Physical Sciences and Mathematics Commons^™

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Transport And Mixing Of Water Masses Across The Southeast Caribbean Ocean Imaged By Seismic Reflection Data, Joseph Renzaglia

Earth Sciences Theses and Dissertations

The Caribbean Sea serves as a major pathway for global thermohaline circulation (THC), which is a complex and vital component of the Earth’s climate system, influencing global heat distribution and oceanic circulation. Though relatively stratified, it is the boundary layer that distributes mass and temperature between the surface waters and the deep ocean where we observe various multiscale mixing processes from mesoscale to fine-scale. In regions where bathymetry is shallower and mechanical mixing forces, such as winds and tides, are more dominant, diapycnal diffusivity is typically stronger, driving vertical mixing. This type of mixing occurs at small scales, typically as …

Comparative Lineament And Geomorphic Analysis Of Chaotic Terrains And Noctis Labyrinthus, Mars, Sarah A. Walton

Electronic Theses and Dissertations

Noctis Labyrinthus (NL) is an extensional trough network connecting the Tharsis rise and Valles Marineris on Mars. Chaotic terrains are a group of polygonally-fractured surface features commonly associated with subsidence due to rapid fluid loss within the subsurface. Polygonal surface patterns are seen at both sites, where geometric topographic highs are bounded by low troughs. Lineaments, topography, and geomorphology of NL and chaotic terrains were analyzed to determine tectonics and fluid influence in the formation and evolution of both sites. NL shows preferential fracture patterns associated with regional extension. Lineaments within chaotic terrains do not show cumulative preferential trends but …

Quantifying Tidewater Glacier-Fjord Environments In The Rapidly Changing Regions Of West And South Greenland, Sydney Baratta

Electronic Theses and Dissertations

The Greenland Ice Sheet has undergone rapid mass loss over the last four decades, primarily through solid and liquid discharge at marine-terminating outlet glaciers. The acceleration of these glaciers is in part due to the increase in temperature of ocean water in contact with the glacier terminus. However, quantifying meltwater injection and heat transport can be challenging due to iceberg abundance, which threatens instrument survival and fjord accessibility. Additionally, acceleration and eventual retreat of tidewater glaciers onto land can change glacier forcing, completely altering fjord water-meltwater dynamics. Here, we couple in situ and remote sensing methods to quantify the upper-layer …

Spatial And Temporal Variability In Snow Properties And Firn Volume Across The Juneau Icefield In Southeast Alaska, Mikaila Mannello

Electronic Theses and Dissertations

Glaciers are important freshwater resources which have far reaching impacts on a range of local to global systems and processes, including ecosystems and societies. As global climate continues to change, the response of glaciers has largely been reductions in ice mass and widespread retreat. A high degree of accumulation and ablation occurs in the near surface which is exposed to the atmosphere. The Juneau Icefield (JIF) has, up until the mid-2010s, historically responded climate change anomalously where its main drainage, Taku Glacier (here forward referred to its native name T’aakú Kwáan Sít’i), has been advancing while all other JIF outlet …

Quantifying Current Soil Brine Contamination Within The Smackover Oil Field In Arkansas Using Multispectral Digital Imagery, Victoria Williams

Electronic Theses and Dissertations

A remote sensing study was performed to quantify current soil brine contamination across the historic Smackover Oil Field in south-central Arkansas, United States. The oil field was established in 1922 and was not subject to the future waste regulations created by the Arkansas Oil and Gas Commission. Brine is a waste product of oil manufacturing which contains water with high salt levels. The storage and transport of brine in the oil field created landscape scarring across the study area.

Landsat 9 multispectral digital imagery was utilized to create supervised classification maps based on earthen pits and creek scarring across the …

Investigating The Effects Of A Southward Flow In The Southeastern Florida Shelf Using Robotic Instruments, Alfredo Quezada

All HCAS Student Capstones, Theses, and Dissertations

We deployed a Slocum G3 glider fitted with an acoustic Doppler current profiler (ADCP), a Conductivity-Temperature-Depth sensor (CTD), optics sensor channels, and a propeller on the Southeastern Florida shelf. The ADCP and CTD provide continuous measurements of Northern and Eastern current velocity components, salinity, temperature, and density, throughout the water column in a high-current environment. The optics sensor channels are able to provide measurements of chlorophyll concentrations, colored dissolved organic matter (CDOM), and backscatter particle counts. Additionally, for one of the glider deployments, we deployed a Wirewalker wave-powered profiling platform system also fitted with an ADCP and a CTD in …

