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Full-Text Articles in Physical Sciences and Mathematics
Unraveling The Fingerprints Of Nox Using Stable Isotopes: Implications For Nox Source Partitioning And Oxidation Chemistry, Wendell William Walters
Unraveling The Fingerprints Of Nox Using Stable Isotopes: Implications For Nox Source Partitioning And Oxidation Chemistry, Wendell William Walters
Open Access Dissertations
The nitrogen (N) and oxygen (O) stable isotope composition (δ15N & δ18O) of nitrogen oxides (NOx )may be a useful tool for constraining NOx emission sources as well as for understanding the atmospheric oxidation pathways responsible for its removal if various NOx sources and sink processes exhibit characteristic isotopic compositions (“fingerprints”). However, this requires (1) an accurate and complete inventory of δ15N(NOx) values from major emission sources, (2) an assessment of the kinetic and equilibrium isotope effects that can impact δ15N and δ18O values of NOx, (3) and test these assumptions by conducting accurate in situ δ15N and δ18O measurements …
Quantifying The Global N2o Emissions From Natural Ecosystems Using A Mechanistically-Based Biogeochemistry Model, Tong Yu
Open Access Theses
Nitrous oxide (N2O) has a great influence on atmospheric chemistry and climate. It is not only a major greenhouse gas, but also one of the largest ozone-depleting substances emitted from the biosphere. Process-based biogeochemistry modeling constrained by site-level observations is a feasible approach to quantifying its emissions at large temporal and spatial scales. This study developed a process-based biogeochemistry model of N2O emissions based on an extant biogeochemistry model, the Terrestrial Ecosystem Model (TEM). The model development includes: 1) incorporating the effects of physical conditions on both nitrification and denitrification and 2) implementing principles of the stoichiometry of carbon and …