Physical Sciences and Mathematics Commons^™

Fabrication And Modification Of Titania Nanotube Arrays For Harvesting Solar Energy And Drug Delivery Applications, Ahmed El Ruby Abdel Rahman Mohamed

Electronic Thesis and Dissertation Repository

The fast diminishing of fossil fuels in the near future, as well as the global warming caused by increasing greenhouse gases have motivated the urgent quest to develop advanced materials as cost-effective photoanodes for solar light harvesting and many other photocatalytic applications. Recently, titania nanotube arrays (TNTAs) fabricated by anodization process has attracted great interest due to their excellent properties such as: high surface area, vertically oriented, highly organized, one-dimensional, nanotubular structure, photoactivity, chemical stability and biocompatibility. This unique combination of excellent properties makes TNTAs an excellent photoanode for solar light harvesting. However, the relatively wide band gap energy of …

An Evaluation Of Borehole Hydraulic Conductivity Equations And Field Determined Soil Water Characteristic Curves, Johnathan Dale Blanchard

Graduate Theses and Dissertations

The methods utilized to determine the hydraulic conductivity of compacted clay liners (CCLs) are of importance for safe guarding the environment from landfill leachate. Therefore, the methods utilized in the analysis of the Two Stage Borehole (TSB) test, as described in the ASTM D6391-11 (Method A, B, and C) standard, were evaluated. Data from hydraulic conductivity tests, as performed on three test pads, were utilized to review the ASTM D6391-11 equations. Additionally, two test pads were instrumented with volumetric water content and soil water matric potential sensors to facilitate the determination of field-obtained soil water characteristic curves (SWCCs) and hydraulic …

Evaluation Of Water Resources And Hydraulic Influences In The Restoration Of The Western Part Of The Mesopotamian Marshlands, Ali Kareem Al-Quraishi

Graduate Theses and Dissertations

The purpose of this study is to assess the water resources and water conveyance system of the western part of the Mesopotamian marshes (Al-Hammar marsh) as well as develop a water conveyance system to distribute water throughout the western Al-Hammar marsh. These processes are significant to identify the current restoration problems and help to create restoration strategies for the marsh. Also, proper management strategy to the Al-Hammar marsh is necessary to preserve the marsh ecosystem, irrigate lands, and provide domestic necessities in the villages.

The overall project is divided into three main chapters which address the current ecological and hydrological …

Transformation Of Nonlinear Waves In The Presence Of Wind, Current, And Vegetation, Haifei Chen

Electronic Theses and Dissertations

Accurate prediction of extreme wave events is crucial for the safe maritime activities and offshore operations. Improved knowledge of wave dissipation mechanisms due to breaking and vegetation leads to accurate wave forecast, protecting life and property along the coast. The scope of the thesis is to examine the wave transformations in the presence of wind, current, and vegetation, using a two-phase flow solver based on the open-source platform OpenFOAM. The Reynolds-Averaged Navier-Stokes (RANS) equations are coupled with a Volume of Fluid (VOF) surface capturing scheme and a turbulence closure model. This RANS-VOF model is adapted to develop a numerical wind-wave-current …

Longitudinal Thermal And Solute Dynamics In Regulated Rivers, Muhammad Rezaul Haider

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Dam releases increase river stage and can reverse groundwater movement into and out of the river. As the flood, thermal, and solute waves travel downstream in a regulated river, the size of the waves is anticipated to be affected both by river processes and exchanges with near river groundwater. This study established a modeling framework to quantify the influences of the groundwater exchanges on the temperatures and solute concentration dynamics along regulated rivers. The wave properties, volume of exchanges, conservative solute mass exchanges, and heat energy exchanges were calculated as a function of time and distance downstream. Results show that …

Stream Temperature Monitoring And Modeling To Inform Restoration: A Study Of Thermal Variability In The Western Us, Jessica R. Wood

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Water temperature is an important variable for aquatic ecosystems. Salmonid population numbers and distribution are heavily influenced by stream temperature, and there is growing concern about the health of salmonid populations with anticipated climate change. Managers are looking to efficiently evaluate options to maintain stream temperatures needed by salmonids. This study evaluated and compared stream temperature restoration alternatives in two streams with warm temperatures using stream temperature monitoring and modeling.

