Physical Sciences and Mathematics Commons^™

Sedimentary Provenance Of The Wedington Member, Fayetteville Shale, From Age Relations Of Detrital Zircons, William Tyson Cains

Graduate Theses and Dissertations

U-Pb geochronology of detrital zircons collected from the Chesterian Wedington Sandstone allows interpretation of sediment provenance and dispersal patterns in the southern midcontinent during the Late Mississippian. Detrital zircons analyzed from six samples of Wedington Sandstone yielded a final result of 565 concordant analyses used for interpretation. Results are plotted as Probability-Density Plots to interpret the spectrum of ages. Significant peaks occurred at 350-500 Ma, 950-1250 Ma, 1300-1500 Ma, 1600-1800 Ma, 1800-2300 Ma, and >2500 Ma. These peaks are interpreted as sourced by crystalline rocks within the Laurentian craton from Taconic-Acadian, Grenville, Midcontinent Granite-Rhyolite, Yavapai-Mazatzal, Paleoproterozoic, and Superior Provinces. The …

Bedrock Geological Map Of The Rockhouse Quadrangle, Carroll And Madison Counties, Arkansas, Douglas Eben Jones

Graduate Theses and Dissertations

A digital geologic map of the Rockhouse quadrangle, Carroll and Madison counties, Arkansas, was created on a 1:24,000 scale using ArcMap 10 and Photoshop CS4. The data obtained in the field are digitized onto the United States Geological Survey (USGS) digital raster graphic (DRG) of the Rockhouse quadrangle. The geology in the Rockhouse quadrangle consist entirely of sedimentary rocks that are Paleozoic ranging from Lower Ordovician to Mississippian in age. The Ordovician System is represented by the Cotter, Powell, Everton, and St. Peter Formations. The Cotter and Powell are the prominent bluff forming units throughout the quadrangle and along the …

Hydrogeology And Chemical Characterization Of Hydrocarbon In Domestic Water Wells, Rancho Villa Subdivision, Rogers, Arkansas, Janelle Renee Sherman

Graduate Theses and Dissertations

This project is centered on the Rancho Villa community in Rogers, Arkansas where several residents have had hydrocarbon contamination in their domestic water wells. The goal of this project was to understand the hydrogeology in the study area, characterize the contaminant chemically, and determine the source of the contaminant. The hydrogeology of the area was determined from previous theses. Seventeen samples were taken from the wells in the Rancho Villa community; each sample was analyzed for geochemical parameters and by Gas Chromatography/Mass Spectrometry (GC/MS) for organic compounds analysis. Four of the 17 samples had a visible non-aqueous layer of hydrocarbon …

Infrared Spectra Analysis Of Thermally Altered Iron Phyllosilicates And The Implications For Mars, William Thomas Bryan

Graduate Theses and Dissertations

This study looks at two iron-rich phyllosilicates, which may be present on Mars. The minerals, greenalite and hisingerite, are rich in iron-II and iron-III, respectively. Small samples (~0.40 grams) of each mineral were crushed and heated in a Lindberg Tube Oven for approximately twenty-four hours at temperatures selected to mimic lava flows and impact events. Following heating, each sample was placed in a Fourier Transform Infrared (FT-IR) spectrometer to collect the near- and mid-infrared spectra. The spectra allowed for these terrestrial analogs to be analyzed with regards to how their structure breaks down with increasing temperature. The samples' colors were …

A Survey Of Heavy Metals In Water, Soil And The Surrounding Plants In The Lower Rio Grande Valley, Erving W. Morelius

Theses and Dissertations - UTB/UTPA

Heavy metal pollution of the environment in recent years has become a major issue of importance for both human and environmental health. Samples were investigated for the potential pollution of the area as it is a vital produce producing area. During the study plant, soil and water samples were collected from the Donna Reservoir and Canal System to test the concentration of various heavy metals. The heavy metals tested included both potentially toxic and micronutrients in the samples which included arsenic, cadmium, chromium, copper, iron, lead, nickel and sulfur. During the study, a sixty day sampling period was used to …

Peridynamic Modeling Of Coupled Mechanical Deformations And Transient Flow In Unsaturated Soils, Rami Jabakhanji

