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The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
Mark R. Anderson
Many endohedral metallofullerenes have a C82 cage surrounding the metals, even though the normal arc-vaporization method of fullerene preparation does not generate C82 in significant abundance.1-10Manolopous et al.11-13attribute the low abundance of empty-cage C82 to the unfavorable electron configuration of this species. Consequently, the prevalence of C82 in metallofullerenes may be the result of an electron transfer from the encapsulated metal atoms to the fullerene cage.10-13 The extent of this charge transfer also contributes to the properties (e.g. catalytic, superconductive, nonlinear optical, and ferromagnetic) that are attributed to the endohedral metallofullerenes.14,15Because of the importance of the charge transfer reaction, characterization …