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Advanced Chemical Oxidation Of 2,4,6-Trichlorophenol By Using Fenton's Reagent - Dechlorination And Toxicity Reduction, Kuang-Wei (Stone) Chen, Irvine W. Wei
Advanced Chemical Oxidation Of 2,4,6-Trichlorophenol By Using Fenton's Reagent - Dechlorination And Toxicity Reduction, Kuang-Wei (Stone) Chen, Irvine W. Wei
Irvine W. Wei
Chlorinated phenols are priority pollutants, regulated by stringent discharge limits. The presence of chlorine increases the toxicity of these phenolic compounds and decreases their biodegradability. This study is to examine the removal of a priority chlorinated aromatic pollutant, 2,4,6-trichlorophenol (TCP), in aqueous solution by using Fenton's Reagent (a mixture of hydrogen peroxide and fenous iron catalyst), in terms of dechlorination and toxicity reduction. Test results indicate that the higher the molar ratio of H₂O₂ to TCP, the faster the release of chloride from TCP. However, the chloride released in all runs eventually approach the same level of theoretical chloride concentration, …
Comparative Displacement Study Of Bilayer Actuators Comprising Of Conducting Polymers, Fabricated From Polypyrrole, Poly(3,4- Ethylenedioxythiophene) Or Poly(3,4-Propylenedioxythiophene), Babita Gaihre, Syed Ashraf, Geoffrey M. Spinks, Peter C. Innis, Gordon G. Wallace
Comparative Displacement Study Of Bilayer Actuators Comprising Of Conducting Polymers, Fabricated From Polypyrrole, Poly(3,4- Ethylenedioxythiophene) Or Poly(3,4-Propylenedioxythiophene), Babita Gaihre, Syed Ashraf, Geoffrey M. Spinks, Peter C. Innis, Gordon G. Wallace
Gordon Wallace
The stress gradient generated due to electrochemical oxidation/reduction of a conducting polymer in a bilayer actuator causes a bending movement. Here we report a comparative study of the displacement of bilayer actuators prepared using different conducting polymers. The effects of conducting polymers obtained from electrochemical or chemical synthesis route: different polymers (polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) PEDOT and poly(3,3-dihexyl-3-4-dihydro-2H-thieno[3,4b][1,4]-dioxepine [PProDOT(Hx) 2]); and different electrolytes (0.1 M lithium trifluromethanesulfonate/propylenecarbonate (LiTFSI/PC) and 1-ethyl-3-methyl imidazolium trifluromethanesulfonate (EMITFSI)) on the displacement amplitude and displacement patterns of these actuators were investigated and compared. The results indicate that the bilayer actuator consisting of an electrochemically synthesized conducting polymer …