Physical Sciences and Mathematics Commons^™

Do Mitigated Wetlands Support Similar Small Mammal Communities As Natural Wetlands?, Krista Noe, Mack Frantz, Christopher T. Rota, Jim Anderson

Presentations

Wetlands provide many ecosystem services and play an important ecological role in wildlife communities. Although wetland mitigation is a standard tool to combat losses to natural wetlands, it is essential to understand if mitigated wetlands are truly replacing natural wetlands in their full capacity. Because one important role of wetlands is to provide habitat for wildlife communities, it is important to determine if these created or restored wetlands can foster a wildlife community that is similar to natural wetlands. One understudied taxa in the realm of wetland mitigation research is small mammals. Our objectives are to examine community composition, occupancy, …

Relating Recharge Mechanisms To Dissolved Inorganic Carbon Dynamics In An Updip Appalachian Coal Mine Discharge, Matthew L. Bell

Presentations

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine dissolved inorganic carbon chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia. Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. …

Comparison Of Methods For Estimating Carbon Evasion And Export Associated With A Coal Mine Discharge, Kyle Lee, Dorothy J. Vesper

Presentations

The evasion of CO2 from terrestrial waters plays a role in the global cycling of carbon but there are few datasets that have an accurate accounting of the flux. It has been shown that discharges from coal mines can have elevated concentrations of CO2 due to sulfuric acid-driven dissolution of carbonate rock. In this study, we compared three methods for calculating the export dissolved inorganic carbon (DIC) and the evaluation of CO2 from an abandoned-mine discharge in West Virginia. In Method #1, the source flux is calculated from the discharge and the concentrations at the portal. In Method #2, the …

Quantifying The Contribution Of Solid Precipitates To The Total Alkalinity In A Coal-Mine Discharge, Lili Lei, Dorothy Vesper

Presentations

Flocculates and precipitates from coal mine drainage (CMD) are an integral part of the geochemical setting in mining-impacted streams. The precipitates may be very small, amorphous, and, depending on their chemistry, play a role in the storage and release of alkalinity. To evaluate the potential impact of CMD-solids on alkalinity, we conducted various tests using model and natural solids. Laboratory measurements of alkalinity are operationally defined by a titration to a fixed pH. When the solid-solution mixtures were tested using the standard alkalinity measurement method, no alkalinity could be detected; however, a possible reason for that was that the standard …

Development Of A Python Library To Facilitate Wqx Dataset Exchanges, Jonathan Musselwhite, Fernando Rojano

Presentations

The assistance of programming tools to speed up the exchange of water quality datasets are necessary. These tools reduce and simplify the steps currently needed to transfer datasets from water quality monitoring stations to public databases. Here it is presented a library developed in Python that programmatically covers the steps related to the upload of datasets following the framework of the Water Quality Exchange (WQX) of the US EPA. This library is mainly characterized by its ability to efficiently connect and transfer data formatted as CSV or XLSX files via the WQX to the National STORET Data Warehouse by mostly …

Functionalized Polycarbonate Commercial Filters For Water Purification, Jeremy Mccloud, Ashton Caruthers, Kennedy Shoults, Rick Sharpe, Sean P. Mcbride

Presentations

Can commerercially available filtration membranes be easily functionalized in such a way to enhence the removal the charged contaminants in the water treatment process? The literature demonstrates there have been two pioneering works that demonstrated that Ultrathin Self-Assembled Nanoparticle (USANP) membranes (composed of ~5 nm diameter metallic gold nanoparticles surrounded by organic ligands) when applied to commercial membranes displayed charge sensitive rejection to molecular dyes and also have the ability to charge modify the openings in commercial filters. The rejection mechanisms in these works are proposed to be either size dependent or charged based. Recent experimental results have demonstrated that …

Evaluating Impacts Of Anthropogenic Disturbance To Wetland Water Quality Functions, Sindupa De Silva, Jim Anderson, Jason A. Hubbart, Michael P. Strager, Elliott Kellner, Christopher T. Rota, Elizabeth A. Byers

