Physical Sciences and Mathematics Commons^™

Distribution And Impacts Of Petroleum Hydrocarbons In Louisiana Tidal Marsh Sediments Following The Deepwater Horizon Oil Spill, Rachel S. Hatch

Theses and Dissertations--Earth and Environmental Sciences

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide ²³⁴Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using ²¹⁰Pb, with verification from ¹³⁷Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon …

Shear-Wave Imaging And Birefringence In A Complex Near-Surface Geological Environment, Ali Z. Almayahi

Theses and Dissertations--Earth and Environmental Sciences

Multiple geophysical and geological data sets were compiled, reprocessed, and interpreted using state-of-the-art signal processing and modeling algorithms to characterize the complex post-Paleozoic geology that overlies the southwestern projection of the Fluorspar Area Fault Complex (FAFC) in western Kentucky. Specific data included 21.5 km of SH-wave seismic reflection, 1.5 km of P-wave seismic reflection, 2 km of electrical resistivity, vertical seismic profiles, Vp and Vs sonic-suspension logs, and 930 lithologic borehole logs. The resultant model indicates three general northeast–southwest-oriented fault zones pass through the study area as southwestern extensions of parts of the FAFC. These fault zones form two significant …

Managing Soil Microbial Communities With Organic Amendments To Promote Soil Aggregate Formation And Plant Health, Shawn T. Lucas

Theses and Dissertations--Plant and Soil Sciences

The effects of managing soil with organic amendments were examined with respect to soil microbial community dynamics, macroaggregate formation, and plant physio-genetic responses. The objective was to examine the possibility of managing soil microbial communities via soil management, such that the microbial community would provide agronomic benefits. In part one of this research, effects of three amendments (hairy vetch residue, manure, compost) on soil chemical and microbial properties were examined relative to formation of large macroaggregates in three different soils. Vetch and manure promoted fungal proliferation (measured via two biomarkers: fatty acid methyl ester 18:2ω6c and ergosterol) and also stimulated …

Modeling Of Co2-Water-Rock Interactions In A Mississippian Sandstone Reservoir Of Kentucky, Anne M. Schumacher

Theses and Dissertations--Earth and Environmental Sciences

This study examined CO₂-water-rock interactions occurring during a carbon sequestration pilot test into a Mississippian oil reservoir in western Kentucky. New samples (n=62) and archived data, both collected from oil wells, were used to characterize the chemistry of formation waters from the Sugar Creek field in Hopkins County. In addition, core and cuttings samples (n=17) from the reservoir and overlying cap-rocks in, or near, the field were analyzed for bulk and clay mineralogy using X-ray diffraction. Electric logs were used to select sample intervals within the overlying cap-rocks and the center of the producing zones in the Jackson …

Spatio-Temporal Variability In Groundwater Discharge And Contaminant Fluxes Along A Channelized Stream In Western Kentucky, Ganesh N. Tripathi

Theses and Dissertations--Earth and Environmental Sciences

Spatio-temporal variability in groundwater discharge and contaminant fluxes along a channelized stream in western Kentucky

Surface and groundwater discharges and contaminant fluxes can vary with time and space depending upon the hydrogeological processes and geological setting of the area of interest. This study examined a ~300-m-long, channelized reach of a first-order perennial stream, Little Bayou Creek, in the Coastal Plain of far western Kentucky during the period October 2010–February 2012. Along the study reach, springs discharge groundwater contaminated by the chlorinated organic compound trichloroethene (TCE) and radionuclide technetium-99 (⁹⁹Tc) released as a result of past activities at the …

Factors Influencing The Establishment And Survival Of Native Hardwood Tree Seedlings Of The Kentucky Inner Bluegrass Blue Ash-Oak Savanna-Woodland, James D. Shaffer

Theses and Dissertations--Biology

Historically, the Kentucky Inner Bluegrass blue ash-oak savanna-woodland was the primary ecosystem of the Inner Bluegrass Region (IBR) of Kentucky. After European settlement, the majority (>99%) of Bluegrass savanna was converted to agricultural and urban land uses. Currently remnant savanna tree species are failing to recruit. Therefore, a long-term restoration ecology project researching competition and disturbance on seedling establishment, survival, and growth has been established at Griffith Woods (the largest remaining savanna in Kentucky) in Harrison Co., KY. Fourteen native hardwood tree species (a total of 6,168 seedlings) have been experimentally planted. Light, soil, surrounding vegetation, and herbivory, factors …

