Physical Sciences and Mathematics Commons^™

Voltammetric Studies Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson

Mark R. Anderson

The voltammetry for a series of related endohedral metallofullerenes is reported. It is found that as additional metal atoms are inserted into the fullerene cage, the first reduction of the metallofullerenes shifts to more negative potentials. This is consistent with more charge being transferred to the fullerene cage from the additional metal atom; however, the magnitude of the shift is much smaller than expected.