Physical Sciences and Mathematics Commons^™

Using Strainmeters To Characterize Enhanced Geothermal Systems, Clem Laffaille

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Thermal Energy Storage Using High Temperature Borehole Heat Exchangers In Unconsolidated Materials, Kayla Bicknell

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Thermal energy storage is a potential method for storing excess energy produced when supply is greater than demand. The use of the subsurface for storing thermal energy has become more recognized as a viable alternative to conventional methods of energy storage. However, high temperature borehole thermal energy storage has yet to be researched in-depth. Therefore, the goal of this project is to determine the feasibility of using the subsurface to store thermal energy at relatively high temperatures.

The focus of this work is to determine what design elements would make a borehole thermal energy storage system most effective and produce …

Radiation Exposure Calibration Of The Al2o3:C With Radium-226 And Cesium-137 Using The Osl Method, Selma Tepeli Aydin

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Optically stimulated luminescence (OSL) dosimetry was utilized to calibrate Al₂O₃:C powder dosimeters, available commercially as the nanoDot® from Landauer Inc., and compare the dosimeter response to radium-226 (²²⁶Ra) and cesium-137 (¹³⁷Cs). The signal from the OSL was quantified using a microSTARii^® OSL reader also produced by Landauer Inc. Dose-response curves were developed for ²²⁶Ra and ¹³⁷Cs experiments (5 dosimeters each) at thirteen absorbed doses. Individual dosimeter response was tracked by serial number. Linear regression analysis was performed to determine if there were significant differences between the intercepts of the …

Measurement Of Microplastics In A Freshwater Micro-Watershed, Cole Bowman

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The role of microplastics as an emerging contaminant can be complex to study because of the lack of standardization in the collection and analysis of microplastic particles. The purpose of this manuscript is to detail an iterative process of different collection methods in trying to understand microplastic deposition and transport in a freshwater micro-watershed through lab-based and field-based studies. A flume experiment was conducted to test the trapping efficiency of a sediment trap design at two different velocities (1.12 m/s and 2.24 m/s). Eight types of microplastics varying in morphology and density were introduced to the flume in order to …

Evaluating The Feasibility Of Using Strain Measured During Sinusoidal Rate Pumping Tests To Characterize An Aquifer, Riley Blais

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Pumping tests with sinusoidal variation in pumping rate have been proposed as a method for improving aquifer characterization. These tests can interrogate a larger aquifer volume than slug tests and they can be more sensitive to small variations in drawdown. Current methods of using sinusoidal variations of rate are based on measuring pressure signals from the reservoir or aquifer, which requires access to monitoring wells. An alternative approach has been developed that measures the strain in the vadose zone instead of pressure in the reservoir. An instrument has been developed at Clemson University that can measure small strains using optical …

High-Energy Storm Events And Their Impacts On Carbon Storage In Tidal Wetlands Of South Carolina, Gavin Gleasman

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Atmospheric carbon dioxide (CO₂) concentrations have been increasing at an accelerating rate for the past two centuries, profoundly impacting global climate change. Atmospheric CO₂ concentrations are influenced by the global carbon cycle through physical and biogeochemical pathways. Tidal wetland environments play a vital role in the global carbon cycle by offsetting atmospheric CO₂ concentrations through their natural physiochemical processes of high autotrophic productivity, allochthonous organic matter deposition, anoxic soils, and continuous accretion which promotes carbon sequestration with long-term storage at the land-ocean margin. The Intergovernmental Panel on Climate Change (IPCC) and United States Global Change Research …

Quantifying Heterogeneity Along A Hillslope Using Seismic Refraction, Structure From Motion, And X-Ray Fluorescence In The Piedmont, South Carolina, Leah Topping

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The critical zone (CZ) is the life sustaining outer layer of the earth that spans from the top of unweathered bedrock to the tops of the trees. This dynamic zone is always evolving because a variety of chemical, physical, and biological processes transform bedrock into regolith, creating a spatially heterogeneous CZ architecture. This study aims to investigate the relationships between regolith thickness, seismic velocities, and chemical profiles as a function of slope position and it is hypothesized bedrock composition, fracture density, and foliation are the key factors controlling the physical heterogeneity in the top 1-2 meters of the CZ. To …

Net-Zero Target And Emissions From Land Conversions: A Case Study Of Maryland's Climate Solutions Now Act, Philip Hutton