Thermobarometry Of Metamorphosed Pseudotachylyte And Determination Of Seismic Rupture Depth During Devonian Caledonian Extension, North Norway, Susan E. Leib

Theses and Dissertations--Earth and Environmental Sciences

Crustal faulting has long been known as the source of shallow seismicity, and the seismogenic zone is the depth (3-15 km) within the crust that is capable of co-seismic slip, largely under brittle conditions. However, some continental seismicity occurs at depths >> 15 km. I performed thermobarometry of mylonitic pseudotachylyte to determine the P-T of a seismogenic extensional fault in the Caledonian Norwegian margin. Two shear zones (Eidsfjord and Fiskfjord) located in northern Norway exhibit brittle extension propagating into the ductile regime of the lower crust as evidenced by the presence of pseudotachylyte. Averages from Eidsfjord (653 ± 38°C and 570 …

Abiotic Nitrate And Nitrite Reactivity With Iron Oxide Minerals, Prakash Dhakal

Theses and Dissertations--Plant and Soil Sciences

Under iron (Fe³⁺)-reducing conditions where aqueous Fe²⁺ and unreduced solid Fe³⁺-oxides commonly coexist, soil Fe²⁺ oxidation has been shown to be coupled with nitrate (NO₃^-) reduction. One possible secondary reaction is the involvement of NO₃^- and nitrite (NO₂^-) with Fe-oxide minerals found in many natural environments. Yet, spectroscopic measurements and kinetic data on reactivity of NO₃^- and NO₂^- with Fe-containing oxide minerals such as goethite (a-FeOOH), and magnetite (Fe₃O­₄) are not found in the literature. The reactivity of …

Predicting The Dynamic Behavior Of Coal Mine Tailings Using State-Of-Practice Geotechnical Field Methods, Ali Salehian

Theses and Dissertations--Civil Engineering

This study is focused on developing a method to predict the dynamic behavior of mine tailings dams under earthquake loading. Tailings dams are a by-product of coal mining and processing activities. Mine tailings impoundments are prone to instability and failure under seismic loading as a result of the mechanical behavior of the tailings. Due to the existence of potential seismic sources in close proximity to the coal mining regions in the United States, it is necessary to assess the post-earthquake stability of these tailings dams.

To develop the aforementioned methodology, 34 cyclic triaxial tests along with vane shear tests were …

Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines

Theses and Dissertations--Biosystems and Agricultural Engineering

Human activity such as surface mining can have substantial impacts on the natural environment. Performing a Cumulative Hydrologic Impact Assessment (CHIA) of such impacts on surface water systems requires knowing the location and extent of these impacted streams. The Jurisdictional Determination (JD) of a stream’s protected status under the Clean Water Act (CWA) involves locating and classifying streams according to their flow regime: ephemeral, intermittent, or perennial. Due to their often remote locations and small size, taking a field inventory of headwater streams for surface mining permit applications or permit reviews is challenging. A means of estimating headwater stream location …

Transformations, Bioavailability And Toxicity Of Manufactured Zno Nanomaterials In Wastewter, Sewwandi Rathnayake

Theses and Dissertations--Plant and Soil Sciences

In order to properly evaluate the ecological and human health risks of ZnO Manufactured nanomaterials (MNMs) released to the environment, it is critical to understand the likely transformation products in the wastewater treatment process and in soils receiving biosolids. To address this critical knowledge gap, we examined the transformation reactions of 30 nm ZnO MNMs in single component and multi-component systems, with phosphate and natural organic matter (NOM). We also assessed the influence of nano ZnO transformation on the bioavailability, and toxicity of ZnO transformation products to Triticum aestivum. The data revealed that ZnO MNMs react with phosphate at …

Modeling Bedrock Mining Hotspots Within The Ouachita National Forest, Arkansas, Stephanie H. Mehlhope

Theses and Dissertations--Geography

This study, concentrating on the Ouachita Mountain Range in western-central Arkansas, extends prior work on treethrows and their influence on soil development in the region by supplying a method of determining hotspots of bedrock mining by treethrow. Binary logistic regression analysis was employed to determine the abiotic and biotic factors that are highly correlated with the rate of bedrock detachment found in uprooted rootwads from three study sites within the Ouachita National Forest. The produced logistic regression models suggest topographic factors, tree specific characteristics, as well as the local geology and soil characteristics all have a significant effect upon the …