Physical Sciences and Mathematics Commons^™

Assessing Stormwater Management Pond Water Quality, Function, And The Potential Biotic Effects To Receiving Waters, Mitchell Elstone

Theses and Dissertations (Comprehensive)

The use of stormwater management ponds (SWMPs) has been increasing over the past five decades. However, an in-depth understanding of the daily performance of SWMPs and functionality during cold periods is limited. This is in part because mandated monitoring is relatively infrequent, and the assumption that SWMPs are inactive between storm events and during the winter. The goals of this research were to better understand daily stormwater (SW) characteristics, the performance of SWMPs based on current forms of evaluation and assess the potential for SWMP effluent to impact downstream biota. Influent and effluent samples from two SWMPs were collected daily …

Chemical Characterization Of Clastic Cave Sediments And Insights Into Particle Transport And Storage In Karst Aquifers, Jill L. Riddell

Graduate Theses, Dissertations, and Problem Reports

Abstract

Chemical characterization of clastic cave sediments and insights into particle transport and storage in karst aquifers

Jill L. Riddell

Cave sediments can be divided into two groups: precipitates and clastics. Precipitates are speleothems, or lithologic or mineral features that are chemically precipitated in the cave environment. Clastic cave sediments are frequently described by depositional facies, sorting, and particle size (Bosch and White, 2004). Robust analytical chemical analyses of these sediments to quantify their physical and chemical components is rarely performed although some chemical characterization of mineralogy and paleomagnetism has become prevalent in recent years (Chess et al., 2010; Sasowsky …

The 3H/3He Groundwater Age-Dating Method And Applications, Troy E. Gilmore, Mikaela L. Cherry, Didier Gastmans, Douglas Kip Solomon, Eric Christopher Humphrey

School of Natural Resources: Faculty Publications

Groundwater age-dating is an important tool for quantifying and managing water resources. Groundwater age is the elapsed time between recharge (at the land surface or water table) and the time when groundwater is sampled. If groundwater is sampled at the point of discharge from an aquifer, then the age represents the groundwater transit time. Groundwater that has recharged in recent decades is considered young groundwater. In many areas, the quality and quantity of young groundwater has been impacted by human activities and groundwater age-dating is useful for quantifying current and historical water and contaminant fluxes into and through aquifers. This …

Model Of Residence Time And Analysis Of Nitrogen Removal For Two Constructed Wetlands At The Franklin Demonstration Farm In Lexington, Illinois, Emma Singh Baghel

Theses and Dissertations

Pollution from nonpoint agricultural runoff has become a major problem facing our streams and rivers today. Not only are fish and aquatic life affected, but so is the quality of our drinking and recreational water resources. Studies have shown that wetlands have proven to be the most cost-effective and low maintenance method of removing nonpoint or diffused contaminate inputs. The biological processes and removal of nutrients in wetlands depend on the total surface area available for microbial activity in the soil and a certain period of water retention time. Since chemical processes take time, the measure of residence time is …

Quantifying The Relationship Among Ground Penetrating Radar Reflection Amplitudes, Horizontal Sub-Wavelength Bedrock Fracture Geometries, And Fluid Conductivities, Carolyn Morgan Tewksbury-Christle

Masters Theses

Accurate characterization of subsurface fractures is indispensible for contaminant transport and fresh water resource modeling because discharge is cubically related to the fracture aperture; thus, minor errors in aperture estimates may yield major errors in a modeled hydrologic response. Ground penetrating radar (GPR) has been successfully used to noninvasively estimate fracture aperture for sub-horizontal fractures at outcrop scale, but limits on vertical and horizontal resolution are a concern. Theoretical formulations and field tests have demonstrated increased GPR amplitude response with the addition of a saline tracer in a sub-millimeter fracture; however, robust verification of existing theoretical equations without an accurate …

Geochemical Controls On Mercury Methylation In Backwaters Of A Gulf Coastal Plain River System, Implications For Water Column Processes, Liam N. Schenk

Graduate Theses and Dissertations

The abundance and distribution of mercury and methyl mercury were investigated at three sites in the lower Ouachita River in the summer of 2010 in an effort to provide the first characterization of the extent of mercury contamination in this river system, and to investigate the potential for mercury methylation in the water column of backwaters off of the main channel. Results showed that filtered methyl mercury was positively correlated to dissolved organic carbon (r2=0.76) for water samples taken from the bottom 1 ft of the water column at three sites, suggesting the importance of dissolved organic carbon in mercury …

