Physical Sciences and Mathematics Commons^™

An Investigation Of The Effects Of Chemical And Physical Weathering On Submerged Karst Surfaces, Bryan Charles Booth

USF Tampa Graduate Theses and Dissertations

Reports an investigation of the effects of chemical and physical weathering on submerged karst surfaces that pairs laboratory studies with computer modeling studies. The first study attempts to quantify the production of carbonate fines; soluble sediments produced by the incomplete dissolution of karst minerals during chemical weathering. Results show carbonate fine production in relation to dissolutional action; Chalk: 42.8%; Coquina: 2.6%; Dolomite: 3.1%; Gray Limestone: 4.8%; Ocala Limestone: 3.1%; Shell Limestone: 6.1%; Travertine: 8.6%. Due to the use of hydrochloric acid as opposed to carbonic acid these results may not be fully valid for application to natural speleogenic processes. The …

Multiple Scales Of Beach Morphodynamic Processes: Measurements And Modelling, Jun Cheng

USF Tampa Graduate Theses and Dissertations

Multiple scales of beach morphodynamic processes ranging from those of wave-breaking induced turbulence, individual wave, storm, seasonal, to inter-annual are examined in this dissertation based on both laboratory and field data. These processes were simulated using process-based numerical models and data-driven models.

At a microscale, separating turbulence from orbital motion under breaking waves in the surf zone is essential to understanding wave-energy dissipation. Velocity data under monochromatic and random waves in the large-scale sediment transport facility (LSTF) were analyzed. Moving averaging provides a simple method for extracting turbulence from velocity measurements under random breaking waves collected at a reasonably high …

A Comparative Analysis Of Portable X-Ray Fluorescence Spectrometry And Stable Isotopes In Assessing Ancient Coastal Peruvian Diets, Theresa Jane Gilbertson

USF Tampa Graduate Theses and Dissertations

This dissertation explores a cross-cultural analysis of the dietary signatures of four coastal cultures of prehistoric Peru. A combination of elemental analysis based on portable x-ray fluorescence spectrometry (pXRF), testing trace elements presented in 209 individuals’ skulls representing the Nazca (38), Cañete (33), Lima (40), and Moche (98) valleys and/or cultures of the first millennium AD, is weighed in conjunction with isotope ratio mass spectrometry (IRMS) to analyze human bone collagen and bone apatite derived from a portion of the individuals represented in the Nazca, Cañete, and Lima cranial samples.

Evidence from the results of both tests are weighed using …

Investigation Of The Mechanisms For Mobilization Of Arsenic In Two Asr Systems In Southwest Central Florida, Gregg William Jones

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery (ASR) is a strategy in which water is injected into an aquifer when it is plentiful and pumped from the aquifer when water is scarce. An impediment to ASR in Florida is leaching of naturally-occurring arsenic from limestone of the Upper Floridan Aquifer System (UFAS) into stored water. The concentration of arsenic in surface water, which serves as the recharge water for many ASR systems, and native groundwater is usually much less than 3.0 µ/L. However, data from ASR wells in Florida show that arsenic in recovered water frequently exceeded the 10 µg/L maximum contaminant level …

Phosphorus Sorption Dynamics In Shallow Groundwater, Coastal Everglades, Florida, Usa, Hilary Flower

USF Tampa Graduate Theses and Dissertations

For this dissertation I studied phosphorus (P) sorption dynamics in the shallow groundwater of the southern Everglades. In particular, I examined how the ambient water type governs soluble reactive P (SRP) availability through adsorption/desorption reactions with the aquifer matrix. Chapter 2 investigated how P sorption dynamics of the mangrove root zone sediment are affected by high bicarbonate brackish groundwater compared to both fresh groundwater and saltwater. The results from chapter 2 show that the sediment exhibited exceptionally low sorption efficiency in the high bicarbonate brackish water, which would allow ambient water SRP concentration to be maintained at a higher level. …

Is Nubia Plate Rigid? A Geodetic Study Of The Relative Motion Of Different Cratonic Areas Within Africa., Mary Wambui Njoroge

USF Tampa Graduate Theses and Dissertations

The Nubia plate is normally considered to be a rigid plate and as such used in the realization of terrestrial reference frame. Gondwana breakup plate reconstruction, the Cameroon volcanic line, seismicity, and the morphology of the Okavango rift zone (ORZ) suggest the presence of internal deformation within the Nubia plate. To test this hypothesis, six different reference frames were developed from the velocity field of three individual regions (West, Central and South), and of different combinations of them (West+Central, South+Central, and Nubia as a whole). The residual velocities with respect to these references frame help us understand the presence of …

