Physical Sciences and Mathematics Commons^™

Reconstructing Geographic And Trophic Histories Of Fish Using Bulk And Compound-Specific Stable Isotopes From Eye Lenses, Amy A. Wallace

USF Tampa Graduate Theses and Dissertations

The present research examined the viability and utility of eye lenses as a source of lifetime stable-isotope records in fish. It is presented in three sections. The first section compared bulk isotopic variation (bulk analysis) within fish eye-lenses at two temporal resolutions and compared patterns obtained from left and right eyes. The first temporal resolution was lower in an attempt to expose broad-scale isotopic changes during life while reducing effort and cost. This approach did reveal lifetime patterns, but tended to miss certain life events, particularly during early life. The second resolution was higher and provided detail that was missed …

The Peculiar Nature Of Florida’S Sandhill Wetlands, Ponds & Lakes— Their Ecohydrology, Relationship With The Regional Aquifer & Importance Within The Landscape., Renae Starr Nowicki

USF Tampa Graduate Theses and Dissertations

This dissertation explores the ecohydrology of Florida’s peculiar and poorly studied sandhill wetland and water features, particularly those located in west-central Florida. The primary research goals include: compilation and summarization of the available ecohydrologic information for features across Florida; comparison of water level and water geochemistry data between sandhill wetlands and waters and the regional aquifer to provide evidence of regional hydrologic control; and use of geophysical applications to examine the hydraulic connections between sandhill wetlands and waters and the regional aquifer.

From this research, a natural history of sandhill wetland and water ecohydrology is presented, highlighting: the differences between …

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …

Boron Variation And The Subducted Sediment Component In The Volcanics From The Bifurcated Portion Of The Lesser Antilles Island Arc (Laia), Ami Margret Ngo Ward

USF Tampa Graduate Theses and Dissertations

North of Martinique island the Lesser Antilles volcanic arc bifurcates, creating a double arc. Here volcanic activity has migrated up to 50 km westward with time, resulting in two volcanic lines that are distinct in age. The eastern line, commonly referred to as the old arc, was active from Early Eocene to Mid-Miocene (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., 1988). The western line, commonly referred to as the recent arc, has been active since the late Pliocene, ~6 Ma ago (Nagle, 1971; Nagle et al., 1976; Westercamp and Tazieff, 1980; Andreieff et al., …

On The Ablation Of Meteors And The Implications On Organic Delivery To Earth, Christopher Alan Mehta

USF Tampa Graduate Theses and Dissertations

The synthesis of prebiotic organic compounds is a key step in the origin of life. Sources of these materials are divided into endogenous and exogenous sources. Endogenous synthesis—occurring potentially on the surface of the Earth—includes such historic experiments as the Miller spark discharge and formose chemistry. However, one avenue for exogenous synthesis to occur is when meteors enters an atmosphere. Using principles of orbital mechanics, geology, physics, and chemistry, we study meteor ablation and the transport of organic matter to the surface of Earth. To do so, I create numerical models that simulates meteors traveling through the atmosphere of Earth …

Fluid-Mobile Trace Element Variability Of Serpentinites And Entrained Crustal Rocks Across The Mariana Forearc System, Raymond M. Johnston

USF Tampa Graduate Theses and Dissertations

In the Mariana subduction system, active serpentinite mud volcanoes are associated with the subduction of the Pacific plate beneath the Philippine plate in a non-accretionary convergent plate margin. This location offers a unique opportunity to study the subduction zone interface with little crustal contamination. The systematics of fluid-mobile trace elements (FME) (As, Cs, Rb, Sb, Tl, Pb, and Sr) in erupted serpentinite muds and entrained serpentinized ultramafic and mafic clasts can place constraints on the release of slab-derived fluids from the downgoing plate, and ultimately the pressure/temperature (P/TC°) conditions at which these fluids are mobilized.