Prevalence, Faunal Composition, And Vertical Distribution Of Bioluminescence In The Pelagic Gulf Of Mexico: Fishes, Crustaceans, Cephalopods And Gelatinous Megaplankton, Devynne M. Brown

All HCAS Student Capstones, Theses, and Dissertations

Bioluminescence is the phenomenon of light emission by living organisms. It occurs through a chemical reaction within an organism and serves various purposes. The diversity of bioluminescent capabilities and occurrence in unrelated taxa suggest that bioluminescence has evolved independently numerous times amongst taxa thriving in certain environments. One such environment is the deep ocean, where little to no sunlight penetrates the water column, specifically in the mesopelagic (200-1000 m depth) and bathypelagic (> 1000 m) zones. The mesopelagic and bathypelagic zones have been extensively sampled and well documented in the Gulf of Mexico (GoM), one of the few places globally …

Exploring Soil Microbial Dynamics In Southern Appalachian Forests: A Systems Biology Approach To Prescribed Fire Impacts, Saad Abd Ar Rafie

Doctoral Dissertations

Prescribed fires in Southern Appalachian forests are vital in ecosystem management and wildfire risk mitigation. However, understanding the intricate dynamics between these fires, soil microbial communities, and overall ecosystem health remains challenging. This dissertation addresses this knowledge gap by exploring selected aspects of this complex relationship across three interconnected chapters.

The first chapter investigates the immediate effects of prescribed fires on soil microbial communities. It reveals subtle shifts in porewater chemistry and significant increases in microbial species richness. These findings offer valuable insights into the interplay between soil properties and microbial responses during the early stages following a prescribed fire. …

Characterizing Silicate Materials Via Raman Spectroscopy And Machine Learning: Implications For Novel Approaches To Studying Melt Dynamics, Blake O. Ladouceur

Doctoral Dissertations

Silicate melt characteristics impose dramatic influence over igneous processes that operate, or have operated on, differentiated bodies: such as the Earth and Mars. Current understanding of these melt properties, such as composition, primarily comes from investigations on their volcanic byproducts. Therefore, it is imperative to innovate on modalities capable of constraining melt information in environments where a reliance on laboratory methods is severed. Recent investigations have turned to Raman Spectroscopy and amorphous volcanics as a suitable pairing for exploring these ideas. Silicate glasses are a proxy for igneous melts; and Raman spectroscopy is a robust analytical technique capable of operating …

Southern Rio Grande Rift Kinematics And Geochronology, Big Bend Fold Geometry, And The Use Of Real Data In Geoscience Education: Contributions To The Understanding Of Big Bend Geology And To Public Geoscientific Literacy, Jessica Kelsch

Open Access Theses & Dissertations

The Big Bend region of Trans-Pecos Texas preserves a rich record of Rio Grande rifting and Laramide-age contraction that provide intrigue to national and state park visitors and field trips for undergraduate geology students. Despite its well-exposed geologic record, the Big Bend region remains an underutilized natural laboratory for studying these two tectonic events. This dissertation combines structural studies of Rio Grande rift and Laramide structures with public outreach and geoscience education studies focused on the Big Bend region. In Chapter 2, existing extensional-kinematic studies from parts of this region are compiled with new fault kinematic and U-Pb geochronologic data …

Enhancing Our Understanding Of Ancient Oceans Through The Investigation Of Molybdenum Behavior Under Sulfidic Conditions, Rachel Faye Phillips

Open Access Theses & Dissertations

The most abundant trace metal in the ocean today, molybdenum (Mo), exhibits distinct behavior in oxygenated water, where it remains predominantly dissolved, compared to euxinic (i.e., oxygen-free and sulfidic) water, in which it is sequestered into the sediment. This dissimilar behavior allows us to use Mo concentrations and isotopic compositions in sediment to reconstruct marine oxygenation conditions throughout geologic history. However, Mo sequestration mechanisms under euxinic conditions remain unresolved, which limits the accuracy and precision of reconstructions made using Mo signatures in the rock record. For my doctoral research, I experimentally investigated abiotic and biotic Mo sequestration mechanisms under various …

Alteration And Mineralization Of The Deep Extension Of The Giant Chuquicamata Porphyry Copper Deposit, Northern Chile, Claudio Andres Araya Torres

Open Access Theses & Dissertations

Porphyry copper deposits are the major source of copper and molybdenum in the world. The deposits consist of large volumes of rock altered by hydrothermal fluids released by shallow, intermediate composition magma chambers, with metallic mineralization present in veins, breccias, and disseminations; ore grades are typically 0.3-1.0 wt.% Cu. The subject of this study, the Chuquicamata porphyry copper deposit in northern Chile, is one of the most productive such deposits in the world, with over 45 million tons of Cu produced since large scale, open pit mining started early in the XXth century. Current production at Chuquicamata is from an …

