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Full-Text Articles in Physical Sciences and Mathematics

Characterization Of Some Natural Copper Samples From The Keweenaw Peninsula Of Lake Superior Using Electron Microscopy And X-Ray Tomography Techniques, Emilie Mk Landry Jul 2022

Characterization Of Some Natural Copper Samples From The Keweenaw Peninsula Of Lake Superior Using Electron Microscopy And X-Ray Tomography Techniques, Emilie Mk Landry

Electronic Thesis and Dissertation Repository

Copper corrosion is of interest to Canada’s Nuclear Waste Management Organization as it relates to their multi-barrier system for nuclear waste disposal in deep geologic repositories. Spent fuel canisters coated with a thin copper layer must persist for up to one million years. Natural copper from the Keweenaw Peninsula in Michigan, USA, has persisted for over 1 billion years and is here characterized to understand copper corrosion over geological time. Copper samples representing three rock types were characterized using optical microscopy, scanning electron microscopy techniques (energy dispersive X-ray spectroscopy and electron backscatter diffraction), and micro-computed X-ray tomography (microCT) to establish …


Combined Effects Of Temperature And Heavy Metals On The Performance Of The Giant Salmonfly., James Frakes, Amanda Andreas, Benjamin P. Colman, Aurthur Woods Jan 2022

Combined Effects Of Temperature And Heavy Metals On The Performance Of The Giant Salmonfly., James Frakes, Amanda Andreas, Benjamin P. Colman, Aurthur Woods

Graduate Student Theses, Dissertations, & Professional Papers

In many freshwater ecosystems, communities of aquatic insects are facing the combined stresses of warmer waters due to climate change and increased exposure to heavy metal toxicants. Although each stressor may threaten aquatic insects independently, they also likely interact in important ways to affect insect physiology and performance. Here we investigate this potential interaction using two populations of aquatic nymphs of the giant salmonfly, Pteronarcys californica, collected from adjacent rivers in Montana: naïve individuals from Rock Creek, a relatively pristine stream, and individuals from the Upper Clark Fork River, which has a history of heavy metal pollution and higher …


Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi Jan 2020

Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi

Graduate Research Theses & Dissertations

Porphyry ore deposits are major sources of copper (Cu) and gold (Au) and form when a magmatic volatile phase (MVP) exsolves from a porphyritic intermediate to felsic melt and transports metals to surrounding country rock where they precipitate in an ore zone. There is a consensus that the chloride concentration of the MVP has a direct relationship to the concentration of Cu and Au in the MVP, but the role of dissolved HCl on Cu and Au concentrations has not been addressed. It is hypothesized that increasing HCl concentrations in the MVP will result in higher concentrations of Cu and …


Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab Jan 2020

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …


An Evaluation Of The Lithologies And Geochemistry Of The Upper Beaver Deposit Of The Kirkland Lake Area, Katherine E. Feick Dec 2016

An Evaluation Of The Lithologies And Geochemistry Of The Upper Beaver Deposit Of The Kirkland Lake Area, Katherine E. Feick

Electronic Thesis and Dissertation Repository

The Upper Beaver Cu-Au deposit contains a unique style of mineralization in the Larder Lake and Kirkland Lake areas in terms of mineralization, alteration style, and age. This study aims to use company-provided data, supplemented with focused data collection, to evaluate what information can be attained from company-provided geochemical data. The evaluation uses a combination of hand sample, petrographic, geochemical, statistical, and microprobe analytical methods.

Lithogeochemical analyses indicated that the altered igneous host rock is calc-alkaline in composition and is most likely part of the diorite-monzonite suite. Further, exploratory data analysis of Au and Cu mineralization identified that there are …


Porphyry Copper Exploration Of The Hualapai Mountains, Mohave County, Arizona, Usa: A Multi-Faceted Approach, Patrick Kevin Meazell Aug 2014

Porphyry Copper Exploration Of The Hualapai Mountains, Mohave County, Arizona, Usa: A Multi-Faceted Approach, Patrick Kevin Meazell

UNLV Theses, Dissertations, Professional Papers, and Capstones

A variety of exploration methods including geologic mapping, trace- and major-level geochemical analyses, fluid inclusion petrography, remote sensing, and SWIR clay spectroscopy were used to investigate the potential for porphyry Cu-Mo mineralization at the Wikieup prospect, in the southern Hualapai Mountains of northwestern Arizona. Aspects of the Mineral Park mine were used as an analogue to guide exploration due to the proximity and similar geology of the area.