The samples analyzed in this …

Stable Isotope Geochemistry Of Shelled Marine Invertebrates: Wide-Ranging Applications, Nasser M. Al-Qattan

USF Tampa Graduate Theses and Dissertations

Mollusks grow by adding discrete growth layers throughout their lifetime (i.e., accretion). More specifically, most marine mollusks precipitate their shells in oxygen isotopic equilibrium with seawater or with a constant offset from equilibrium. The stable oxygen isotope values (δ¹⁸O) of their shells are determined by the temperature and δ¹⁸O values of the surrounding water during calcification without significant vital effects. In comparison, the stable carbon isotope values (δ¹³C) of their shells reflect those of the dissolved inorganic carbon (δ¹³C- DIC) and respired carbon dioxide. Therefore, variations in the oxygen and carbon isotope …

Modeling And Assessing Lava Flow Hazards, Elisabeth Gallant

USF Tampa Graduate Theses and Dissertations

Lava flow hazards are one of the few constant themes across the wide spectrum of volcanic research in the solar system. These dynamic hazards are controlled by the location of the eruption, the topography and material properties of the land upon which the flow spreads, and the properties of the lava (e.g., volume, temperature, and rheology). Understanding the influences on eruption location and how lava flows modify the landscape are important steps to accurately forecast volcanic hazards. Three studies are presented in this dissertation that address di˙erent aspects of modeling and assessing vent opening and lava flow hazards.

The first …

Framing Geologic Numeracy For The Purpose Of Geoscience Education: The Geoscience Quantitative Preparation Survey, Victor J. Ricchezza

USF Tampa Graduate Theses and Dissertations

The Geoscience Quantitative Preparation Survey (GQPS) was developed to address a deficiency in the available literature regarding the competency and preparation of early-career geologists in geoscience job-related quantitative skills – namely, geologic numeracy. The final version of the GQPS included self-confidence, usage, satisfaction, and demographic sections. The GQPS was expected to produce data that would allow for an evaluation of the geologic numeracy of early-career geologists and the success of approximately 20 years of increased focus on quantitatively literate geoscience graduates.

The self-confidence section of the GQPS included quantitative methods and quantitative skills. The usage section asked whether participants used …

Tracking Sediment Bypassing, Geomorphological Analysis, And Regional Sediment Management At Tidal Inlets, Tanya M. Beck

USF Tampa Graduate Theses and Dissertations

Tidal inlets on sandy shorelines separate barrier islands and serve as a conduit for transport of sand and water between embayments and oceans, seas, or other tidally influenced waterbodies. Tides and waves induce currents along the coastline that transport sediment across-shore and alongshore. Coastal managers must optimize barrier-inlet system stability while conserving limited sediment resources, and often base management decisions and engineering design upon geomorphic and numerical models that predict the morphological behavior of tidal inlets on short-to-medium timescales (years to decades). The overall goal of this study was threefold. First, to provide science-based practical guidance for regional sediment management …

Reconstruction Of Radar Images By Using Spherical Mean And Regular Radon Transforms, Ozan Pirbudak

USF Tampa Graduate Theses and Dissertations

The goal of this study is the recovery of functions and finite parametric distributions from their spherical means over spheres and designing a general formula or algorithm for the reconstruction of a function f via its spherical mean transform. The theoretical study is and supported with a numerical implementation based on radar data. In this study, we approach the reconstruction problem in two different way. The first one is to show how the reconstruction problem could be converted to a Prony-type system of equations. After solving this Prony-type system of equations, one can extract the parameters that describe the corresponding …

The Distribution And Biogeochemistry Of Subtropical Intertidal Microbial Mats, Bert D. Anderson

USF Tampa Graduate Theses and Dissertations

Microbial mats have played an important role in the carbon (C) and nutrient cycles since the Archean Eon and modern mats are important contributors to the biogeochemistry of intertidal wetlands. Microbial mats are flat assemblages of microbes that are currently found in many unvegetated habitats globally. Intertidal salt pans are a common habitat for microbial mats, however little is known about the distribution of microbial mats within the intertidal landscape. Understanding the spatial distribution of microbial mats is critical to developing quantitative estimates of the impacts of microbial mats on their ecosystems. We photographically measured the presence and density of …

