Physical Sciences and Mathematics Commons^™

Application Of High-Precision 3d Seismic Exploration Technology In Huainan Mining Area, Liu Jun, Zhao Wei, Han Biwu

Coal Geology & Exploration

In order to deeply analyze the indication of oil shale development characteristics on paleoenvironments and provide theoretical guidance for oil shale resource evaluation, the organic geochemistry and elemental geochemistry characteristics of the Neogene Zhangcun Formation oil shale in the central part of the Qinshui basin were analyzed by Rock-Eval and TOC and the paleoclimate and paleogeographic environments of the depositional period were discussed as well. The results show that the oil shale of Zhangcun Formation has the low oil content which Tar=4.15%, higher hydrocarbon potential, kerogen is of sapropel type(I₁), which has relatively shallow burial depth. The element …

Crustal Evolution Of The New England Appalachians: The Rise And Fall Of A Long-Lived Orogenic Plateau, Ian Hillenbrand

Masters Theses

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the …

Mexican Obsidian On Maui: Hawaiian Connection, Harmonic Convergence, Or Hokum?, Matthew Boulanger

Anthropology Research

In 2014, the television show America Unearthed (A & E Networks) featured an episode discussing evidence for pre-Columbian contact between Polynesia and continental North and South America. Included in this “evidence” was a large spearpoint, allegedly found on the island of Maui. The show’s host argues that the spearpoint is made on obsidian from central Mexico, and therefore represents evidence for direct contact between Polynesian and Maya peoples prior to the sixteenth century CE. A detailed analysis of the spearpoint, including geochemical sourcing, reveals that it is indeed made of so-called Pachuca obsidian from central Mexico; however, the size, shape, …

Surface Alteration In The Ölkelduháls, Nesjavellir, And Geysir Hydrothermal Systems, Iceland: Implications For Mars, Jordan Ludyan

Theses and Dissertations

Silica- and sulfate-rich deposits observed by Mars Exploration Rover (MER) Spirit near Home Plate, Gusev crater, Mars, indicate alteration of Mars basalt by a diverse array of hydrothermal fluids and processes. Constraining the precise fluid conditions present at the time of deposition for these deposits on Mars relies on investigations of terrestrial hydrothermal systems that produce similar mineral assemblages. Alteration products and fluids collected from the Ölkelduháls, Nesjavellir, and Geysir hydrothermal areas in southern Iceland cover a wide range of end-member and intermediate fluid and alteration environments, and provide a means to compare the secondary minerals produced from different hydrothermal …

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das

Earth and Planetary Sciences ETDs

Boron has been detected on Mars [Gasda et al., 2017, Das et al., 2019, 2020] within calciumsulfate veins found within clay-rich rocks on Mars by the Mars Science Laboratory (MSL) rover using Laser Induced Breakdown Spectroscopy (LIBS) analysis. Boron plays a vital role in stabilizing ribose on Earth and has been suggested as a key requirement for life [Scorei et al., 2006, 2012; Furukawa et al., 2013, 2017; Becker et al., 2019]. Additionally, boron readily adsorbs to phyllosilicate clay minerals and is often associated with biologic processes in clay soils. The discovery of boron on Mars in proximity to phyllosilicate …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Evaluation And Analysis Of Paleoenvironments Of The Neogene Oil Shale Of Zhangcun Formation, Qinshui Basin, Liu Yanhai, Li Kunjie, Liu Dongna, Xue Shubin, Liu Yangfe, Chu Yonghui

Coal Geology & Exploration

In order to deeply analyze the indication of oil shale development characteristics on paleoenvironments and provide theoretical guidance for oil shale resource evaluation, the organic geochemistry and elemental geochemistry characteristics of the Neogene Zhangcun Formation oil shale in the central part of the Qinshui basin were analyzed by Rock-Eval and TOC and the paleoclimate and paleogeographic environments of the depositional period were discussed as well. The results show that the oil shale of Zhangcun Formation has the low oil content which Tar=4.15%, higher hydrocarbon potential, kerogen is of sapropel type(I₁), which has relatively shallow burial depth. The element …

Interpretations Of Lava Flow Properties From Radar Remote Sensing Data, Gavin Douglas Tolometti, Catherine Neish, Gordon R. Osinski, Scott S. Hughes, Shannon E. Kobs-Nawotniak

Earth Sciences Publications

The surface morphology and roughness of a lava flow provides insight on its lava properties and emplacement processes. This is essential information for understanding the eruption history of lava fields, and magmatic processes beneath the surface of Earth and other planetary bodies such as the Moon. The surface morphology is influenced by lava properties such as viscosity, temperature, composition, and rate of shear. In this work, we seek to understand how we can interpret the emplacement processes and lava properties of lava flows using remote sensing data. Craters of the Moon (COTM) National Monument and Preserve in Idaho hosts a …

