Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das Nov 2020

Boron Adsorption In Clay Minerals: Implications For Martian Groundwater Chemistry And Prebiotic Processes, Matthew A. Nellessen, Laura Crossey, Patrick J. Gasda, Horton Newsom, Abdulmehdi Ali, Eric J. Peterson, Nina Lanza, Adriana Reyes-Newell, Dorothea Delapp, Chris Yeager, Andrea Labouriau, Roger C. Wiens, Samuel Clegg, Shelbie Legett, Debarati Das

Earth and Planetary Sciences ETDs

Boron has been detected on Mars [Gasda et al., 2017, Das et al., 2019, 2020] within calciumsulfate veins found within clay-rich rocks on Mars by the Mars Science Laboratory (MSL) rover using Laser Induced Breakdown Spectroscopy (LIBS) analysis. Boron plays a vital role in stabilizing ribose on Earth and has been suggested as a key requirement for life [Scorei et al., 2006, 2012; Furukawa et al., 2013, 2017; Becker et al., 2019]. Additionally, boron readily adsorbs to phyllosilicate clay minerals and is often associated with biologic processes in clay soils. The discovery of boron on Mars in proximity to phyllosilicate …


Removal Of Pb2+ And Cd2+ From Aqueous Solutions Using Pocl3 Cross-Linked Carboxymethyl Derivatives Of Legume Starch, Ayodele Akinterinwa, Ebun Oladele, Albert Adebayo, Olubode Ajayi Sep 2020

Removal Of Pb2+ And Cd2+ From Aqueous Solutions Using Pocl3 Cross-Linked Carboxymethyl Derivatives Of Legume Starch, Ayodele Akinterinwa, Ebun Oladele, Albert Adebayo, Olubode Ajayi

Makara Journal of Science

Starch was extracted from Kwakil beans and cross-linked with POCl3 (1% v/w of starch dry basis [db]). The cross-linked starch (PCS) derivative was carboxymethylated with sodium monochloroacetate (5% to 30% w/w of starch db) to obtain cross-linked carboxymethyl starch (PCCS) derivatives. The derivatives were used in the adsorption of Pb2+ and Cd2+, and the process was monitored using atomic adsorption spectrometer. Carboxymethylation enhanced adsorption of ions (Cd2+, 95% to 96%; Pb, 65% to 94%), and it was more appreciable with Pb2+ than Cd2+ as degree of substitution increased from 0.008 to 0.052. …