Rethinking Map Literacy And An Analysis Of Quantitative Map Literacy, Ming Xie

USF Tampa Graduate Theses and Dissertations

Maps are increasingly being used in traditional and virtual media, and civic discourse on political, social, and environmental issues, among others, is more and more becoming influenced by them. The often-used expression of a “picture tells a 1000 words” has never been so apt in our progressively more visual world. Despite this increased role and importance of maps, map literacy, as a field of research, remains rather underdeveloped. This is especially so for thematic maps, the very type of map that is finding increasing currency in discourse. As part of this under-developed nature of map literacy, the quantitative skills used …

Documenting Evolution: Comparing And Contrasting Late Mesozoic And Late Cenozoic Molluscan Patterns, Joshua Slattery

USF Tampa Graduate Theses and Dissertations

Despite major advances, evolutionary theory still has numerous shortcomings in terms of fully understanding the controls on speciation and diversification. A major factor limiting our knowledge is how biology and paleobiology view speciation from separate micro- and macro-evolutionary perspectives, respectively. Biologists typically examine microevolutionary changes within species from various biogeographic, behavioral, morphological, and genetic perspectives, which contrasts to the macroevolutionary approach of most paleobiologists, who have examined the same phenomena at larger scales but with the standpoint of time, have also concentrated on aspects of global or regional diversification (e.g., richness, origination rates, and extinction rates) over the long-term. Noticeably …

Volcanic Electrification: A Multiparametric Case Study Of Sakurajima Volcano, Japan, Cassandra M. Smith

USF Tampa Graduate Theses and Dissertations

Electrical activity at volcanoes has been recently recognized as a potential new remote sensing technique for plume-forming eruptions. Volcanic electrical activity takes place in the conduit and plume and therefore has the benefit of being a direct indicator of surface activity. This is unlike seismic signals, which indicate magma/gas movement underground, and infrasound signals, which indicate a surface explosion but not necessarily the formation of an ash plume. There are two distinct types of volcanic electrical discharges: volcanic lightning and continual radio frequency (CRF) impulses. This dissertation explores the relationships between these two electrical signals and other commonly monitored volcanic …

High-Resolution Investigation Of Event Driven Sedimentation: Response And Evolution Of The Deepwater Horizon Blowout In The Sedimentary System, Rebekka A. Larson

USF Tampa Graduate Theses and Dissertations

This Dissertation combines the investigation of the sedimentological impacts of the Deepwater Horizon (DwH) blowout event in the deep-sea benthos, with the refinement and advancement of methods and approaches for high-resolution investigations of events preserved in sedimentary records. An approach that combined, rapid collection of cores, a continued annual time series collection of cores, and high-resolution sampling and analyses, in particular short-lived Radioisotopes (SLRad), enabled the temporal resolution required to detect the sedimentary response to the short-duration DwH event, and evaluate post-event sedimentation patterns at a comparable time scale (months).

The collection of 179 sediment cores from 80 sites between …

Estimating Coastal Water Turbidity Using Viirs Nighttime Measurement, Chih-Wei Huang

USF Tampa Graduate Theses and Dissertations

Coastal water turbidity is a key environmental factor that influences the relative clarity of the water, which therefore reduces sunlight penetration. The comprehensive spatial and temporal coverage of remote sensing allows mapping of water turbidity near the coast. Even in locations where time-consuming and expensive conventional turbidity monitoring programs exist, local technological limitations prevent complete coverage. Traditional optical satellite techniques using the visible band also have limitations in monitoring turbidity due to non-optimal observing conditions such as clouds, sun-glint, and thick aerosols. In this study, in order to complement the daytime satellite measurements, I used the data from Visible Infrared …