Geochemical Characterization Of Base Metals In Stream Water And Sediments In The Caddo Lake Watershed, Cass, Harrison, And Marion Counties, Texas, Melinda S. Faulkner, Melanie L. Ertons, Joseph D. Watkins

Faculty Publications

The Caddo Lake watershed is located in northeastern Texas and encompasses much of Cass, Harrison, and Marion counties. The watershed is drained by major streams and tributaries flowing in an easterly direction over Eocene-aged rocks and sediments of the Wilcox and Claiborne groups, and empty into the western arm of Caddo Lake. Since 1995, Caddo Lake and some of its tributaries have been included on the State of Texas Clean Water Act 303(d) list by the Texas Commission on Environmental Quality (TCEQ) for impairment due to mercury content in edible tissue, depressed dissolved oxygen, base metal concentrations, and low pH …

Top–Down Control On Eruptive Style At Masaya Volcano Inferred From Melt Composition, Lisa Hlinka

Student Theses

Highly explosive, Plinian-type eruptions of basaltic magma are enigmatic because basaltic melts have lower viscosities than more silicic melts which have traditionally been considered essential for such explosive eruption style. Masaya volcano, Nicaragua, is one of the few basaltic volcanoes to have generated a wide range of eruptive styles, from effusive lava lake activity to voluminous Plinian fall deposits. This volcano thus offers a unique case study to better constrain ideas on basaltic eruption style controls.

We analyze olivine-, plagioclase- and clinopyroxene-hosted melt inclusions as well as matrix glasses from lava lake (LL) ejecta and two Plinian tephra deposits—the 2.1 …

Geochemical Characteristics Of Elements In The Paleogene Yunlong Formation And The Restoration Of Paleoenvironment In Lanping Basin, Liu Xiaokang, Zhang Zhibo, Zhu Zhijun, Wu Chuanfu, Wei Xingxing, Liu Haiyan, Jin Tengrui, Baima Quzong

Coal Geology & Exploration

In order to restore the sedimentary environment of the Paleogene Yunlong Formation in the Lanping basin, inductively coupled plasma mass spectrometry(ICP-MS) was used to analyze trace elements in 13 samples of gypsum, limestone, gypsum mud, mudstone and sandstone from the Paleogene Yunlong Formation in Lanping Basin. The sedimentary environments and paleoclimate are estimated based on the spider diagram of trace elements in each lithology and the characteristics of the ratio of Cu/Zn, Sr/Cu and Sr/Ba and the content of Sr. The results show that:gypsum, limestone, gypsum mud, mudstone and sandstone are all rich in Rb, Pb, Zr; gypsum and gypsum …

Rare Earth Element Contents, Geochemistry Of Soil Samples Between Burdur And Isparta Region And Assessment Of Their Origin, Ebru Tat, Mustafa Gürhan Yalçin

Bulletin of the Mineral Research and Exploration

This study was carried out in 5 locations between Burdur and Isparta in the inner southern part of Isparta Bend. The study aims to determine the rare earth element (REE) concentrations in the soil samples collected from the field and to interpret the origin of the high concentrations detected. In this context, a total of 104 samples were collected from Canakli Village (19 samples), Cobanisa Village (34 samples), Kuyubasi Village (17 samples), Kuzca Village (17 samples), and Yilanli Village (17 samples) in the study field. The average ∑REE (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, …

Geochemical Variability & Implications For Magma Transport At 14°N On The Mid-Atlantic Ridge, Emma Elizabeth Mccully

Boise State University Theses and Dissertations

Observations of seafloor bathymetry and gravity surveys indicate that magma focuses in the center of slow spreading Mid-Ocean Ridge (MOR) segments, however; it is not well constrained how magma is generated, stored, and transported to the segment ends. There are two end-member models for magma transport: 1) a focused magma model wherein the magma upwells beneath the entire ridge axis, is focused and pools beneath the center of the segment, and is then transported towards the segment ends via lateral diking in the shallow crust and 2) a distributed magma model wherein magma vertically upwells and is erupted on the …

Paleoenvironment Reconstruction Of The Eocene Southeastern Tethys Using Geochemistry Of Sedimentary Rocks, Liliana CalderóN Convers