The Hualapai Mountains are a series of northwest-trending Precambrian gneisses, schists, granitoids and amphibolites that have been cut by younger intrusive rocks. Within the Wikieup study area, the intrusive rocks include aplite …


Organic Copper Binding Ligands And Thiol Compounds Produced By Bacteria And In The Elizabeth River, Virginia, Christina Louise Dryden Jul 2014

Organic Copper Binding Ligands And Thiol Compounds Produced By Bacteria And In The Elizabeth River, Virginia, Christina Louise Dryden

OES Theses and Dissertations

This dissertation presents work focusing on copper and organic copper binding ligands in laboratory cultures and the Elizabeth River, Virginia. Laboratory cultures of the marine bacterium Vibrio parahaemolyticus were used to demonstrate the influence of elevated copper concentrations on copper-complexing ligand and thiol production. Copper-complexing ligands similar in binding strength to the strongest natural ligands were detected in V. parahaemolyticus cultures (log K′CuL = 11.8–13.2). A strong correlation (r2 = 0.973) was found between total thiol and copper-complexing ligand concentrations at all copper concentrations examined.

A yearlong seasonal study was undertaken in a heavily polluted estuary to ascertain …


Geophysical Model Of The Cu-Mo Porphyry Ore Deposit At Copper Flat Mine, Hillsboro, Sierra County, New Mexico, Adrian Emmanuel Gutierrez Jan 2014

Geophysical Model Of The Cu-Mo Porphyry Ore Deposit At Copper Flat Mine, Hillsboro, Sierra County, New Mexico, Adrian Emmanuel Gutierrez

Open Access Theses & Dissertations

A 3D gravity model of the Copper Flat Mine was performed as part of the exploration of new resources in at the mine. The project is located in the Las Animas Mining District in Sierra County, New Mexico. The mine has been producing ore since 1877 and is currently owned by the New Mexico Copper Corporation, which plans o bringing the closed copper mine back into production with innovation and a sustainable approach to mining development. The Project is located on the Eastern side of the Arizona-Sonora-New Mexico porphyry copper Belt of Cretaceous age. Copper Flat is predominantly a Cretaceous …


Destruction Of Chlorinated Hydrocarbons By Zero-Valent Zinc And Bimetallic Zinc Reductants In Bench-Scale Investigations, Christopher Scott Cushman Jan 2014

Destruction Of Chlorinated Hydrocarbons By Zero-Valent Zinc And Bimetallic Zinc Reductants In Bench-Scale Investigations, Christopher Scott Cushman

Browse all Theses and Dissertations

Many remediation technologies have been developed to treat extensive subsurface contamination by chlorinated hydrocarbons (CHCs). One such technology is a permeable reactive barrier (PRB), which contains reactive media that acts as an electron donor in order to reduce CHCs. Extensive effort has been placed on finding the most suitable reactive media in PRBs, with zero-valent iron (ZVI) being the most commonly utilized media. However, zero-valent zinc (ZVZ) is a promising replacement for ZVI in PRBs as it will more readily donate electrons, resulting in more rapid degradation of CHCs. In addition, amending a secondary/catalytic metal to primary metal surface can …


Effects Of Salinity And Dissolved Organic Matter On Cu Toxicity To Americamysis Bahia In Estuarine Environments, Rabia Nasir Jan 2014

Effects Of Salinity And Dissolved Organic Matter On Cu Toxicity To Americamysis Bahia In Estuarine Environments, Rabia Nasir

Theses and Dissertations (Comprehensive)

As salinity increases the geochemical speciation of Cu is altered as a result of organic/inorganic complexation/competition. Such salinity changes may further challenge the osmoregulatory capabilities of euryhaline organisms. This chemical-biological interaction complicates the understanding of the impacts of Cu in estuarine waters. Dissolved organic matter (DOM) has been widely established to be an important modifier of Cu toxicity in freshwaters however its effectiveness in modulating Cu toxicity across the range of salinities that occur in estuarine conditions has not been studied in a systematic manner. Site to site differences in DOM quality with respect to the potential for toxicity mitigation …


The Impact Of Sulfide Mineral Weathering On The Isotopic Signatures Of Fe And Cu In Metal-Rich Streams, Ana Lourdes Gutierrez Jan 2011

The Impact Of Sulfide Mineral Weathering On The Isotopic Signatures Of Fe And Cu In Metal-Rich Streams, Ana Lourdes Gutierrez

Open Access Theses & Dissertations

The oxidative weathering of sulfide minerals, like pyrite, at the Earth's surface controls the formation of acid mine drainage sites as well as the Fe isotope composition of these areas and the main processes taken place. In this study, water and rock samples were collected from acidic drainages (most from abandoned mining sites) from the St. Juan Mountains in Colorado. The water samples were measured in-situ for dissolved oxygen, dissolved Fe(II), pH, and conductivity. Filtered acidified, unfiltered acidified, and Fe-oxide samples were analyzed for their metal concentrations. Ion-exchange chromatography was applied to both water and digested oxide fractions in order …