Open Access Dissertations

A coupled peridynamic model for mechanical deformations and transient moisture flow in unsaturated soils is developed. The model is capable of simulating the emergence and evolution of cracks triggered by volumetric strains in the soil which are associated with changes in moisture content. The development of our model is motivated by the need for a tool to analyze and evaluate the impact of dessication cracks on the movement of moisture and the mechanical properties of soils at the field scale. The model is based on the peridynamic reformulation of elasticity proposed by Silling for simulating the deformation of bodies with …

The Mechanism And Timescales Of Soil Formation In The Hyper-Arid Atacama Desert, Chile, Fan Wang

Open Access Dissertations

The planetary surfaces that evolve in the near absence of water are strikingly different from surfaces where water is abundant, but their formation is poorly documented. This research is an in-depth exemplary work in the Atacama Desert in northern Chile to understand the soil formation in hyper-arid environments, as an analog for planetary surfaces such as the Mars. In detail, the basic mechanism regarding the source material, timescale, paleo-climatic settings and the role of crypto-biotic crusts have been investigated to constrain the Atacama soil development.

The geochemical, isotopic and mineralogical composition of atmospheric dust deposited along a West-East transect in …

The Formation Of Distal Impact Ejecta, Brandon C. Johnson

Open Access Dissertations

Here we present two models for the dynamics of ejection and formation of distal impact ejecta. The first model focuses on the most highly shocked material that forms a massive expanding vapor plume or fireball. In this model molten droplets or spherules condense from the vapor. We model the expanding vapor plume using a one dimensional Lagrangian hydrocode. The condensation of droplets is treated by directly coupling the equations for homogeneous nucleation and growth with our hydrocode. The second model is focused on less energetic material ejected as part of the excavation flow. Using the iSALE hydrocode, we determine the …

Observation-Based Algorithm Development For Subsurface Hydrology In Northern Temperate Wetlands, Chun-Mei Chiu

Open Access Dissertations

This study investigates wetland subsurface hydrology, as well as biogeochemistry - which is strongly influenced by water and temperature dynamics - as these interactions are expected to be highly significant, yet remain poorly represented in current ecosystem and climate models.

Northern wetlands have received widespread public attention due to steadily increasing summer mean global temperatures, extreme precipitation events and higher rates of natural greenhouse gas emissions, as well as the significant impacts on them due to human activities. The goal of my graduate research has been to improve quantification of the role of subsurface hydrology in northern wetlands by using …

A Geomechanical Study Of The Mississippian Boone Formation, Karen Nicole Mason Buckland

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas is a chert-limestone sequence analogous to the subsurface Mississippi Lime reservoir in parts of Oklahoma and Kansas. It has low permeability and produces via horizontal drilling and hydraulic fracturing. The response to stimulation by fracturing is dependent on the quantity of chert in the area. Chert nodules and laterally extensive chert layers in the sequence are variable. Locally, cm- to dm-scale chert bedding is continuous and comprises up to 50% of the outcrop. Elsewhere, the chert is nodular and intermittent.

Samples collected from representative outcrops spanning the thickness and aerial extent of the formation …

Insights Into The Timing, Origin, And Deformation Of The Highland Mountains Gneiss Dome In Southwestern Montana, Usa, Lane Markes Boyer

Graduate Theses and Dissertations

The Highland Mountains of southwestern Montana offer a unique view of the Archean igneous and metamorphic rocks within the Great Falls tectonic zone (GFTZ). A Paleoproterozoic structural gneiss dome has been interpreted in the southern extent of the Highland Mountains. The ∼ 130km² of exhumed metamorphic rocks and gneiss dome exposed in the Highland Mountains are the primary focus of this research. The formation of the Highland Mountains gneiss dome is proposed to be directly related to a northwest-side down detachment (the Steels Pass shear zone) that formed during terrane collision along the GFTZ. The field investigation determined foliation …

Analysis Of Tripolitic Chert In The Boone Formation (Lower Mississippian, Osagean), Northwest Arkansas And Southwestern Missouri, Paul Marchand Minor

Graduate Theses and Dissertations

The Boone Formation in northwest Arkansas and southwestern Missouri exposes a nearly complete sequence of Lower Mississippian chert-bearing carbonates deposited by a single 3rd order transgression and regression. An abundant amount of chert that has replaced limestone highlights the Boone, but little is understood about the timing and development of chert in Lower Mississippian carbonates. Interpretation of the diagenetic history of the chert, in particular tripolite, has significant implications beyond the outcrop. Determining the origin, timing, and extent of tripolitic chert in the Lower Mississippian System improves reservoir characterization in subsurface petroleum reservoirs in the mid-continent that are laterally equivalent …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Subsurface Stratigraphy And Characterization Of Mississippian (Osagean To Meramecian) Carbonate Reservoirs Of The Northern Anadarko Shelf, North-Central Oklahoma, Brett Robert Wittman