Theses, Dissertations and Culminating Projects

The Early Eocene hyperthermals are a series of transient global warming events that occurred between 54.09 and 52.63 Ma, and are considered as ancient analogues for future climate change. These hyperthermal events are well studied in the deep sea sites, but have not been investigated in the eastern Tethys Ocean. Here, we report new major and trace element geochemistry and stable carbon isotope data of the Early Eocene strata deposited in a shallow marine foreland basin prior to the main stage of India-Asian continent collision at Qumiba section in the Tingri County, southern Tibet. These geochemical data are used to …

Structure And Adsorption At The BastnäSite-Water Interface: Fundamental Investigations Toward Rare Earth Mineral Recovery, Anna Kristiina Wanhala

Doctoral Dissertations

This dissertation investigates the interfacial structure and reactivity of a rare earth mineral in the context of froth flotation. Bastnäsite [(Ce,La,Nd)FCO3], one of the primary mineral sources of rare earth elements, has been chosen for this investigation. Flotation separation relies on selective adsorption of collector ligands to the desired mineral surface in solution; fundamental understanding of these adsorption reactions will aid in the development of more effective separation technologies.

Chapter 1 presents an introduction to the significance of rare earth minerals and the process of froth flotation. Chapters 2 and 3 address the adsorption reactions of ligand molecules at the …

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

MSU Graduate Theses

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Chemostratigraphy Of Carbonate Gravity Flows Of The Wolfcamp Formation In Crockett County, Midland Basin, Texas, Alex Blizzard, Julie Bloxson

Electronic Theses and Dissertations

Sediment gravity flows into deep-water environments are important stratigraphic traps in lithologically diverse reservoirs generating multiple plays for hydrocarbon exploration. These highly heterogeneous deposits can be studied by utilizing chemostratigraphy and higher-order sequence stratigraphy; being an accurate method for reservoir characterization. Studying these gravity flows along a carbonate platform’s slope can further expand an understanding of the stratigraphy that is filling adjacent basins. The application of elemental analyses can support in identifying mineralogy that impact reservoir quality, especially when conventional testing cannot be applied.

This study utilizes five cores containing the Wolfcamp Formation from the southeastern slope of the Central …

Geochemistry Of The Lazufre Volcanic Complex: Determining The Geometries And Processes Of The Magmatic Sources In The Central Andean Volcanic Zone, Brooke Erin Benz

MSU Graduate Theses

The Central Andes in South America contain many active volcanoes and volcano complexes due to constant subduction producing extrusive rocks varying in composition. The Lazufre Complex, Chile-Argentina border, consists of two Pleistocene volcanic centers, Lastarria and Cordon del Azufre andesite and dacite lava flows and domes. Whole-rock K-Ar dates of lavas from Cordon del Azufre place the most recent eruptions at 0.6-0.3 Ma ±0.3 Ma. Major-element data of plagioclase and pyroxene show homogeneous compositions between the centers, which is consistent with whole rock major- and trace-element compositions. The primary composition of the pyroxenes are augite and diopsides for cpx and …

Pumice Compositions And Mineral Chemistry From Lascar Volcano, Chile, Madelaine M. Stearn

MSU Graduate Theses

Lascar volcano is one the most active volcano in the Central Volcanic Zone of the Andean Cordillera, with 36 Holocene eruptions including a VEI 4 eruption in April 1993. Activity has not been consistent throughout time, and therefore, the processes behind it are poorly understood. Lascar volcano has cyclic behavior and has had four stages of activity, each of which had a unique eruptive style and product composition. Stage I (<43 >ka) had primarily mafic andesite lavas erupted effusively from a stratocone. Stage II initiated with dome building events ESE of the original vent and culminated in the 26.45 ka …

Archaeological Feature Identification Through Geochemical Analysis Of Arctic Sediments From The Cape Krusenstern National Monument, Northwest Alaska, Patrick William Reed

Dissertations and Theses

Identification and interpretation of archaeological phenomena is typically based on visual cues and the physical presence of "something archaeological," such as a diagnostic artifact, landscape modification, or structural element. Yet many archaeological features, i.e. the discrete archaeological deposits related to past human behavior, lack clear indicators of human activity that provides clues to the feature's origin. At the Cape Krusenstern beach ridge complex, located in northwest Alaska, ambiguous features, that could be natural or anthropogenic (vegetation anomalies), or are of unknown cultural function (indeterminate), comprise 60% of the identified features at the complex. These ambiguous features represent a large gap …

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …

Geochemical Analysis And Heat-Treatment Of Natural Sapphires From Madagascar And Tanzania In Oxidizing And Reducing Conditions, Lukas Karuza, Dr. Michael B. Wolf, Brian Konecke Phd