Presentations

Wetland ecosystems play fundamental roles in regulating our freshwater resources, yet they are not comprehensively protected from degradation and loss. West Virginia, USA has wetlands across diverse landscapes and geography that feed into both the Chesapeake Bay and Gulf of Mexico. The state is also comprised of diverse anthropogenic land-use practices. We are assessing 200 wetlands over 2 years to evaluate how anthropogenic disturbance impact wetland water quality functions. Select water quality parameters (20), and relative diversity and abundance of vegetation and macroinvertebrates will be used as bioindicators. They will be compared with GIS assessments of watershed land cover/ land-use …

Boulders As A Lithologic Control On River And Landscape Response To Tectonic Forcing At The Mendocino Triple Junction, Charles Shobe, Georgina Bennett, Gregory Tucker, Kevin Roback, Scott Miller, Joshua Roering

Faculty & Staff Scholarship

Constraining Earth’s sediment mass balance over geologic time requires a quantitative understanding of how landscapes respond to transient tectonic perturbations. However, the mechanisms by which bedrock lithology governs landscape response remain poorly understood. Rock type influences the size of sediment delivered to river channels, which controls how efficiently rivers respond to tectonic forcing. The Mendocino triple junction region of northern California, USA, is one landscape in which large boulders, delivered by hillslope failures to channels, may alter the pace of landscape response to a pulse of rock uplift. Boulders frequently delivered by earthflows in one lithology, the Franciscan mélange, have …

The Role Of Infrequently Mobile Boulders In Modulating Landscape Evolution And Geomorphic Hazards, Charles M. Shobe, Jens M. Turowski, Ron Nativ, Rachel C. Glade, Georgina L. Bennett, Benedetta Dini

Faculty & Staff Scholarship

A landscape’s sediment grain size distribution is the product of, and an important influence on, earth surface processes and landscape evolution. Grains can be large enough that the motion of a single grain, infrequently mobile in size-selective transport systems, constitutes or triggers significant geomorphic change. We define these grains as boulders. Boulders affect landscape evolution; their dynamics and effects on landscape form have been the focus of substantial recent community effort. We review progress on five key questions related to how boulders influence the evolution of unglaciated, eroding landscapes: 1) What factors control boulder production on eroding hillslopes and the …

Soil Response Of Helicopter Liming In The Monongahela National Forest, Jarrett Douglas Fowler

Graduate Theses, Dissertations, and Problem Reports

Soils in the Monongahela National Forest (MNF) are acidic due to sandstone parent material, acid deposition, uptake of base cations by vegetation, and release of organic acids by organic matter (OM) decomposition. Increases in soil acidity have caused declines in forest health and changed species composition and nutrient status. Liming can neutralize soil acidity, but no large-scale liming projects have been done on acid forest soils in the USA. In anticipation of acquiring funding for a proposed liming project in the MNF, in 2007 and 2009 10 sites were selected to sample and analyze soils before lime was applied. In …

Petrographic And Core Analysis Of The Jurassic Norphlet Formation: A Case Study In The Lithofacies Control Of Diagenesis And Porosity In The Flomaton Field, Al, Jarrett Thomas Smith

Graduate Theses, Dissertations, and Problem Reports

This study includes a sedimentologic and petrographic study of cores and thin-sections from the Jurassic Norphlet Formation in the Flomaton Field in southern Alabama to define a specific paragenetic history of each facies encountered and to identify key controls on reservoir quality. Eolian dune, nearshore, sand flat, and wadi facies were likely encountered in Norphlet core and thin-section samples that displayed a high degree of heterogeneity between them in terms of porosity, grain contacts, cement abundance/type, intergranular volume, and overall diagenetic processes. These distinct petrographic differences suggest that the paragenesis in the Flomaton Field is primarily facies controlled. The eolian …

Application Of 3d Seismic Signal And Geomechanical Attributes For Subsurface Fracture Characterization: A Case Study In Clearfield County, Central Pennsylvania, Iman F. Zulkapeli

Graduate Theses, Dissertations, and Problem Reports

Hydrocarbon exploration in unconventional reservoirs is highly risky due to the nature of the reservoirs and the variability in fractures and reservoir geomechanical properties in the subsurface. The reservoir needs to be fully characterized to avoid any complication such as frac hit, wellbore failure, blowout, or even a dry hole. The Clearfield reservoir produces an exceptionally low amount of gas, compared to the neighboring region in the proximity, which has been poorly understood. This raises the question as to what causes the reservoir to have low productivity.

