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Full-Text Articles in Physical Sciences and Mathematics

Microwave-Assisted Synthesis Of Zno Micro-Javelins, Suresh Pillai, Declan Mccormack, John M. Kelly, Sibu C. Padmanabhan Nov 2009

Microwave-Assisted Synthesis Of Zno Micro-Javelins, Suresh Pillai, Declan Mccormack, John M. Kelly, Sibu C. Padmanabhan

Articles

The microwave (MW)-assisted formation of ZnO micro-javelins from zinc nitrate and urea in aqueous solution is described. The particles (named as ‘micro-javelins’ because of their high aspect ratio and needle-like tips) grow hexagonally with well-defined facets in the h0110i direction and pointed tips in (0001) direction. Powder X-ray diffraction patterns show the appearance of a strikingly dominant (1000) orientation. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigations reveal the morphological evolution of these hexagonal ZnO particles with time. The effect of precursor concentrations, counterion type andMWirradiation power and their consequent influence on pH and Zn2+ ion concentration are …


Simple Versatile Shearing Interferometer Suitable For Measurements On A Microscopic Scale, Emilia Mihaylova, Vincent Toal Jan 2009

Simple Versatile Shearing Interferometer Suitable For Measurements On A Microscopic Scale, Emilia Mihaylova, Vincent Toal

Articles

Microelectromechanical systems (MEMS) behave differently from massive samples. Conventional testing and inspection techniques usually fail at the microscale. Recently there has been an increasing interest in the application of optical techniques for microstructure testing, because they are high-resolution, non-contact, full-field, fast and relatively inexpensive. New interferometric systems, which are suitable for microscopic optical metrology, are of interest for engineering and industrial applications. A modified electronic speckle pattern shearing interferometer (ESPSI) with a very simple shearing device has been designed for metrology applications on the microscale. The shearing device consists of two partially reflective glass plates. The reflection coefficients of the …


One-Pot Synthesis Of Anionic (Nitrogen) And Cationic (Sulfur) Codoped High-Temperature Stable, Visible Light Active, Anatase Photocatalysts, Suresh Pillai, Declan Mccormack, Steven Hinder, Pradeepan Periyat Jan 2009

One-Pot Synthesis Of Anionic (Nitrogen) And Cationic (Sulfur) Codoped High-Temperature Stable, Visible Light Active, Anatase Photocatalysts, Suresh Pillai, Declan Mccormack, Steven Hinder, Pradeepan Periyat

Articles

No abstract provided.


One-Pot Synthesis Of Anionic (Nitrogen) And Cationic (Sulfur) Codoped High-Temperature Stable, Visible Light Active, Anatase Photocatalysts, Suresh Pillai, Declan Mccormack, Steven Hinder, Pradeepan Periyat Jan 2009

One-Pot Synthesis Of Anionic (Nitrogen) And Cationic (Sulfur) Codoped High-Temperature Stable, Visible Light Active, Anatase Photocatalysts, Suresh Pillai, Declan Mccormack, Steven Hinder, Pradeepan Periyat

Articles

No abstract provided.


Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy Jan 2009

Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy

Articles

Traditional anti-corrosion technology has relied heavily on using reducible metal species, predominantly hexavalent chromium (Cr(VI)), for protecting reactive metal alloys such as aluminium which is extensively used in the aerospace sector. However, the impending changes in the use of Cr(VI) in Europe and the United States have forced aerospace manufacturers to examine alternative materials for protecting aluminium. One of the most promising alternatives being investigated are organosilane based sol-gels containing anticorrosion additives. In this work the anti-corrosion properties of magnesium (II) nitrate (Mg(NO3)2) as a inhibitor was investigated at different concentrations (0.1% - 1.0 wt %) in a methyltriethoxysilane (MTEOS) …


A Covert Encryption Method For Applications In Electronic Data Interchange, Jonathan Blackledge, Dmitry Dubovitskiy Jan 2009

A Covert Encryption Method For Applications In Electronic Data Interchange, Jonathan Blackledge, Dmitry Dubovitskiy

Articles

A principal weakness of all encryption systems is that the output data can be ‘seen’ to be encrypted. In other words, encrypted data provides a ‘flag’ on the potential value of the information that has been encrypted. In this paper, we provide a new approach to ‘hiding’ encrypted data in a digital image.

In conventional (symmetric) encryption, the plaintext is usually represented as a binary stream and encrypted using an XOR type operation with a binary cipher. The algorithm used is ideally designed to: (i) generate a maximum entropy cipher so that there is no bias with regard to any …


Converging Flow Between Coaxial Cones, O. Hall, A. D. Gilbert, C. P. Hills Jan 2009

Converging Flow Between Coaxial Cones, O. Hall, A. D. Gilbert, C. P. Hills

Articles

Fluid flow governed by the Navier-Stokes equation is considered in a domain bounded by two cones with the same axis. In the first, 'non-parallel' case, the two cones have the same apex and different angles θ = α and β in spherical polar coordinates (r, θ, φ). In the second, 'parallel' case, the two cones have the same opening angle α, parallel walls separated by a gap h and apices separated by a distance h/sinα. Flows are driven by a source Q at the origin, the apex of the lower cone in the parallel case. The Stokes solution for the …


Nonaxisymmetric Stokes Flow Between Concentric Cones, O. Hall, C. P. Hills, A. D. Gilbert Jan 2009

Nonaxisymmetric Stokes Flow Between Concentric Cones, O. Hall, C. P. Hills, A. D. Gilbert

Articles

We study the fully three-dimensional Stokes flow within a geometry consisting of two infinite cones with coincident apices. The Stokes approximation is valid near the apex and we consider the dominant flow features as it is approached. The cones are assumed to be stationary and the flow to be driven by an arbitrary far-field disturbance. We express the flow quantities in terms of eigenfunction expansions and allow for the first time for nonaxisymmetric flow regimes through an azimuthal wave number. The eigenvalue problem is solved numerically for successive wave numbers. Both real and complex sequences of eigenvalues are found, their …