enables further improvement of thickness and uniformity of precursor films. The calcinated precursor film was successfully converted to dense and uniform YBCO film after annealing in wet Ar/O2 atmosphere. The measured critical current value was about 273 A/cm-w (Jc ~ …


A Study On The Charge-Discharge Mechanism Of Co3o4 As An Anode For The Li Ion Secondary Battery, Yong-Mook Kang, Min-Sang Song, Jin-Ho Kim, Hyun-Seok Kim, Min-Sik Park, Jai-Young Lee, Hua-Kun Liu, S X. Dou Jun 2013

A Study On The Charge-Discharge Mechanism Of Co3o4 As An Anode For The Li Ion Secondary Battery, Yong-Mook Kang, Min-Sang Song, Jin-Ho Kim, Hyun-Seok Kim, Min-Sik Park, Jai-Young Lee, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Co3O4 has shown acceptable electrochemical properties as the anode material of Li secondary batteries. In detail, its capacity reached about 700 mAh/g, twice as high as graphite, and 93.4% of initial capacity was retained after 100 cycles. EIS (electrochemical impedance spectroscopy) analyses revealed that after the 1st cycle, the insertion or extraction of Li ions in Co3O4 can occur homogeneously and reversibly (randless-like behavior, homogeneous mixture: Co + Li2O (in the state of Li insertion), Co3O4 (in the state of Li extraction)). In fact, the coulombic efficiency of Co3O4 was almost 100% except for the 1st cycle. According to P. …


Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou Jun 2013

Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou

Shi Xue Dou

In this work, the authors report on significant flux pinning enhancement in MgB2 that has been easily obtained using a liquid additive, silicon oil. MgB2 bulk samples with 0 up to 30 wt % silicon oil added were prepared by an in situ reaction. Results showed that the Si and C released from the decomposition of the silicon oil formed Mg2Si and substituted into B sites, respectively. Increasing the amount of the Si oil up to 15 wt % has resulted in the reduction of the lattice parameters, as well as Tc and R(300 K)/R(Tc) values, accompanied by a significant …


Flux-Pinning Mechanism In Silicone-Oil Doped Mgb2: Evidence For Charge-Carrier Mean Free Path Fluctuation Pinning, Shaban R. Ghorbani, Xiaolin Wang, S X. Dou, Sung-Ik Lee, Md S. Hossain Jun 2013

Flux-Pinning Mechanism In Silicone-Oil Doped Mgb2: Evidence For Charge-Carrier Mean Free Path Fluctuation Pinning, Shaban R. Ghorbani, Xiaolin Wang, S X. Dou, Sung-Ik Lee, Md S. Hossain

Shi Xue Dou

Flux-pinning mechanism of MgB2 doped with 10 wt % silicone-oil sintered at low and high temperatures has been investigated by magnetic measurements. The field dependence of the critical current density, jc(B), was analysed within the collective pinning model. A crossover field, Bsb, from the single vortex to the small vortex bundle-pinning regime was observed. For both types of sintered samples, the temperature dependence of Bsb(T) at low temperature is in good agreement with the δl pinning mechanism, i.e., pinning associated with charge-carrier mean free path fluctuation. At temperatures close to the critical temperature, however, there is evidence for δTc pinning, …


Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu Feb 2013

Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu

Shulei Chou

Flexible, free-standing, paper-like, graphene-silicon composite materials have been synthesized by a simple, one-step, in-situ filtration method. The Si nanoparticles are highly encapsulated in a graphene nanosheet matrix. The electrochemical results show that graphene-Si composite film has much higher discharge capacity beyond 100 cycles (708 mAh g− 1) than that of the cell with pure graphene (304 mAh g− 1). The graphene functions as a flexible mechanical support for strain release, offering an efficient electrically conducting channel, while the nanosized silicon provides the high capacity.


Nanocrystalline Nio Hollow Spheres In Conjunction With Cmc For Lithium-Ion Batteries, Chao Zhong, Jiazhao Wang, Shulei Chou, Konstantin Konstantinov, Mokhlesur Rahman, Hua Liu Feb 2013

Nanocrystalline Nio Hollow Spheres In Conjunction With Cmc For Lithium-Ion Batteries, Chao Zhong, Jiazhao Wang, Shulei Chou, Konstantin Konstantinov, Mokhlesur Rahman, Hua Liu

Shulei Chou

Hollow spherical NiO particles were prepared using the spray pyrolysis method with different concentrations of precursor. The electrochemical properties of the NiO electrodes, which contained a new type of binder, carboxymethyl cellulose (CMC), were examined for comparison with NiO electrodes with polyvinylidene fluoride (PVDF) binder. The electrochemical performance of NiO electrodes using CMC binder was significantly improved. For the cell made from 0.3 mol L−1 precursor, the irreversible capacity loss between the first discharge and charge is about 43 and 24% for the electrode with PVDF and CMC binder, respectively. The cell with NiO–CMC electrode has a much higher discharge …


Contextual Effects In Modeling For Small Domain Estimation, Mohammad-Reza Namazi-Rad, David G. Steel Dec 2012

Contextual Effects In Modeling For Small Domain Estimation, Mohammad-Reza Namazi-Rad, David G. Steel

Professor David Steel

Many different Small Area Estimation (SAE) methods have been proposed to overcome the challenge of findingreliable estimates for small domains. Often, the required data for various research purposes are available at differentlevels of aggregation. Based on the available data, individual-level or aggregated-level models are used in SAE.However, parameter estimates obtained from individual and aggregated level analysis may be different, in practice.This may happen due to some substantial contextual or area-level effects in the covariates which may be misspecifiedin individual-level analysis. If small area models are going to be interpretable in practice, possible contextualeffects should be included. Ignoring these effects leads …


Coupling Biophysical And Socioeconomic Models For Coral Reef Systems In Quintana Roo, Mexican Caribbean, Deborah Cleland, Jess Melbourne-Thomas, Craig Johnson, Pascal Perez, Jeremy Eustache, Elizabeth Fulton Nov 2012

Coupling Biophysical And Socioeconomic Models For Coral Reef Systems In Quintana Roo, Mexican Caribbean, Deborah Cleland, Jess Melbourne-Thomas, Craig Johnson, Pascal Perez, Jeremy Eustache, Elizabeth Fulton

Professor Pascal Perez

No abstract provided.


Electrochemical Deposition Of Porous Vox And Mno2 Nanowires On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua Liu, S Dou Nov 2012

Electrochemical Deposition Of Porous Vox And Mno2 Nanowires On Stainless Steel Mesh For Flexible Supercapacitors, Shulei Chou, Jiazhao Wang, Hua Liu, S Dou

Shulei Chou

Porous vanadium oxide (VOx) and MnO2 nanowires were synthesized by an electrochemical deposition method using stainless steel mesh as substrate. The as-prepared porous VOx and MnO2 nanowire films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy. The cyclic voltammetry (CV) results show that the MnO2 nanowire film shows specific capacitance of 195, 170, 158, and 91 F g-1 at scan rates of 5, 10, 20, and 50 mV s-1, respectively. The porous VOx film displays specific capacitance of 152, 124, 99, and 76 F g …