Chromium, Copper, And Arsenic Concentration And Speciation In Soil Adjacent To Chromated Copper Arsenate (Cca) Treated Lumber Along A Topohydrosequence, Donald Roy Schwer Iii Jan 2010

Chromium, Copper, And Arsenic Concentration And Speciation In Soil Adjacent To Chromated Copper Arsenate (Cca) Treated Lumber Along A Topohydrosequence, Donald Roy Schwer Iii

University of Kentucky Master's Theses

Arsenic (As), Chromium (Cr), and Copper (Cu) are ubiquitous in soils as a result of anthropogenic and geogenic processes. The fate of As, Cr, and Cu in the environment is largely governed by their speciation, which is influenced by soil physiochemical properties. This study investigated the influence of soil physiochemical properties and landscape position on As, Cr, and Cu concentration and speciation in soils adjacent to Chromated Copper Arsenate (CCA) treated lumber fence posts. Concentration gradients showed elevated total As and Cu adjacent to the three fence posts, which decreased with increasing distance from the posts. In addition, As and …


Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna Jan 2010

Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna

Open Access Theses & Dissertations

Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …


Copper Isotope Fractionation During Surface Adsorption And Intracellular Incorporation By Bacteria, Jesica Urbina Navarrete Jan 2010

Copper Isotope Fractionation During Surface Adsorption And Intracellular Incorporation By Bacteria, Jesica Urbina Navarrete

Open Access Theses & Dissertations

Copper isotopes may prove to be a useful tool for investigating bacteria-metal interactions recorded in natural waters, soils, and rocks. However, experimental data that constrain Cu isotope fractionation in biologic systems are limited and unclear. In this study we utilized Cu isotopes (65Cu) as a tool to investigate Cu-bacteria interactions, including surface adsorption and intracellular incorporation. Experiments were conducted with individual Gram-positive (Bacillus subtilis) and Gram-negative (Escherichia coli) bacterial species as well as with bacterial consortia from several natural environments. Adsorption experiments were conducted with live or dead cells over the pH range 2.5 to 6. Surface adsorption of Cu …


Investigations Of Grade Control, Macarthur Mine, Yerington, Nevada: An Oxidized Porphyry Copper System, Joseph Daniel Louis Lori Jan 2010

Investigations Of Grade Control, Macarthur Mine, Yerington, Nevada: An Oxidized Porphyry Copper System, Joseph Daniel Louis Lori

Open Access Theses & Dissertations

Supergene enriched, low-grade oxidized porphyry copper deposits are of great economic value. Oxidized porphyry sections are economic targets because even low-grade prospects have the potential to produce low-cost copper in an environmentally friendly fashion due to easy leachability and high recovery rates of the oxide mineralization. The MacArthur Mine, in the historic Yerington mining district of Nevada, is the focus of this study. The MacArthur is a tilted oxidized porphyry deposit, partially mined by open pit methods, hosted in the Jurassic Bear Quartz Monzonite of the Yerington batholith. The objective of the study is to define controls of copper oxide …


Oxidized Copper Mineralization Along The Continental Fault Near Butte, Montana, Theodore H. Eyde May 1955

Oxidized Copper Mineralization Along The Continental Fault Near Butte, Montana, Theodore H. Eyde

Bachelors Theses and Reports, 1928 - 1970

Located in the fault zone of the Continental fault near the western edge of Boulder batholith of southwestern Montana the oxidized copper deposits are developed by three open pit mines, one of which is a presently in operation. Copper has been deposited by descending cold solutions which have leached copper from the surrounding quartz monzonite and deposited within the crushed fault zone. Local high grade 'bunches' of ore occur along narrow limonite veins, remnants of primary sulfide veins which have been enriched by the descending cold solutions.


Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline Jun 1954

Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline

Bachelors Theses and Reports, 1928 - 1970

When a cold-worked metal is annealed, it’s physical properties hange as a result of a new grain structure. The annealing treatment is divided into three stages according to the changes that occur in the distorted metal: (1) recovery, (2) recrystallization, and (3) grain growth.


The Application Of Electric Energy To The Metallurgy Plants In Montana, Edwin J. Duncan Sep 1953

The Application Of Electric Energy To The Metallurgy Plants In Montana, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Since the year 1800, metallurgy has been affiliated with electricity. In fact, the two industries have grown side by side, being naturally dependent upon each other and having a parallel growth.