Post-Wildfire Effects On A Headwater Stream In The San Bernardino National Forest, Kelley Giron

Electronic Theses, Projects, and Dissertations

Southern California has experienced prolonged drought conditions that have supported frequent wildfires that adversely impact ecosystems, natural resources, and human development. A primary consequence of these events is the impact on water quality and quantity. Of equal concern is evaluating how diverse land use configurations within a watershed can alter the physio-chemical properties of headwater reaches where drought and wildfire conditions are prevalent. To better understand the extent to which wildfires impact water quality and quantity across a headwater watershed, this study investigates wildfire impacts from the 2021 South Fire to Lytle Creek, a headwater stream of the Santa Ana …

Investigating Seismicity And Structure Of The Pecos, Texas Region Of The Delaware Basin Using A Temporary Nodal Network, Jenna Lynn Faith

Open Access Theses & Dissertations

With increasing earthquakes in the Delaware Basin since 2009, earthquake studies, including accurate hypocenters, are critically needed in the Delaware Basin to identify the structures producing earthquakes, and to determine if they are related to unconventional petroleum development and production. In 2018, with funding from the Texas Seismological Network (TexNet), the University of Texas at El Paso deployed and maintained a nodal network of 25 Magseis Fairfield Z-Land Generation 2 5-Hz seismic nodes in the Pecos, Texas region of the Delaware Basin, known as The Pecos Array. The network was deployed from November 2018 until the beginning of January 2020, …

Using Shallow Electromagnetic And Magnetic Techniques To Map Soil Texture And Characterize Salinity And Water Dynamics Below Pecan Orchards, El Paso County, Texas, Kristina Sasser

Open Access Theses & Dissertations

Non-invasive, near surface geophysical tools provide a time efficient and cost-effective approach to study the shallow subsurface. Electromagnetic induction (EMI) instruments are a category of these near surface methods that provide spatial and temporal information (2-D to 4-D) about shallow (<6 m) subsurface properties, from which soil salinity, clay content, and water content can be estimated. However, deconstructing soil apparent electrical conductivity (ECa) from EMI methods into its component parts remains a challenge. This research uses EMI and magnetic geophysical techniques to: (1) compare and contrast the distribution and behavior of ECa, both spatially and temporally, at two flood irrigated agricultural sites (pecan orchards) with different soil layers, properties, and controls on electrical conductivities that lie within the same floodplain in far west Texas; and (2) develop a one-dimensional inversion model using ECa and soil texture data at specified layers from established sites of known high and low ECa to determine soil layer resistivities at various dates during the irrigation season. Data are compared to soil sensor bulk EC and volumetric water content data at corresponding depths to validate results. Soils at both sites exhibit large ECa contributions from textural controls, and irrigation frequency. The combination of these two controls dictate where and how quickly secondary minerals precipitate, clog soil pores, reduce infiltration, and salinize the groundwater. Insight from this research aids in ongoing efforts to characterize vadose zone hydrology in dryland critical zones with high infiltration and serves as a guide for locations where future soil sampling will occur.

Wavelet Compression As An Observational Operator In Data Assimilation Systems For Sea Surface Temperature, Bradley J. Sciacca

University of New Orleans Theses and Dissertations

The ocean remains severely under-observed, in part due to its sheer size. Containing nearly billion of water with most of the subsurface being invisible because water is extremely difficult to penetrate using electromagnetic radiation, as is typically used by satellite measuring instruments. For this reason, most observations of the ocean have very low spatial-temporal coverage to get a broad capture of the ocean’s features. However, recent “dense but patchy” data have increased the availability of high-resolution – low spatial coverage observations. These novel data sets have motivated research into multi-scale data assimilation methods. Here, we demonstrate a new assimilation approach …

Toward A Greater Comprehension Of The Paraná Epicontinental Sea During The Late Paleozoic Ice Age: The Glacial And Postglacial Record In The Western Paraná Basin (Brazil) And The Kaokoveld Fjord Network (Namibia), Eduardo Luiz Menozzo Da Rosa

Theses and Dissertations

The late Paleozoic Ice Age (LPIA; 362 to 255 Ma) was an icehouse interval that drove substantial changes in Earth’s surficial systems. Numerous paradigms regarding aspects of the LPIA were established throughout ~150 years of research based primarily on the evolving state of knowledge in sedimentology. The near-field lithological evidence for widespread glaciation across sedimentary basins of Gondwana are the building blocks for comprehensive paleoclimatic, biologic, paleogeographic, and ice volume models. Nevertheless, the embodied glacial record from several late Paleozoic Gondwanan depocenters still rely on insufficient and/or outdated sedimentologic and stratigraphic studies, which can lead to misinterpretations in models built …