Full-Waveform Inversion Of Common-Offset Ground Penetrating Radar (Gpr) Data, Sajad Jazayeri

USF Tampa Graduate Theses and Dissertations

Maintenance of aging buried infrastructure and reinforced concrete are critical issues in the United States. Inexpensive non-destructive techniques for mapping and imaging infrastructure and defects are an integral component of maintenance. Ground penetrating radar (GPR) is a widely-used non-destructive tool for locating buried infrastructure and for imaging rebar and other features of interest to civil engineers. Conventional acquisition and interpretation of GPR profiles is based on the arrival times of strong reflected/diffracted returns, and qualitative interpretation of return amplitudes. Features are thereby generally well located, but their material properties are only qualitatively assessed. For example, in the typical imaging of …

Variations Of Sedimentary Biogenic Silica In The Gulf Of Mexico During The Deepwater Horizon And Ixtoc-I Oil Spill., Jong Jin Lee

USF Tampa Graduate Theses and Dissertations

The goal of this research is to understand the impacts of the 2010 Deepwater Horizon oil spill and the 1970-1980 IXTOC-I oil spill and other anthropogenic activity (e.g. dam construction) on surface water primary productivity by measuring sedimentary biogenic silica. It is known that sedimentary biogenic silica is distinct from mineral – bound silica, therefore it has been used as a proxy record for surface water primary productivity (e.g. diatom blooms). The Deepwater Horizon oil spill resulted in a widespread Marine Oil Snow Sedimentation and Flocculent Accumulation (MOSSFA) event. The IXTOC-I oil spill was one of the largest oil spills …

Assessing Paleo-Coastal Caves Evolution And Sea Level Changes In Mallorca: Results From Radiometric Dating Of Speleothems, Giuseppe Lucia

USF Tampa Graduate Theses and Dissertations

Sea level affects the littoral morphology and structure in different ways. In coastal karst basins, dissolutional and depositional processes are strictly related to sea level variation. A great variety of karst-related geomorphological features and cave deposits exist above, below, and at sea level, and are extremely useful to study past changes of relative sea level. Within these, vadose speleothems such as flowstones and stalagmite, can document unequivocal maximum sea level constraints as well as record phreatic phases of sea level rise. Here we present a series of geochronological data from the eastern Mallorca and show the implication of relative sea …

Examining The Spatial And Temporal Variations In Co2 Partial Pressure In The Deep Vadose Zone Above Jinapsan Cave, Guam, Jamar Regis

USF Tampa Graduate Theses and Dissertations

Carbon dioxide is the primary driver of dissolution and precipitation reactions in epigene limestone caves. While much work has been conducted on CO2 dynamics involved in dissolution in the phreatic zone, less research has been conducted on vadose CO2 dynamics, especially in tropical caves developed in eogenetic limestones. In this study, we investigate spatial and temporal variation in pCO2 in the deep vadose zone of eogenetic limestone above Jinapsan Cave, located in northern Guam. Five years of carbonate chemistry data from three dripwater sites in Jinapsan Cave (Flatman, Station1, and Trinity) were used to model the theoretical pCO2 with which …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Timing And Rates Of Events In The Generic Volcanic Earthquake Swarm Model, Tianyu Rong

USF Tampa Graduate Theses and Dissertations

In this thesis I combine data from 29 volcanic earthquake swarms that follow the pattern predicted by the Generic Volcanic Earthquake Swarm Model (GVESM; Benoit and McNutt, 1996) to investigate whether the relative timing of various parameters of pre-eruptive volcanic earthquake swarms could be used to forecast the time of an impending eruption. Based on the analysis of seismic unrest preceding many eruptions, the GVESM suggests that it is common to see an increase first in high-frequency earthquakes, then low-frequency earthquakes, then the onset of volcanic tremor. While this pattern is useful to volcano-seismologists, the relative timing and durations of …