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Many climate change “solution” plans include net-zero goals, which involve balancing the anthropogenic greenhouse gas emissions (GHG) with their removal. Achieving net-zero goals is particularly problematic for soils because they are often excluded from GHG inventories and reduction plans. For example, Maryland’s Climate Solutions Now Act (Senate Bill 528) put forward a target of net-zero emissions by 2045. To achieve these goals, the state of Maryland (MD) needs to quantify GHG emissions. Soils are currently excluded from MD’s GHG assessments. This study examines the challenges in meeting net-zero goals by using carbon dioxide (CO₂). The current study quantified …

Impacts Of Preferential Flow On Tc-99and Np-237 Vadose Transport In Soils At The Savannah River Site, Josh Parris

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Since the 1950s, the United States has produced approximately 90,000 metric tons of spent nuclear fuel (SNF) (Office of Nuclear Energy, 2022); however, no long-term storage solutions are available. Technecium-99 and neptunium-237, two fission products found in SNF, readily form highly mobile species in oxidizing conditions (Hu, 2008; Bondietti, 1979) and have respective half-lives of 2.13 x 10⁵ and 2.14 x10⁶ years (Hu, 2010). Considering these characteristics, ⁹⁹Tc and ²³⁷Np are two risk-driving isotopes found in SNF storage. The process of macropore-facilitated preferential flow, transport through cracks within a soil matrix, has been recognized to increase …

Evaluation Of Zero-Net-Rate Pumping Tests, Austin Smith-Jones

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Accurately estimating the distribution of aquifer properties is key to understanding contaminant movement in the subsurface. The distribution of aquifer properties is typically addressed using slug or constant-rate well tests, and the pros and cons of these tests are well known. Slug tests are appealing because they avoid removing contaminated water, but their results are affected by well skin and the small volume of displaced water limits the volume of aquifer that can be evaluated. Constant-rate well tests have the disadvantage of requiring disposal of potentially contaminated water, but they can generate properties that are more representative than slug tests, …

Explaining Spatio-Temporal Evolution Of Extreme Hydro-Climatic Events Using A Complex Network Framework, Somnath Mondal

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Severe hydroclimatic extreme events, such as droughts, heatwaves, and heavy rainfall, are occurring with increasing frequency and causing significant impacts on both people and the environment. These events also compound in space and time, leading to even more significant consequences. Therefore, it is essential to comprehend these phenomena' concurrent and time-delayed progression across different temporal and spatial scales to address adaptation and mitigation effectively. To accurately understand and map the co-evolution of extreme events, it's necessary to have a thorough grasp of their spatiotemporal patterns, how they propagate and interact with one another, and the underlying mechanisms driving their occurrence. …

Computational And Experimental Investigations Of Alkali Cation Interactions At The Rutile – Water Interface, Isaac Johnston

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Overall, the objective of this dissertation was to investigate the degree of sorption for the alkali cations on rutile to ascertain the impact of different cation properties, such as ion size and charge density, on sorption mechanics as well as probe how the ion may alter the surface – aqueous interface. Initial molecular dynamic simulations and batch experiments showed minimal surface sorption for any alkali cation at relatively low concentrations while simultaneously suggesting the enthalpy of deprotonation shifts slightly in the presence of the alkali cations at different ionic strengths. The cations are likely causing small reorientations of the near-surface …

Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson

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The formation of uranyl phosphate precipitate is a remediation strategy because the low solubility of uranyl phosphate minerals, like chernikovite, limits the mobility of uranium in contaminated soils. However, organic ligands can complex with aqueous metal cations to form more soluble species. For example, citrate is a commonly occurring organic ligand produced by plants and microbes that increases the solubility of uranium and therefore the dissolution of uranyl phosphate minerals in the uranyl phosphate-citrate system. This effect is an important control on the mobility of uranium in organic-rich, and near-surface vegetated environments. Nevertheless, key aspects of the citrate-uranyl phosphate system …

Cover Cropping And Organic Amendments To Improve Sandy Soils Under Organic Vegetable Production, Charles Williamson

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Coastal Plain soils in the Southeastern USA are typically sandy with poor soil structure, low soil organic carbon (SOC) content, and meager soil fertility that pose challenges to organic agriculture. Adding organic inputs is a strategy to improve these soils' physical, chemical, and biological characteristics. Here, we aim to investigate the impacts of Cover Cropping (CC) and manure inclusions on sandy soils under organic vegetable production. The experiment design was a randomized complete block with two treatments of manure application (with and without) and four CC treatments of cereal rye (Secale cereale), hairy vetch (Vicia villosa), …

Geology-Based Shear-Wave Velocity Model Of Reference Site Conditions In South Carolina For Seismic Site Response Analysis, Camilius Amevorku

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Assessing earthquake hazard in the State of South Carolina is important because it is one of the most seismically active regions of the eastern United States and has experienced earthquakes of damaging levels in the historical past. Examples of these damaging seismic events are the 1886 Charleston earthquake (M 6.7 to 7.5) and the 1913 Union County earthquake (M 4.5 to 5.5).