Radiation Exposure Calibration Of The Al2o3:C With Radium-226 And Cesium-137 Using The Osl Method, Selma Tepeli Aydin

All Theses

Optically stimulated luminescence (OSL) dosimetry was utilized to calibrate Al₂O₃:C powder dosimeters, available commercially as the nanoDot® from Landauer Inc., and compare the dosimeter response to radium-226 (²²⁶Ra) and cesium-137 (¹³⁷Cs). The signal from the OSL was quantified using a microSTARii^® OSL reader also produced by Landauer Inc. Dose-response curves were developed for ²²⁶Ra and ¹³⁷Cs experiments (5 dosimeters each) at thirteen absorbed doses. Individual dosimeter response was tracked by serial number. Linear regression analysis was performed to determine if there were significant differences between the intercepts of the …

Thermal Energy Storage Using High Temperature Borehole Heat Exchangers In Unconsolidated Materials, Kayla Bicknell

All Theses

Thermal energy storage is a potential method for storing excess energy produced when supply is greater than demand. The use of the subsurface for storing thermal energy has become more recognized as a viable alternative to conventional methods of energy storage. However, high temperature borehole thermal energy storage has yet to be researched in-depth. Therefore, the goal of this project is to determine the feasibility of using the subsurface to store thermal energy at relatively high temperatures.

The focus of this work is to determine what design elements would make a borehole thermal energy storage system most effective and produce …

The Spatial And Temporal Distribution Of Large Rock Blocks And Control On Landscape Evolution In The Ozarks, Chelsea Moran

Graduate Theses and Dissertations

Geologists often use landscape form to infer landscape processes through time. While climate and tectonics shape geomorphic form, the potential range of spatial or temporal scales that can shape any specific landscape can render landscape process-form based hypotheses too general for consideration. Contributions by mathematical modeling have helped bridge the gap between inferring processes from form, notably in how sediment transport dynamics shape hillslopes. However, few models encapsulate the movement of large rock blocks ( >2 meters across) and their potential impact as hillslope sediment transport disruptors. The Upper Buffalo River watershed (BRW) in the Ozarks of northern Arkansas has …

Geospatial Analysis Of Weathering And Recession On Architectural Limestone At The 1891 Powerhouse/Icehouse In Eureka Springs, Arkansas, Stuart Bruce Wright

Graduate Theses and Dissertations

The objective of this study of the architectural limestone of the 1891 Powerhouse/Icehouse in Eureka Springs, Arkansas was to analyze the environmental factors that influenced the deterioration and surface recession of this historical stone structure. The focus of this research was to examine and establish a baseline study that may assist in future monitoring and documentation of this historic limestone structure on stone weathering. A replicable methodology was specifically created toward this baseline research in hopes that it represented a solid baseline study. Observations and data analyses revealed the relationship between the architectural limestone building structure and the dominating recession …

Environmental And Agronomic Evaluation Of Struvite In Rice Production Systems, Diego Della Lunga

Graduate Theses and Dissertations

Furrow-irrigation constitutes an alternative water regime that has been increasingly adopted in Arkansas. Among the management of nutrients in furrow-irrigated systems, phosphorus (P) represents a substantial challenge. The environmental sustainability of rice (Oryza sativa) production systems needs to be evaluated across different water regimes and fertilizer-P sources. Therefore, the objectives of the following studies were to: i) evaluate season-long carbon dioxide (CO2) and methane (CH4) emissions and global warming potential (GWP) under different tillage treatments [i.e., conventional tillage (CT) and no-tillage (NT)] and at different site positions (i.e., up-, mid-, down-slope) along the predominant slope of a production-scale, furrow-irrigated rice …

Maximum Depositional Age Analysis Using Paired La-Icp-Ms And Ca-Id-Tims Detrital Zircon U-Pb Geochronology, Benjamin L. Howard

Graduate Theses and Dissertations

The “law of detrital zircons” states that a sedimentary unit cannot be older than its youngest detrital zircon. The youngest U-Pb date(s) from detrital zircon may thus be used to infer a given sedimentary deposit’s maximum depositional age (MDA). MDAs may be calculated in various ways using dates from zircon U-Pb geochronology. Common dating methods used for U-Pb geochronology are laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS), a low- and high-resolution instrument type, respectively. Chapter 2 will systematically compare paired LA-ICP-MS and CA-ID-TIMS dates from the same zircon grains to assess the agreement …