Geophysical Evidence For Mid-Crustal Magma Reservoirs In The Lassen Volcanic Region, California, Samantha Catherine Tavarez

USF Tampa Graduate Theses and Dissertations

Regional-scale complete Bouguer gravity anomalies underlying the Lassen and Shasta -Medicine Lake regions in northern California and southern Oregon are associated with subduction of the Gorda plate beneath North America. These generally negative anomalies reflect where underplating has deepened to form the mantle wedge, and where subduction has given rise to a series of Quaternary volcanoes comprising the southernmost end of the Cascade range. Multiple conductive bodies were identified by Park and Ostos (2013) in their magnetotelluric (MT) study of the broader Lassen volcanic region. Their broadband and long period measurements were conducted along a 250 km profile spanning from …

Evaluation Of Low-Cost Low Impact Development Practices In Southwest Florida For The Control Of Urban Runoff, Laura Kathren Rankin

USF Tampa Graduate Theses and Dissertations

Stormwater management is required due to development and alteration of the natural environment. It is heavily regulated in Florida and at the national level. Over the last two decades, Low Impact Development (LID) has been promoted as a sustainable and environmentally friendly method of controlling urban runoff. Case studies, provided in Chapter 2, show that LIDs can restore watershed hydrology by balancing the water budget. The difference in runoff between pre-development and post-development appears to increase with soil perviousness. However, the potential for mitigating the impacts of urbanization through runoff reduction is also greater for pervious, sandy soils that dominate …

In Situ Studies Of Limestone Dissolution In A Coastal Submarine Spring, Rachel Marie Schweers

USF Tampa Graduate Theses and Dissertations

Limestone dissolution in karst environments is likely due to geochemistry of the water, the actions of microbial communities, and the effect of water flow. We explored the rate of limestone dissolution and will examine here the microbial communities associated with the limestone. A conduit within the brackish cave, Double Keyhole Spring, on the coast of central west Florida was the site of the experiment. PVC pipes (5cm x 16cm) were filled with crushed limestone that was screened to a 1.9cm – 2.54cm size range. There were three treatments (5 replicates each): Control - sealed autoclaved controls with limestone and conduit …

A Bat-Guano-Derived Δ15N And Δ13C Record Of Paleoenvironmental Change: Zidită Cave, Romania, Daniel Martin Cleary

USF Tampa Graduate Theses and Dissertations

Because nitrogen isotopes are fractionated along the soil-plant-insect-bat-guano pathway, it may be possible to reconstruct environmental and climatic changes reflected in the nitrogen isotopic composition of guano. A 1.5-m core of bat guano from Zidită Cave (western Romania) provides a record of climatic and anthropogenic influence on the regional nitrogen cycle and paleoenvironmental controls on nitrogen transforming processes. Increasing and decreasing trends of nitrogen isotopic composition (δ¹⁵N values) correspond well with changes in the influence of farming practices, deforestation, and forest expansion. These influences likely had a significant effect on the openness of the nitrogen cycle, resulting in …

Informing The Design And Deployment Of Health Information Technology To Improve Care Coordination, Diego A. Martinez

USF Tampa Graduate Theses and Dissertations

In the United States, the health care sector is 20 years behind in the use of information technology to improve the process of health care delivery as compared to other sectors. Patients have to deliver their data over and over again to every health professional they see. Most health care facilities act as data repositories with limited capabilities of data analysis or data exchange. A remaining challenge is, how do we encourage the use of IT in the health care sector that will improve care coordination, save lives, make patients more involved in decision-making, and save money for the American …

Millennial-Scale Variability Of A Major East Antarctic Outlet Glacier During The Last Glaciation, Michelle Guitard

USF Tampa Graduate Theses and Dissertations

Ongoing retreat of Antarctica’s marine-based glaciers is associated with warm (~2° C) modified Circumpolar Deep Water intrusion onto the continental shelf, suggesting that Southern Ocean temperatures may influence Antarctic ice sheet stability. Understanding past cryosphere response to environmental forcing is crucial to modeling future ice sheet behavior. Of particular interest is the response of the East Antarctic Ice Sheet (EAIS), which stands to contribute ~20 m to global sea level. However, marine sediment sequences recording timing and variability of EAIS fluctuations through the last major climate shift, the Last Glacial Maximum (LGM), are either missing from the margin or have …

Ocean Forcing Of Quaternary East Antarctic Ice Sheet Evolution: An Ice-Proximal Sedimentary Perspective, Michelle E. Guitard