Small-strain shear-wave velocity (V_S) is an important parameter in performing site response analysis. The deep nature of the top of reference firm rock (i.e., V_S ≥ 760 m/s or B-C boundary) due to …

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

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Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The ¹⁴C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast²¹ collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …

Characterization Of Water Flow And Solute Transport Driven By Preferential Flow In Soil Vadose Zone, Abdullah Al Mamun

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The vadose zone acts as a buffer zone between the ground surface and the aquifers underneath and controls the transmission of infiltrating water and contaminants, for example, pesticides and chemical spills. Therefore, understanding the flow and transport processes that dominate the vadose zone is important. Macropores are ubiquitous and particularly found in abundance in the vadose zone. These macropores facilitate preferential flow, through which water travels rapidly deep into the soil, bypassing most of the porous matrix. Preferential flow and transport have environmental significance as their processes impact hydrology, ecology, agriculture, subsurface contamination, and waste management sectors. Thus, the overall …

Wetland Uranium Transport Via Iron-Organic Matter Flocs And Hyporheic Exchange, Connor J. Parker

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Uranium (U) released from the M-Area at the Department of Energy Savannah River Site into Tims Branch, a seasonal wetland and braided stream system, is estimated to be 43,500 kg between 1965 and 1984. The motivation for this work is the uranium’s persistence in the wetland for decades, where it is estimated that 80% of the U currently remains in the Tims Branch wetland. U has begun to incorporate into wetland iron (Fe) and carbon cycles, associating with local Fe mineralogy and deposits of rich wetland organic matter (OM). The objective of this work is to characterize the chemical phases …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

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Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

A Conservative Numerical Scheme For The Multilayer Shallow Water Equations, Evan Butterworth

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An energy-conserving numerical scheme is developed for the multilayer shallow water equations (SWE’s). The scheme is derived through the Hamiltonian formulation of the inviscid shallow water flows related to the vorticity-divergence variables. Through the employment of the skew-symmetric Poisson bracket, the continuous system for the multilayer SWE’s is shown to preserve an infinite number of quantities, most notably the energy and enstrophy. An energy-preserving numerical scheme is then developed through the careful discretization of the Hamiltonian and the Poisson bracket, ensuring the skew-symmetry of the latter. This serves as the groundwork for developing additional schemes that preserve other conservation properties …

Vermont Global Warming Solutions Act: The Costs Of Inaction From Land Conversions, Grayson L. Younts

All Theses

The Vermont (VT) Global Warming Solutions Act (GWSA, 2020) sets greenhouse gas (GHG) emissions reduction targets as 26% below 2005 by 2025, 40% below 1990 by 2030 and 80% below 1990 by 2050 for energy-related emissions only. Vermont’s omission of GHG emissions from land conversions can result in significant costs of inaction (COI), which can hinder state’s mitigation and adaptation plans and result in a climate crisis-related risks (e.g., credit downgrade). Science-based spatio-temporal data of GHG emissions from soils as a result of land conversions can be integrated into the conceptual framework of “action” versus “inaction” to prevent GHG emissions. …

Longleaf Pine Restoration In The South Carolina Sandhills Wiregrass Gap, Jacob W. Murray

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Longleaf pine restoration has been a topic of great concern and intrigue in the southeast and has taken on new fervor in recent decades as restoration methods continue to develop. Many landowners and forest managers are now pursuing ecological forestry and restoration ecology in great numbers as a new form of land management. However, niche regions can often be overlooked, as is the case with the Carolina Sandhills Wiregrass Gap, an area devoid of wiregrass and one that is on the outskirt regions of the historical longleaf pine range. Field studies were conducted pre- and post-harvest during two growing seasons …

Reinforcement Learning Policy Gradient Methods For Reservoir Operation Management And Control, Sadegh Sadeghi Tabas

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Changes in demand, various hydrological inputs, and environmental stressors are among issues that water managers and policymakers face on a regular basis. These concerns have sparked interest in applying different techniques to determine reservoir operation policy and improve reservoir release decisions. As the resolution of the analysis rises, it becomes more difficult to effectively represent a real-world system using traditional approaches for determining the best reservoir operation policy. One of the challenges is the “curse of dimensionality,” which occurs when the discretization of the state and action spaces becomes finer or when more state or action variables are taken into …

Soil Moisture And Light Conditions Impact Digital And Visual Soil Color Assessments, Isabella Hill