Tree-Ring Reconstruction Of Ouachita River Streamflow, Keaton Cade Jenkins-Joyce

Graduate Theses and Dissertations

The Ouachita River drains the Ouachita Mountains and Upper Coastal Plain in Arkansas and Louisiana. The Ouachita River is used for navigation, power generation, recreation, water supply, and wastewater treatment. The river has been prone to low flows during drought and extreme flooding, which were principal justifications for the construction of three large multipurpose dams on the stream. It is likely that the use of the Ouachita River will be stressed by future population growth, economic expansion, and climate change. For this study, tree-ring chronologies from various locations in and near the Ouachita River drainage basin were used to reconstruct …

Shallow Groundwater Distributions And Changes With Sea Level Rise In Seattle, Washington, Taylor L. Watson

Graduate Theses and Dissertations

Sea level rise (SLR) associated hazards, such as coastal flooding and erosion, are pressing issues of great concern for coastal communities across the globe. Shallow and emergent groundwater can contribute to groundwater hazards such as flooding, landslides, or damage to shallow infrastructure. This study investigates the shallow groundwater within Seattle, Washington, and projects how it will respond to SLR using interpolation and numerical groundwater modeling methods. Then, a geologic modeling method is presented as a preliminary investigation of heterogeneity and anisotropy within the aquifer system. In the results for the present-day interpolation, ~6 % of the coastal buffer –the total …

Using Remote Sensing To Determine Riparian Resilience In Beaver Dammed Versus Un-Dammed Corridors Following Whiplash Weather, Sophie Charlotte Valérie Aubry

Master of Science in Environmental Sciences and Management Projects

Beaver complexes slow and store water allowing for riparian growth which in turn fosters biodiversity, retains carbon, and enhances resistance to fires and drought. Given the benefits associated with beaver complexes and the potential they have for climate mitigation, California hopes to reintroduce beavers and restore their habitat throughout the state. However, the impact of high peak flow events on beaver complexes and their adjacent riparian corridors is less understood and requires more documentation at various spatial scales. To better understand the potential beavers may have as climate change mitigators it is important to understand beaver complex resiliency following a …

Multi-Objective Water Management In Idaho's Henrys Fork Watershed: Leveraging Reservoir Operation And Groundwater Pathways To Benefit Aquatic Habitat, Christina N. Morrisett

All Graduate Theses and Dissertations, Fall 2023 to Present

Multi-user water management is a challenging arena further complicated by climate change. This research is based in the Henrys Fork, Snake River, Idaho—an agricultural watershed that exemplifies those throughout the semi-arid American West. This dissertation uses an integrated approach that considers groundwater-river relationships, farm-scale decisions and basin-scale outcomes, upstream reservoir operation for downstream aquatic habitat, water rights, and collaborative stakeholder management to identify drought adaptation strategies accordingly.

Chapter 2 uses an interdisciplinary approach to quantify how improvements to irrigation efficiency at the farm-scale (i.e., converting from flood to sprinkler irrigation) can add up to affect hydrology at the landscape-scale and …

Rheological Bridge Zones: A New Perspective To Explore Strain Localization And Rock Rheological Weakening, He Feng

Electronic Theses and Dissertations

Strain localization, a ubiquitous geological phenomenon, emerges when rock undergoes extensive weakening and accommodates disproportionate deformation. This phenomenon spans from brittle faulting to viscous flow, known as shear zones. Despite its prevalence, discussions on weakening primarily center on highly strained samples, rather than the initial deformation state. This research delves into the evolution of localization and rheology in intact rocks.

Heterogeneous mechanical properties within the lithosphere vary based on mineralogy, microstructure, and environmental conditions. Chapter 2 characterizes microscale structures termed "bridge zones." These zones, observed through optical and electron microscopy, exhibit distinctive morphologies. Comprising fine-grained aggregates, bridge zones link weak …

Phosphorus Dynamics In Calcareous Soils Amended With Organic Matter, Logan Banner

All Graduate Reports and Creative Projects, Fall 2023 to Present

Phosphorus (P) is considered immobile in calcareous soils. Organic matter is known to enhance P mobility in these soils. Few studies have considered what role iron oxides might play in P sorption in calcareous soils, especially in the presence of soluble organic matter. This study investigated P sorption dynamics in sand-based, simulated soil systems in the absence or presence of 5 mM carbon (C) as humic acid (HA). Treatments included combinations of dicalcium phosphate dihydrate (DCPD), calcite, and ferrihydrite. Solutions containing 10 mg P L^-1 in a background of 0.01 M CaCl₂were equilibrated with each solid treatment …