USF Tampa Graduate Theses and Dissertations

Antarctica and the Southern Ocean play a critical role in Earth’s climate system. Antarctica’s ice sheets contain enough ice to raise global sea level by ~58 m, and the Southern Ocean distributes climate signals and nutrients to the major ocean basins and the deep ocean. Antarctica’s largest ice sheet, the East Antarctic Ice Sheet (EAIS), was considered stable compared to those in West Antarctica and the Antarctic Peninsula because it was thought to be grounded above sea level. However, subglacial topography now reveals vast submarine basins and measurements of ice velocity in the Pacific sector indicate marine-terminating outlet glacier thinning …

Spatiotemporal Sensing And Informatics For Complex Systems Monitoring, Fault Identification And Root Cause Diagnostics, Gang Liu

USF Tampa Graduate Theses and Dissertations

In order to cope with system complexity and dynamic environments, modern industries are investing in a variety of sensor networks and data acquisition systems to increase information visibility. Multi-sensor systems bring the proliferation of high-dimensional functional Big Data that capture rich information on the evolving dynamics of natural and engineered processes. With spatially and temporally dense data readily available, there is an urgent need to develop advanced methodologies and associated tools that will enable and assist (i) the handling of the big data communicated by the contemporary complex systems, (ii) the extraction and identification of pertinent knowledge about the environmental …

Reconstructing Paleoenvironments Of The Plio-Pleistocene Tamiami Formation Of Florida With Benthic Foraminifera, Heather Bender

USF Tampa Graduate Theses and Dissertations

There is general agreement that a range of paleodepths and environments are represented in the individual shell units of the middle Pliocene to earliest Pleistocene Tamiami Formation of southwest Florida, but maximum depths remain poorly constrained. Here, benthic Foraminifera abundances are used as a paleoenvironmental proxy to compare the upper Tamiami from quarries in Sarasota, Florida to Recent modern coastal, bay, and reef habitats of Florida, the Grand Cayman Islands, and Puerto Rico, ranging in depth from 0 to 55 meters. I used: (1) ordination techniques, including detrended correspondence analysis (DCA) and cluster analysis, to compare upper Tamiami foraminiferal assemblages …

Mid-Holocene Speleothem Climate Proxy Records From Florida And Belize, Anna L. Pollock

USF Tampa Graduate Theses and Dissertations

As global temperatures rise due to anthropogenic climate change, water resources, thus economies, are threatened. A geologically recent period of increased temperatures is the mid-Holocene and an investigation of its climate may allow for a better understanding of future precipitation and changes to regional water resources. The regions of interest are tropical Northern Central America and subtropical North America with Belize and Florida representing each climate zone. By reconstructing mid-Holocene climate in Florida and Belize, I hope to provide a better understanding of how increased temperatures and a reduced latitudinal temperature gradient impacts both precipitation patterns and variability. Today, drivers …

Morphodynamics Of Mullet Key, West-Central Florida, Emeli Sandoval

USF Tampa Graduate Theses and Dissertations

Mullet Key is a right angle barrier island located at the mouth of Tampa Bay, west-central Florida. Based on historical shoreline data from 1873, the Gulf (west)-facing section of the beach has been dynamic illustrating large beach advances and retreats of up to 500 m on a decadal scale, while the south (channel)-facing section of the beach has shown to maintain a stable shoreline. This study focuses on the morphodynamics of the Gulf-facing beach. Since the 1920s, most of the Gulf-facing beach has been accreting except at the southern end near the Tampa Bay main channel. However, over the past …

The Speleogenesis Of Vallgornera Cave (Mallorca, Spain): A Mineralogical And Morphological Study, Jacqueline Amelia Diehl

USF Tampa Graduate Theses and Dissertations

Cova des Pas de Vallgornera (CPV) is morphologically and scientifically, the most prominent karst feature of Mallorca Island (Spain). It consists of over 74 km of passages developed within two carbonate lithologies (reef front and back reef facies) of Upper Miocene age. Two distinct cave patterns are recognized, both tightly controlled by the type of facies; spongework mazes and collapse chambers are characteristic for the reef front unit, whereas linear, fracture-guided galleries develop in the back reef carbonates. CPV is abundantly decorated with a variety of speleothems.