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Determining soil color has traditionally been done visually, but inaccuracies with this method have been documented, including disagreement in evaluators, to differences in physical color books. Determining Munsell soil color in the field is also subject to environmental conditions, including soil water content (SWC) and light intensity. New digital spectral technology designed for determining soil color may offer accurate assessments regardless of human inaccuracies and environmental conditions. This research aimed to assess if visual observations differed from digital measurements of Munsell soil color as well as, the impacts of SWC and light on visual observations and digital measurements of soil …

Feasibility Study Of Porous Media Compressed Air Energy Storage In South Carolina, United States Of America, Alexandra-Selene Jarvis

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Renewable Energy Systems (RES) such as solar and wind, are expected to play a progressively significant role in electricity production as the world begins to move away from an almost total reliance on nonrenewable sources of power. In the US there is increasing investment in RES as the Department of Energy (DOE) expands its wind power network to encompass the use of offshore wind resources in places such as the South Carolina (SC) Atlantic Coastal Plain. Because of their unstable nature, RES cannot be used as reliable grid-scale power sources unless power is somehow stored during excess production and recovered …

Biogeochemical Processes In Hydrosoil Of Pilot-Scale Constructed Wetland Treatment Systems Designed For Treatment Of Selenium, Christina Blaszkiewicz

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Two pilot-scale wetland treatment system cells (nutrient amended and unamended) were designed and constructed to reduce aqueous Se concentrations in simulated energy-derived water. Specific objectives of this study were: (i) measure and correlate hydrosoil conditions with Se concentrations vertically through the hydrosoil; (ii) investigate Se-accumulating biogeochemical processes (dissimilatory Se reduction and sorption) operating in the hydrosoil; and (iii) evaluate the effect of a nutrient amendment on hydrosoil conditions, Se accumulation, and Se-sequestering biogeochemical processes in the hydrosoil. Se accumulation (i.e. total Se concentration) and hydrosoil conditions were measured with depth in the hydrosoil. Se-sequestering biogeochemical processes were investigated by counting …

Toward Understanding The Thermodynamics And Mechanisms Of Actinide Sorption Reactions, Shanna Estes

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The environmental fate of actinides is greatly influenced by interfacial reactions, including sorption onto solid surfaces. Because changes in the primary hydration sphere of the actinide are expected to greatly influence the thermodynamics (i.e., reaction enthalpy and entropy) of these reactions, examining actinide sorption thermodynamics may provide insight into actinide sorption mechanisms. Additionally, examining actinide sorption thermodynamics may enhance the ability to model or predict these reactions in environmental or engineered systems where variable or elevated temperatures are expected. However, few researchers have studied actinide sorption thermodynamics. Therefore, this research examined the thermodynamics of Eu(III) (a trivalent actinide analog), Th(IV), …

Transformation Of Uranium In A Geological Environment, Derrell Hood

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Incorporation of uranium into iron oxide minerals is a promising mechanism for the environmental immobilization of U(VI). In this study, synthesized hematite was doped with uranium and analyzed with SEM-EDS, TEM, XRD, and ICP-MS. The results of this analysis strongly indicate uranium incorporation into the mineral, as well as the possible presence of a co-precipitated uranium mineral clarkeite. Preliminary results also shows an increase in the amount of uranium associated with the hematite particles as a function of mineral aging. Cyclic Voltammetry (CV) was used to induce and characterize electrochemical changes of uranium in the doped hematite system; these changes …

Air-Regulated Siphon Spillways: Performance, Modeling, Design, And Construction, Joshua Boatwright

All Theses

1:Little data exists in the literature for quantification of siphon spillway performance. Proper design of an air regulated siphon spillway requires knowledge of required flow rates and minimum vent size. A set of small siphon spillways were constructed to measure flow rate and required vent size relative to physical characteristics including pipe diameter, length of pipe, and elevation head. Vent sizing was shown to be logarithmically proportional to flow rate. Results were used to develop predictive models for flow rate and vent sizing. Models were validated and refined through testing on a siphon spillway installed on a pond at LaMaster …

An Examination Of Radionuclide Transport In The Vadose Zone Using Field Lysimeters, Michael Witmer

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Understanding how radionuclides interact in the subsurface is important for the remediation of contaminated sites, assessment of risk due to radioactive waste disposal, and designing new radioactive waste management strategies. The current understanding of the geochemical behavior of radionuclides in the subsurface and more specifically the vadose zone has been developed through reactive transport modeling supplemented by laboratory experiments. Interactions between radionuclides with the mineral particles and organic matter in the vadose zone can be very complex and while laboratory experiments produce valuable data, few controlled, intermediate scale transport studies have been performed. In order to accurately predict vadose zone …