Agricultural Herbicide Transport In A First‐Order Intermittent Stream, Nebraska, Usa, Jason Vogel, Joshua Linard

United States Geological Survey: Staff Publications

The behavior of herbicides in surface waters is a function of many variables, including scale of the watershed, physical and chemical properties of the herbicide, physical and chemical properties of the soil, rainfall intensity, and time of year. In this study, the transport of 6 herbicides and 12 herbicide degradates was examined during the 2004 growing season in an intermediate‐scale agricultural watershed (146 ha) that is drained by a first‐order intermittent stream, and the mass load for each herbicide in the stream was estimated. The herbicide load during the first week of storm events after application ranged from 17% of …

Laboratory Determination Of Multicomponent Effective Diffusion Coefficients For Heavy Metals In A Compacted Clay, M. Zeki̇ Çamur, Hasan Yazicigi̇l

Turkish Journal of Earth Sciences

Diffusion and sorption of heavy-metal ions (Cd, Cr, Cu, Fe, K, Mn, Ni, Pb, and Zn) through an Ankara clay liner were studied experimentally. The Ankara clay consists of calcite, quartz, smectite and illite, and is a highly plastic inorganic clay with optimum weight water content of 32% and corresponding dry density of 1.413 g/cm3. Under optimum compaction conditions, effective porosity (volumetric water content) and hydraulic conductivity in the material were determined as 0.45 and 1.3 to 2.6x10-9 cm/s, respectively. The Ankara clay adsorbed Cd, Cr, Cu, Fe, K, Mn, Ni, Pb, and Zn metals, but desorbed Ca, Mg and …

Modeling Surface And Subsurface Pesticide Transport Under Three Field Conditions Using Przm-3 And Gleams, Robert W. Malone, Richard C. Warner, Stephen R. Workman, Matt E. Byers

Biosystems and Agricultural Engineering Faculty Publications

Contaminant transport models should be evaluated over a wide range of conditions to determine their limitations. The models PRZM and GLEAMS have been evaluated many times, but few studies are available in which predicted movement in runoff and percolate were simultaneously evaluated against field data. Studies of this type are essential because pesticide leaching and runoff are mutually dependent processes. For this reason, PRZM-3 and GLEAMS were evaluated for their ability to predict metribuzin concentrations in runoff, sediment, subsurface soil, and pan lysimeters under three field conditions (yard waste compost amended, no-till, and conventional-till) on a Lowell silt loam soil. …

Spatial And Temporal Variability In Seepage Between A Contaminated Aquifer And Tributaries To The Ohio River, Alan E. Fryar, David L. Brown, David B. Wenner, Todd C. Rasmussen, Eric J. Wallin

KWRRI Research Reports

Because interactions between ground water and tributaries may influence contaminant loading to rivers, we delineated seepage along Little Bayou and Bayou Creeks in McCracken County, Kentucky, during a two-year period. From the Paducah Gaseous Diffusion Plant, on the divide between the creeks, trichloroethene and technetium-99 plumes extend several km toward the Ohio River. Gaining conditions occur where the creeks are incised into coarse sediments in the river's flood plain. Such conditions were marked by upward hydraulic gradients within the bed; maximum specific discharge (q) > 0.24 m d^-1; relatively narrow ranges of stream, piezometer, and bed temperatures; relatively cool …

Modeling Transport Of Colloid-Bound Herbicides And Heavy Metals To Groundwater, Anastasios D. Karathanasis, R. E. Phillips, A. K. Seta

KWRRI Research Reports

Recent studies have suggested that contaminant transport to groundwater may be enhanced by association with colloidal particles. This study evaluated the role of water dispersible colloids with diverse mineralogical composition in co-transporting selected herbicides and heavy metals through intact soil columns. Colloid recovery in the eluents ranged from 45-90% for the herbicides and 10-60% for the heavy metals. The presence of colloids enhanced the transport of atrazine by 2-18%, and metolachlor by 8-30%. The corresponding increase for Cu and Zn was 2-150 and 5-30 times, respectively. For Pb, there was essentially no elution in the absence of colloids, suggesting nearly …