The overarching goal of this study is to provide evidence towards the cave's …

Nearest Neighbor Foreign Exchange Rate Forecasting With Mahalanobis Distance, Vindya Kumari Pathirana

USF Tampa Graduate Theses and Dissertations

Foreign exchange (FX) rate forecasting has been a challenging area of study in the past. Various linear and nonlinear methods have been used to forecast FX rates. As the currency data are nonlinear and highly correlated, forecasting through nonlinear dynamical systems is becoming more relevant. The nearest neighbor (NN) algorithm is one of the most commonly used nonlinear pattern recognition and forecasting methods that outperforms the available linear forecasting methods for the high frequency foreign exchange data. The basic idea behind the NN is to capture the local behavior of the data by selecting the instances having similar dynamic behavior. …

Modeling Intrusive Geometries Of A Shallow Crustal Intrusion: New Evidence From Mount Ellsworth, Utah, Nathan Nushart

USF Tampa Graduate Theses and Dissertations

Surface displacements resulting from upper-crustal intrusion of melt are a paramount concern for communities and facilities located in or near active volcanic areas (e.g. Campi Flegrei, Yucca Mtn.). Study of active intrusions such as Campi Flegrei, Italy west of Mt. Vesuvius, is limited to remote observations through geophysical/geodetic procedures. While the surface displacement due to melt emplacement at depth can easily be determined, the geometries and depth of intrusions are often based on simplified assumptions (e.g. spheres and prolate or oblate ellipsoids). These models benefit from data constraining both the geometries of the individual intrusions, and the kinematics and mechanics …

Communication Of Lava Flow Hazards At The San Francisco Volcanic Field, Flagstaff, Arizona, Catherine St. John Carter

USF Tampa Graduate Theses and Dissertations

This thesis examines different methods of communicating volcanic hazards to the population of Flagstaff, Arizona using the results of a recent lava flow hazard assessment of the nearby San Francisco Volcanic Field (SFVF). Harburger (2014) determined that given a lava flow originating in the SFVF, there is a statistical probability that it will inundate the city of Flagstaff or even originate from a vent within the city limits. Based on the recurrence rates for the most recent eruptions (3 x 10-4/year), the probability of lava flow inundation in Flagstaff is 1.1 x 10-5 per year.

This study considers the effects …

Schreibersite: Synthesis, Characterization And Corrosion And Possible Implications For Origin Of Life, Nikita Latesha La Cruz

USF Tampa Graduate Theses and Dissertations

We present study of the synthesis and reactions of an analog of the meteoritic mineral schreibersite with formula (Fe,Ni)3P, believed to be a prebiotic source of reactive phosphorus that may have prompted the formation of phosphorylated biomolecules near the time of the origin of life (Pasek and Lauretta, 2005). The mineral was synthesized by mixing stoichiometric proportions of elemental iron, nickel and phosphorus and heating in a tube furnace at 820°C for approximately 235 hours under argon or under vacuum, a modification of the method of Skála and Drábek (2002). The mineral was characterized using X-ray diffractometry (XRD), X-ray photoelectron …

Ground-Coupled Air Waves: A Seismological Case Study Of The Explosion Quakes Of The 2007 Eruption Of Pavlof Volcano, Alaska, Cassandra Marie Smith

USF Tampa Graduate Theses and Dissertations

An abnormally high number of explosion quakes were noted during the monitoring effort for the 2007 eruption of Pavlof Volcano on the Alaskan Peninsula. In this study we manually counted the explosion quakes from their characteristic ground-coupled air waves. This study makes an effort at better quantifying the number of explosion quakes and how the characteristic ground-coupled air waves are affected by wind direction and wind speed. Additionally this study investigates how the ground coupled air waves might be used in a monitoring or analysis effort by calculating energy release and gas mass release. Over 3.2x10⁴ quakes were recorded. …

A Composite Spatial Model Incorporating Groundwater Vulnerability And Environmental Disturbance To Guide Land Management, Johanna L. Kovarik

USF Tampa Graduate Theses and Dissertations

Research has long recognized and studied the dynamics of groundwater processes. More recently, groundwater dependent ecosystems (GDEs) are being recognized for their diversity and vulnerability to anthropogenic impact. Groundwater in karst landscapes presents a distinctive situation where flow through the subsurface often moves rapidly on the scale of days and weeks as opposed to years or millennia in other systems. This distinctive situation of karst systems and their vulnerability to human impacts necessitate an integrated and multifaceted approach for the management of these important resources. However, development of such an approach is complicated by the difficulty of obtaining detailed data …

Glaciological Applications Of Terrestrial Radar Interferometry, Denis Voytenko

USF Tampa Graduate Theses and Dissertations

Terrestrial Radar Interferometry (TRI) is a relatively new ground-based technique that combines the precision and spatial resolution of satellite interferometry with the temporal resolution of GPS. Although TRI has been applied to a variety of fields including bridge and landslide monitoring, it is ideal for studies of the highly-dynamic terminal zones of marine-terminating glaciers, some of which are known to have variable velocities related to calving and/or ocean-forced melting. My TRI instrument is the Gamma Portable Radar Interferometer, which operates at 17.2 GHz (1.74 cm wavelength), has two receiving antennas for DEM (digital elevation model) generation, and images the scenes …