This study focuses on the natural fracture characterization using high-quality 3D seismic signal …

Refining The Sedimentology And Geochemistry Of The Mid-Permian Blaine Formation Of The Rebecca K. Bounds Core From Greeley County, Kansas, Brigitte Petras

Graduate Theses, Dissertations, and Problem Reports

Red siliciclastics and evaporites of Permian Nippewalla Group in mid-continental US were deposited in western equatorial Pangea. Previous studies of these rocks record Permian air temperatures as high as 73 °C, saline lake waters with a pH as low as ~1, and sedimentology that shows arid conditions. This current study conducts detailed sedimentological observations and geochemical analyses of the Blaine Formation of the Nippewalla Group. The Rebecca K. Bounds core from west-central Kansas is used to interpret the depositional environments and diagenetic history of the Blaine Formation.

The lithologies of the Blaine Formation, listed in order of most to least …

Variations In Produced Water Chemistry And Relation To Regional Geology And Production In The Marcellus Shale, Northcentral West Virginia, Jonathan M. Brady

Graduate Theses, Dissertations, and Problem Reports

An investigation of 74 Marcellus Shale wells across northcentral West Virginia indicates changes in produced water chemistry and quantity can be related to geologic conditions based on well logs and core data. These changes are determined by reviewing multiple produced water analyses for individual wells for periods up to ten years. Results show variations among the areas in this study. From west to east across central Harrison County to central Taylor County, then north into Monongalia County, gamma-ray logs show increasing intensity, especially in the middle and lower Marcellus. XRD mineralogy from core data shows increasing clay content from west …

Effect Of Oxidative Breakers On Organic Matter Degradation, Contaminant Mobility And Critical Mineral Release During Shale-Fracturing Fluid Interactions In The Marcellus Shale, Shaun Donmoyer

Graduate Theses, Dissertations, and Problem Reports

Production of oil and gas from organic-rich shale formations has become viable through advancements in multi-stage hydraulic fracturing. The decline of shale gas production after the initial days of fracturing operations coupled with falling oil and gas prices, has pushed industry operators to use new chemical additives as an attempt to increase hydrocarbon production. The implementation of highly reactive fracturing fluids that include strong oxidizing agents, pose as a potential solution to increase well productivity. Strong oxidizing chemicals commonly known in fracturing operations as breakers, are used to improve the viscosity of gel-based fluids after the proppant is transported into …

A Snapshot Of Ancient Microbial Life: Microorganisms And Organic Compounds In Primary Fluid Inclusions In Bedded Halite, Neoproterozoic Browne Formation Of Central Australia, Sara I. Schreder-Gomes

Graduate Theses, Dissertations, and Problem Reports

Modern shallow brine environments contain an abundance of microorganisms. Microorganisms, mineral crystals, and air bubbles can be trapped with those brines in primary fluid inclusions in bedded halite as it grows in shallow saline surface waters. Primary fluid inclusions and their contents can be preserved, unaltered, for millions of years.

The ~830 million-year-old Browne Formation of central Australia contains intervals of bedded halite with unaltered primary fluid inclusions. Intervals of bedded halite were sampled in the Empress 1A core from ~1480 m – 1520 m depths. Here, I used petrography to describe suspect microorganisms and organic compounds that were trapped …

Independent, Semi-Automated Classification Of Petrographic Features In Volcanic Rocks Using Fiji And Weka, Holly Danielle Pettus

Graduate Theses, Dissertations, and Problem Reports

Traditional methods of collecting quantitative petrographic data from thin sections (modal mineralogy, size distribution, shapes, etc.) are time- and labor-intensive, and rarely have sample sizes adequate to statistically describe complex rocks (i.e. volcanic rocks). Although manual counting and measurements are now routinely supplemented by digital image analysis, the majority of quantitative petrographic studies still go through a manual digitization stage where object classes are traced before further analyses. This is a major rate-limiting step that reproduces the same problems of small n-values resulting from significant effort. We have valuated the potential and limitations of using the Trainable Weka Segmentation (TWS) …

