Physical Sciences and Mathematics Commons^™

Implications Of An Improved Water Equation Of State For Water-Rich Planets, Chenling Huang, David R. Rice, Zachary M. Grande, Dean Smith, John H. Boisvert, Oliver Tschauner, Ashkan Salamat, Jason Steffen

Geoscience Faculty Research

Water (H2O), in all forms, is an important constituent in planetary bodies, controlling habitability and influencing geological activity. Under conditions found in the interior of many planets, as the pressure increases, the H-bonds in water gradually weaken and are replaced by ionic bonds. Recent experimental measurements of the water equation of state (EOS) showed both a new phase of H-bonded water ice, ice-VIIt, and a relatively low transition pressure just above 30 GPa to ionic bonded ice-X, which has a bulk modulus 2.5 times larger. The higher bulk modulus of ice-X produces larger planets for a given mass, thereby either …

Human Health And Wellness In Space: A Review Of Common Effects, Current Research, And Methods Of Prevention, Sonnet Xu, Rajendra Persaud, Nazrul I. Khandaker, Jasmin Budhan

Publications and Research

Space poses a threat to space crew wellness, where microgravity, isolation, radiation, and other conditions exert strain on human health. This study explores the changes to the human body in space and how it contributes to major threats to health during spaceflights. The effects of the hostile environment of outer space are all examined here, along with resultant changes to behavior, physiology, and the difficulty of remote diagnosis for health treatment in space. This review also considers the implications to the human cartilage, brain, and eyes along with the various other hazards and physiological alterations.

Human health in space is …

Mars 2020: A Step Closer To The Red Planet, Kevin Ng, Matthew Khargie, Omadevi Singh, Sashi Singh, Nazrul I. Khandaker, Rajendra Persaud

Publications and Research

This research paper primarily focuses on the NASA Mars 2020 mission, but will also revisit and discuss past rover missions. As the Mars 2020 mission is ongoing, some information will be updated accordingly. For decades, humans have dreamed of the colonization of Mars for many reasons, such as some similarities shared by Earth and Mars or the close proximity to our planet. In fact, dozens of films, books, and articles have been written, especially in the past 2 decades, about the possibility. As technology advances, we develop newer equipment to hopefully make this possibility into a reality. Of course, placing …

Microgravity And Its Bearing With Space Flight-Related Research, Farhan Tanvir, Nazrul I. Khandaker, Rajendra Persaud, Jeff Guan

Publications and Research

This study investigates the unique properties and applications of microgravity in the context of spaceflight research. Understanding and harnessing the behaviors of a microgravity environment opens up the doors to long-term space travel and consequently, future missions to other planets within our solar system. More specifically, simulating and conducting experiments in microgravity environments helps us explore its effects on the various necessary tasks and behaviors that are carried out during spaceflight. The most immediate and pronounced effects of microgravity are on human physiology. In particular, studies have shown that prolonged exposure to microgravity can result in a 20% decrease in …

Measured Optical Absorption Cross Sections Of Tio, Peter Bernath

Chemistry & Biochemistry Faculty Publications

A laboratory emission spectrum of TiO in the visible and near-infrared regions (476–1176 nm) has been calibrated and corrected. High-resolution experimental absorption cross sections for TiO with natural isotopic abundance are provided at a temperature of about 2300 K. These cross sections have been compared with those derived from the ExoMol line list. The experimental cross sections can be used directly as a template for cross correlation TiO detection in hot Jupiter exoplanets.

The Effect Of The 21 August 2017 Total Solar Eclipse On The Phase Of Vlf/Lf Signals, A. Rozhnoi, M. Solovieva, S. Shalimov, Dimitar Ouzounov, P. Gallagher, G. Verth, J. Mccauley, S. Shelyag, V. Fedun

Mathematics, Physics, and Computer Science Faculty Articles and Research

An experimental study of the phase and amplitude observations of sub‐ionospheric very low and low frequency (VLF/LF) signals is performed to analyze the response of the lower ionosphere during the 21 August 2017 total solar eclipse in the United States of America. Three different sub‐ionospheric wave paths are investigated. The length of the paths varies from 2,200 to 6,400 km, and the signal frequencies are 21.4, 25.2, and 40.75 kHz. The two paths cross the region of the total eclipse, and the third path is in the region of 40–60% of obscuration. None of the signals reveal any noticeable amplitude …

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence …

Photocatalytic Reduction Of Fumarate To Succinate On Zns Mineral Surfaces, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

The reductive tricarboxylic acid (rTCA) cycle is an important central biosynthetic pathway that fixes CO₂ into carboxylic acids. Among the five reductive steps in the rTCA cycle, the two-electron reduction of fumarate to succinate proceeds nonenzymatically on the surface of photoexcited sphalerite (ZnS) colloids suspended in water. This model reaction is chosen to systematically study the surface photoprocess occurring on ZnS in the presence of [Na₂S] (1–10 mM) hole scavenger at 15 °C. Experiments at variable pH (5–10) indicate that monodissociated fumaric acid is the primary electron acceptor forming the monoprotic form of succinic acid. The following …