The Construction And Operation Of A Universal Specimen Mount With Protective Lead Shield For The Purpose Of Determining Pole Figures Using The Schulz-Decker Transmission Technique, Richard L. Fausner Jun 1953

The Construction And Operation Of A Universal Specimen Mount With Protective Lead Shield For The Purpose Of Determining Pole Figures Using The Schulz-Decker Transmission Technique, Richard L. Fausner

Bachelors Theses and Reports, 1928 - 1970

It was the purpose of this study to construct a universal mount, to construct a protective lead shield, to operate the instrument, and to provide a pole figure using the transmission method of Schulz and Decker. There are at present several lengthy x-ray methods of determining the grain orientation of metals. These methods are mainly photographic. In order to provide a rapid means of obtaining the necessary information concerning the grain orientation of a metal, a universal mount was constructed.


Host Rocks And Gangue Minerals Associated With Copper Deposits In Plutonic Igneous Rocks, Richard D. Montgomery May 1953

Host Rocks And Gangue Minerals Associated With Copper Deposits In Plutonic Igneous Rocks, Richard D. Montgomery

Bachelors Theses and Reports, 1928 - 1970

All of the information on the various districts has come directly from published reports. The investigation was suggested by Mr. Forbes Robertson. The geographical extent of the deposits was confined to the western United States. Many of these deposits are of the disseminated porphyry type. A few of the de­posits, such as at Butte, Montana, were of the fissure vein type.


The Effect Of Manganese On The Age Hardening Of Aluminum-Copper Alloys, Keith P. Burgess May 1953

The Effect Of Manganese On The Age Hardening Of Aluminum-Copper Alloys, Keith P. Burgess

Bachelors Theses and Reports, 1928 - 1970

It is known that age-hardening occurs in alloys of the solid solution type containing a hardening constituent, of a metal or metallic compound which is more soluble in the solvent phase at higher tempertures than at lower temperatures.


The Benefication Of A Low-Grade, Montana Scheelite Ore, Walter G. Parker May 1953

The Benefication Of A Low-Grade, Montana Scheelite Ore, Walter G. Parker

Bachelors Theses and Reports, 1928 - 1970

The increasing importance of tungsten as an industrial metal and the recent discoveries of extensive deposits of low-grade tungsten ores in Montana led to the investigation which is reported in this paper. The purpose of this investigation was to determine if a saleable concentrate could be obtained from one of these low-grade, Montana scheelite ores.


The Effect Of Ferric Iron Upon The Current Efficiency And The Deposition Of Copper In The Electrowinning Of Copper From Copper Sulphate Solutions, James L. Owings May 1952

The Effect Of Ferric Iron Upon The Current Efficiency And The Deposition Of Copper In The Electrowinning Of Copper From Copper Sulphate Solutions, James L. Owings

Bachelors Theses and Reports, 1928 - 1970

In the hydrometallurgy of copper, probably the most widely used method for the precipitation of copper is by electrolysis using insoluble anodes. The process is similar in many respects to the electrolytic refining of copper; one of the main differences is the use of insoluble anodes in electrowinning as compared to the use of impure copper anodes in electrorefining. Impurities, however, are common to both processes. The nature of these impurities differ and the problem of purifying the electrolyte is also different.


Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight May 1952

Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the fundamental magnetic characteristics of induction and hysteresis, for the alloy Cu2MnAl. This is a ternary, ferromagnetic Heusler alloy. The problem is not only to determine these characteristics for the alloy as-cast but to heat treat it and observe the manner in which different heat treat­ments affect these two fundamental magnetic characteristics.


An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson May 1952

An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson

Bachelors Theses and Reports, 1928 - 1970

Precipitation hardening alloys has assumed a major role in modern day development of alloys. In his search for stronger, harder materials, the metallurgist has often been limited by the cost of metals which posses the needed properties.


The Effect Of Iron Upon The Electrowinning Of Copper With An Amalgam Electrode, John A. Alexander May 1952

The Effect Of Iron Upon The Electrowinning Of Copper With An Amalgam Electrode, John A. Alexander

Bachelors Theses and Reports, 1928 - 1970

Current commercial use of the mercury cathode cell is limited to two types of electrolytic sodium cells-­the Castner cell and the Sorenson cell. Mercury as a cathode medium has also found application in polarographic analysis, a method of a simultaneous quantitative and qualitative analysis of several metal components of solution.


Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson May 1951

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.


Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson May 1951

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.


Ferromagnetic Alloys In The System Cu-Mn-Zn, W. Michael Yim May 1951

Ferromagnetic Alloys In The System Cu-Mn-Zn, W. Michael Yim

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine whether ferromagnetic alloys exist in the ternary sys­tem Cu-Mn-Zn analogous to the other Heusler alloys. The work in this thesis is a preliminary investi­gation on these alloys using a common metallographic re­search technique and augmented with X-ray methods.


The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster May 1951

The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster

Bachelors Theses and Reports, 1928 - 1970

Cadmium is produced solely as a by-product and all cadmium of commerce is obtained from zinc ores. It is a rare occurrence when zinc deposits are found which do not contain some cadmium.