Graduate Theses and Dissertations

Mississippian carbonate strata of the midcontinent contain prolific oil and gas reservoirs. Production from these carbonates has been primarily from two reservoir types, the Mississippi "chat" and recently denser chert-rich mudstone intervals. The"chat" interval is a high porosity chert residuum associated with the both the Osagean and basal Pennsylvanian unconformity. The distribution of the "chat" reservoir is discontinuous and heterogeneous. Recent horizontal drilling successes have reinvigorated academic and industry interest in the Lower Mississippian. Much of the activity is now targeting lower porosity, cherty, mudstone intervals of the Reeds Spring and Cowley Formations, which were previously considered to be non-economic. …

Classification Of Satellite Time Series-Derived Land Surface Phenology Focused On The Northern Fertile Crescent, Brian Embree Bunker

Graduate Theses and Dissertations

Land surface phenology describes events in a seasonal vegetation cycle and can be used in a variety of applications from predicting onset of future drought conditions, to revealing potential limits of historical dry farming, to guiding more accurate dating of archeological sites. Traditional methods of monitoring vegetation phenology use data collected in situ. However, vegetation health indices derived from satellite remote sensor data, such as the normalized difference vegetation index (NDVI), have been used as proxy for vegetation phenology due to their repeated acquisition and broad area coverage. Land surface phenology is accessible in the NDVI satellite record when images …

Litter Conditioning Is Differentially Affected By Leaf Species, Phosphorus Enrichment, And Light Availability, Erin E. Scott

Graduate Theses and Dissertations

Anthropogenic enrichment of nitrogen and phosphorus is one of the most pervasive and detrimental threats to aquatic ecosystems worldwide. In streams that rely on allochthonous basal food resources, such as leaves, nutrient pollution can result in altered food quality and decreased carbon (C) standing stocks. However, the magnitude and mechanisms of this change in quality are poorly understood. Laboratory microcosm studies were conducted to 1) quantify the response of litter C:P to a gradient of phosphorus (P) enrichment (0, 0.05, and 0.5 mg SRP/L) across leaf species with variable levels of degradability (sugar maple and oak), and 2) quantify the …

Geophysical Surveys And Archaeological Insights At Fort Pierre Chouteau A Frontier Trading Post On The Middle Missouri, Margaret Maurine Patton

Graduate Theses and Dissertations

Fort Pierre Chouteau in present day South Dakota was the most important fur trading post of the American Fur Company in the 1830s, serving as a regional hub for the fur trade. The Fort was sold to the U.S. Military in 1855 for use as a base in the Sioux Wars but was abandoned in 1856. Geophysical surveys and previous excavations indicate evidence of both occupations. Geophysics is an important tool for determining the extent of archaeological sites, yet the relationships between geophysical anomalies and excavation features may not be readily evident. Initial geophysical surveys (Kvamme 2007) were completed to …

Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour

Graduate Theses and Dissertations

The main objectives of this thesis are to estimate Mg isotopic compositions of the Moon and achondrites, to understand the behavior of Mg isotopes during magmatic differentiation processes in different planetary bodies, and to evaluate the extent of Mg isotopic heterogeneity in the solar system. In order to achieve these goals, Mg isotopes have been measured for 47 well-characterized lunar samples and 22 differentiated meteorites by MC-ICPMS. The limited Mg isotopic variations among mare and highland regolith, mare breccias, and highland impact-melt rocks reflect negligible Mg isotope fractionation during lunar surface processes (e.g. solar wind, cosmic rays, micrometeorite bombardments, meteorite …

An Evaluation Of Spatial Variability Of Water Stress Index Across The United States: Implications Of Supply And Demand In The East Vs The West, Jennifer Ann Roath

Open Access Theses

In order to support both human and environmental needs, high quality fresh water must be available when and where it is required. As a metric for indicating unsustainable water usage, WSI is only useful when the values reflect accurate interactions between supply and demand; however, the complexity of temporal and spatial variability of available fresh water complicates the analysis of water stress.

The overall goal of this project was to investigate the spatial variability of water stress across the United States and the appropriate spatial scale for management decisions. To accomplish this, a national dataset describing spatial distribution and breakdown …