Regional Correlation And Depositional History Using Well Log And Core Data Of The Middle Devonian Marcellus Poseidon 8m Well, Westmoreland County, Pennsylvania, Usa, Emily R. Jackson

Graduate Theses, Dissertations, and Problem Reports

The Marcellus Shale is the largest natural gas producing formation in the Appalachian basin, and as such, presents a unique opportunity for continued research on an area that is critical to meeting the energy needs of the current society. Although the Marcellus has historically been extensively researched, acquisition of well log and core data from the Marcellus Poseidon 8M well in Westmoreland County, PA, allows for application of a new method of data integration, which was utilized in this project to specifically understand the depositional environment and create a correlation with other study wells throughout the basin. This integration was …

Reservoir Characteristics And Lateral Variability Of The Marcellus Formation At The Allegheny Mountain Front, Bruno J. Abersold

Graduate Theses, Dissertations, and Problem Reports

The Marcellus Formation, a large shale gas reservoir located within in the Appalachian basin, produces the energy that fuels the economy across the United States. Well data and rock core for the Coastal 1H well, found in Fayette County, Pennsylvania, provides the basis to understand reservoir characteristics and depositional processes of the Marcellus Formation across the basin. The well is located near along the eastern edge of the productive fairway and adjacent to the Allegheny mountain front. We used characteristics, such as total organic carbon (TOC), geomechanical properties, and lithology, to integrate with ten other available wells across the basin. …

The Impact Of Unsaturated Zone Thickness On The Severity Of Saltwater Intrusion In Coastal Aquifers From Overtopping, Dennis Jesse Carpinello

Graduate Theses, Dissertations, and Problem Reports

Storm-surge inundation and wave overwash, collectively overtopping, causes the land surface to be inundated with seawater, resulting in vertical infiltration of saline waters into underlying coastal aquifers, which can have severe consequences on freshwater resources. Unsaturated zone thickness plays an important role in determining the severity of saltwater contamination resulting from an overtopping event. This study uses numerical modeling to investigate vertical saltwater infiltration and salinization, and the subsequent aquifer recovery to overtopping events for coastal aquifers with different unsaturated zone thicknesses. Groundwater models were developed using the numerical code SUTRA to solve saturated-unsaturated, density-dependent groundwater flow and solute …

Evaluation Of A Low-Cost Uas And Phenocams For Measuring Grapevine Greenness, Timothy J. Hoheneder

Graduate Theses, Dissertations, and Problem Reports

Unpersoned aerial systems (UAS) could provide winegrowers with the potential to monitor vineyard productivity with ultra-high-resolution imagery and low operational costs. This ability could prove particularly valuable in the challenging cool-climate viticultural areas of Appalachia. Especially in this mountainous region of increasingly variable microclimates, there could be of great value from an ability to use UAS-measured greenness to monitor wine grape phenology and predict harvest quality and quantity. In this study, I assess how UAS-measured greenness relates to three complementary measures of field-based: leaf angle measurements, phenocam measured greenness, and leaf spectral measurements of greenness. After correlating these field-based measures …

Estimating The Azimuthal Mode Structure Of Ultra Low Frequency Waves And Its Effects On The Radial Diffusion Of Radiation Belt Electrons, Mohammad Barani

Graduate Theses, Dissertations, and Problem Reports

Characterizing the azimuthal mode number 𝑚 of Ultra Low Frequency (ULF) waves is critical to quantifying the radial diffusion of radiation belt electrons. A Wavelet cross-spectral technique is applied to the compressional ULF waves observed by multiple pairs of GOES and MMS satellites to estimate the mode structure of ULF waves. A more realistic distribution of mode numbers is achieved by inclusion of the modes corresponding to different wave propagation directions as well as at 𝑚 higher than fundamental mode number. For the event study of a geomagnetic storm using GOES data, ULF wave power is found to dominate at …