40ar/39ar Ages Of Lunar Impact Glasses: Relationships Among Ar Diffusivity, Chemical Composition, Shape, And Size, John W. Delano Phd, Nicolle Zellner

Atmospheric and Environmental Science Faculty Scholarship

Lunar impact glasses, which are quenched melts produced during cratering events on the Moon, have the potential to providenot only compositional information about both the local and regional geology of the Moon but also information about the impact flux over time. We present in this paper the results of 73 new 40Ar/39Ar analyses of well-characterized, inclusion-free lunar impact glasses and demonstrate that size, shape, chemical composition, fraction of radiogenic 40Ar retained, and cosmic ray exposure (CRE) ages are important for 40Ar/39Ar investigations of these samples. Specifically, analyses of lunar impact glasses from the Apollo 14, 16, and 17 landing sites …

Hunting Starstuff: Searching For Calcium-Aluminum-Rich Inclusions In Cometary Dust, Christian Engelbrecht

STAR Program Research Presentations

NASA’s Stardust mission (1999 - 2006) returned physical samples of the particles ejected by the comet 81P/Wild 2, collected in ultralight and extremely low density aerogel. These samples have been extensively analyzed using X-Ray Fluorescence (XRF), among other techniques, to determine the elemental, chemical and mineralogical composition of Wild 2. Because comets are thought to be formed in the icy outer regions of the solar system, billions of years ago, the Stardust data gives us details of the composition of the ancient solar system and its subsequent evolution. One of the surprises to come out of the data is the …

Landsat-8: Science And Product Vision For Terrestrial Global Change Research, David P. Roy, M. A. Wulder, T. R. Loveland, C. E. Woodcock, R. G. Allen, M. C. Anderson, D. Helder, J. R. Irons, D. M. Johnson, R. Kennedy, T. A. Scambos, C. B. Schaaf, J. R. Schott, Y. Sheng, E. F. Vermote, A. S. Belward, R. Bindschadler, W. B. Cohen, F. Gao, J. D. Hipple, P. Hostert, Desert Research Institute, Reno, Nv, C. O. Justice, Ayse Kilic, V. Kovalskyy, Z. P. Lee, L. Lymburner, J. G. Masek, J. Mccorkel, Y. Shuai, R. Trezza, J. Vogelmann, R. H. Wynne, Z. Zhu

School of Natural Resources: Faculty Publications

Landsat 8, a NASA and USGS collaboration, acquires global moderate-resolution measurements of the Earth's terrestrial and polar regions in the visible, near-infrared, short wave, and thermal infrared. Landsat 8 extends the remarkable 40 year Landsat record and has enhanced capabilities including new spectral bands in the blue and cirrus cloud-detection portion of the spectrum, two thermal bands, improved sensor signal-to-noise performance and associated improvements in radiometric resolution, and an improved duty cycle that allows collection of a significantly greater number of images per day. This paper introduces the current (2012–2017) Landsat Science Team's efforts to establish an initial understanding of …

Petrography, Stable Isotope Compositions, Microraman Spectroscopy, And Presolar Components Of Roberts Massif 04133: A Reduced Cv3 Carbonaceous Chrondrite, Jemma Davidson, Devin L. Schrader, Conel M. Alexander, Dante S. Lauretta, Henner Busemann, Ian A. Franchi, Richard C. Greenwood, Harold Connolly Jr., Kenneth J. Domanik, Alexander Verchovsky

School of Earth & Environment Faculty Scholarship

Here, we report the mineralogy, petrography, C-N-O-stable isotope compositions, degree of disorder of organic matter, and abundances of presolar components of the chondrite Roberts Massif (RBT) 04133 using a coordinated, multitechnique approach. The results of this study are inconsistent with its initial classification as a Renazzo-like carbonaceous chondrite, and strongly support RBT 04133 being a brecciated, reduced petrologic type >3.3 Vigarano-like carbonaceous (CV) chondrite. RBT 04133 shows no evidence for aqueous alteration. However, it is mildly thermally altered (up to approximately 440 °C); which is apparent in its whole-rock C and N isotopic compositions, the degree of disorder of C …

Laboratory Astrophysics: Using Ebit Measurements To Interpret High Resolution Spectra From Celestial Sources, Carey Scott, Joshua Thompson, N. Hell, Greg V. Brown

STAR Program Research Presentations

Astrophysicists use radiation to investigate the physics controlling a variety of celestial sources, including stellar atmospheres, black holes, and binary systems. By measuring the spectrum of the emitted radiation, astrophysicists can determine a source’s temperature and composition. Accurate atomic data are needed for reliably interpreting these spectra. Here we present an overview of how LLNL’s EBIT facility is used to put the atomic data on sound footing for use by the high energy astrophysics community.