Geology: Student Scholarship & Creative Works

Natural or synthetic sapphires can be heat-treated to improve the clarity by removing “silk” (inclusions) and to change color by introducing color-inducing elements (i.e., chromophores) into the lattice structure or changing their valency. Due to these reasons, sapphires can be heat-treated to increase their monetary value. Twenty natural blue (C1), 20 green (C2), and 20 clear (C3) sapphires from Madagascar and Tanzania were heat-treated in a muffle furnace in oxidizing and reducing conditions, from 1200 to 1600℃, for 10-hour soak time. In total, 5 experiments were conducted in which soak time remained constant: experiment 1 was performed at 1200℃, exp. …

Geochemical And Industrial Properties Of The Kejal Kaolin Deposit, Nw Iran, Tohid Nouri, Rahim Masoumi

Turkish Journal of Earth Sciences

The Kejal kaolin deposit, situated in the northwest of Iran, is considered a small part of the Hashtjin hydrothermal zone. The kaolinization process in this deposit has occurred in ignimbritic and volcanic tuff parent rocks in different grades such that severely kaolinized samples can be found in the middle section of the kaolinization profile. Kaolinite is the most abundant clay mineral in the studied samples. Quartz and cristobalite are the main minerals while anatase is the minor mineral of the kaolin samples. Among the major oxides, SiO2, Al2O3, and TiO2 show the highest concentrations in kaolin samples. The mass change …

Geochemistry And Petrography Of Beach Sands Along The Western Coast Of Ghana:Implications For Provenance And Tectonic Settings, Mahamuda Abu, Emmanuel Daanoba Sunkari

Turkish Journal of Earth Sciences

The paleoweathering, provenance, and tectonic setting of sediments of the western coast of Ghana were unraveled using the geochemistry of 29 beach sands, which are characterized by coarse-, medium-, and fine-grained sizes. The coarse-grained beach sands contain higher SiO2 content (2.9-96 wt.%) than the medium-grained (4.9-94 wt.%) and fine-grained (16.1-90.7 wt.%) sands, implying that the increase in grain size is related to the increase in SiO2 content. Al2O3 and CaO concentrations are higher in the fine- and medium-grained sands than the coarse-grained sands. The beach sands are compositionally immature based on the index of compositional variable values (1.17-141) and Th/Sc …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

Mineralogical, Petrographic, And Geochemical Characterization Of Colored İscehisarmarbles (Afyonkarahisar, W-Turkey), Meti̇n Bağci

Turkish Journal of Earth Sciences

The İscehisar marbles are located 25 km northeast of Afyonkarahisar on the Ankara highway in the vicinity of the town of İscehisar. These marbles have economic importance in the Afyon region. The purpose of this study was to reveal the mineralogical, petrographic, and geochemical characteristics of the İscehisar marbles, displaying different colors, structures, textures, and other different features. Based on polarized light microscopy investigations, the İscehisar marbles can be classified into 3 subgroups: from bottom to top 1) calcitic marbles composed of calcite minerals, 2) transition/interlayer marbles, and 3) dolomitic marbles. According to the field descriptions, each subgroup has various …

Investigating Effects Of Carbonate Minerals On Shale- Hydraulic Fracturing Fluid Interactions In The Marcellus Shale, Brennan Matthew Ferguson

Graduate Theses, Dissertations, and Problem Reports

Natural gas extracted from tight shale formations, such as the Marcellus Shale, represent an important and developing front in energy exploration. By fracturing these formations using pressurized fracturing fluid, previously unobtainable hydrocarbon reserves may be tapped. While pursuing this resource hydraulic fracturing operations leave chemically complex fluids in the shale formation for at least two weeks. This provides a substantial opportunity for the hydraulic fracturing fluid (HFF) to react with the shale formation at reservoir temperature and pressure. In this study, we investigated the effects of the carbonates on shale-HFF reactions with a focus on the Marcellus Shale. We determined …

Applying Garnet And Zircon Ree Linkages To Determine Timing Of P-T Conditions And Tectonic Implications For Uhp Eclogites And Hp Granulites, Dulan Uhp Terrane, China, Wesley Weisberg

All Master's Theses

The Dulan ultrahigh-pressure (UHP) terrane in western China hosts rocks that record continental collision, however; the timing of peak P-T conditions in UHP eclogites and HP granulites, and the tectonic significance of their spatial relationship within the Dulan UHP terrane are not well understood. This study, (1) evaluates rare earth element (REE) equilibrium between garnet and zircon, to assess coeval growth; (2) links timing (from zircon) to the P-T history (from garnet) to constrain the P-T-t path of the Dulan UHP terrane and interpret implications for zircon growth; (3) refines P-T conditions for HP granulite; and (4) evaluates the tectonic …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …