Physical Sciences and Mathematics Commons^™

Halogen And Non-Traditional Isotope Geochemistry Of Planetary And Terrestrial Materials, Anthony Gargano, Zachary Sharp, Justin Simon, Charles Shearer, Adrian Brearley, James Day

Earth and Planetary Sciences ETDs

This dissertation presents the advances in non-traditional isotope geochemistry of planetary and terrestrial materials encompassing chlorine, sulfur, and zinc isotopes, as well as halogen geochemistry. A wide breadth of materials was studied throughout the completion of this work including iron meteorites, achondrites, chondrites, Apollo lunar samples, as well ancient marine chert, and carbonate sediments. Much of the focus involved the development of a method capable of simultaneously measuring the halogen contents and chlorine isotope compositions of geological materials. Here, I present these data sets to broadly characterize the process of devolatilization of planetary materials, and specifically the problem of ‘halogen-poisoning’ …

Petrology And Geochemistry Of Evolved Achondrites: Planetesimal Mantles And Crusts, Zoltan Vaci

Earth and Planetary Sciences ETDs

Melting and differentiation are fundamental to early solar system evolution on planetary bodies that accreted enough material to heat up radioactively or through impacts and breach their solidi. Partially and fully melted material is present in the meteorite record in the form of primitive achondrites and achondrites, which are fragments of planetesimals that underwent heating events in the first few million years of solar system history. Although the vast majority of this material is mafic or ultramafic, new evolved samples, recovered in the last few decades, are pushing the petrologic and geochemical boundaries of planetesimal melting, differentiation, and crust formation. …

Microstructural And Microchemical Studies Of Fluid–Chondrule Interactions In A Pristine Cr Carbonaceous Chondrite And Apatite In Martian Nakhlites, Marina Martínez

Earth and Planetary Sciences ETDs

PROJECT 1: Chondrites are the most primitive objects in the solar system, aggregates of the material that formed in the solar protoplanetary disk during the first 1-5 million years of its formation. However, petrographic observations indicate that most chondrites have been modified by secondary processes, including aqueous alteration, thermal metamorphism, and shock. Fortunately, a few chondrites largely escaped these processes and are considered pristine, such as the CR carbonaceous chondrite Queen Alexandra Range (QUE) 99177. QUE 99177 is an excellent sample for deciphering information about the reactions that took place between unaltered anhydrous solar nebular components and water under highly …

Microstructural Constraints On The Nebular And Asteroidal Histories Of Calcium-Aluminum-Rich Inclusions From Cv3 Chondrites, Shaofan Che

Earth and Planetary Sciences ETDs

The petrology and mineralogy of calcium-aluminum-rich inclusions (CAIs) from CV3 carbonaceous chondrites have been investigated using transmission electron microscopy (TEM). The goal of this dissertation is twofold: (1) to gain new insights into the nebular processes, such as vapor-solid reactions, accretion, transport, that are responsible for the formation of non-igneous CAIs, and (2) to better understand the role of fluid in the secondary alteration of CAIs on the CV3 chondrite parent body. This work represents the first systematic microstructural study of CAIs from CV3 chondrites.

Chapter 2 presents the microstructural observations of primary mineralogies of fine-grained, spinel-rich inclusions (FGIs) from …

Magmatic Hydrothermal Alteration And Secondary Post-Shock Features In Martian Olivine-Phyric Basalt Northwest Africa 10416; Petrology And Geochemistry Of Primitive Achondrite Northwest Africa 11042, Zoltan Vaci

Earth and Planetary Sciences ETDs

The Martian olivine-phyric basalt Northwest Africa (NWA) 10416 contains large olivine xenocrysts whose cores have been stained brown by hydrothermal alteration and whose rims are composed of pristine olivine overgrowths. Microanalysis of these olivine cores reveals various degrees of amorphization, some of which have been overprinted by terrestrial weathering, evident as part of a weathering rind along the exposed surface of the meteorite. Studies of a completely unweathered terrestrial analogue basalt from southern Colorado reveal similar features and indicate that both basalts were altered in a supersolidus magma chamber setting. The alteration features in NWA 10416 thus imply the presence …