The first study identified pockets of cold water that are important to native fish species in Nevada’s Walker River. Comparison of monitoring results with existing basin-scale model outputs identified two …

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH₄, CO₂) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH₄ and CO₂ at all sampling dates and locations. Concentrations of dissolved CH₄ and CO₂ ranged …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Investigation Of Setting Time And Compressive Strength Of Ready-Mixed Concrete Blended With Returned Fresh Concrete, Negasi Niguse Gebremichael

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Center for Sustainable Transportation Infrastructure (CSTI), in its 2012 study, estimated that out of all the concrete leaving the plant, between 2% and 7% of concrete returns to the plant unused as a returned fresh concrete (RFC). Disposal of both the truck wash water and RFC is a growing concern for the industry. Most industry personnel contacted during the investigation, agree that reusing is superior to recycling of this substantial RFC economically and environmentally. This study will determine if the reuse of RFC in subsequent batches compromises the quality of newly blended concrete.

The effect of RFC on fresh …

Multi-Dimensional Drought Risk Assessment Based On Socio-Economic Vulnerabilities And Hydro-Climatological Factors, Ali Ahmadalipour

Dissertations and Theses

Drought is among the costliest natural hazards developing slowly and affecting large areas, which imposes severe consequences on society and economy. Anthropogenic climate change is expected to exacerbate drought in various regions of the globe, making its associated socioeconomic impacts more severe. Such impacts are of higher concern in Africa, which is mainly characterized by arid climate and lacking infrastructure as well as social development. Furthermore, the continent is expected to experience vast population growth, which will make it more vulnerable to the adverse effects of drought. This study provides the first comprehensive multi-dimensional assessment of drought risk across the …

Analysis Of The Acid-Base Balance Of Mainstream Tobacco Smoke And Its Effect On The Gas/Particle Partitioning Of Nicotine, Amy Kathleen Devita-Mcbride

Dissertations and Theses

Tobacco smoke particulate matter (PM) is a complex mixture of condensed organic compounds, with about 5 to 10% water. Its general properties are similar in some respects to that of atmospheric organic aerosol PM and thus provides a useful surrogate when studying atmospheric PM. Due to its ability to undergo acid-base chemistry, nicotine is of particular interest in the tobacco smoke system. The gas/particle partitioning of nicotine depends on the protonation state of nicotine in the particles, so the distribution of nicotine between these phases provides a means of understanding the acid-base balance in the tobacco smoke system. The goal …

Hydrogeochemical Investigation Of Recharge Pathways To Intermediate And Regional Groundwater In Cañon De Valle And Technical Area 16, Los Alamos National Laboratory, Brendan W. Brady

Civil Engineering ETDs

In aquifers consisting of fractured or porous igneous rocks, as well as conglomerate and sandstone products of volcanic formations, silicate minerals actively dissolve and precipitate (Eby, 2004; Eriksson, 1985; Drever, 1982). Dissolution of hydrated volcanic glass is also known to influence the character of groundwater to which it is exposed (White et al., 1980). Hydrochemical evolution, within saturated zones of volcanic formations, is modeled here as a means to resolve the sources feeding a perched groundwater zone. By observation of solute mass balances in groundwater, together with rock chemistry, this study characterizes the chemical weathering processes active along recharge pathways …

An Enhanced Bridge Weigh-In-Motion Methodology And A Bayesian Framework For Predicting Extreme Traffic Load Effects Of Bridges, Yang Yu

LSU Doctoral Dissertations

In the past few decades, the rapid growth of traffic volume and weight, and the aging of transportation infrastructures have raised serious concerns over transportation safety. Under these circumstances, vehicle overweight enforcement and bridge condition assessment through structural health monitoring (SHM) have become critical to the protection of the safety of the public and transportation infrastructures. The main objectives of this dissertation are to: (1) develop an enhanced bridge weigh-in-motion (BWIM) methodology that can be integrated into the SHM system for overweight enforcement and monitoring traffic loading; (2) present a Bayesian framework to predict the extreme traffic load effects (LEs) …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Sustainability Of Community-Managed Rural Water Supply Systems In Amazonas, Peru: Assessing Monitoring Tools And External Support Provision, Jacob E. Mangum

USF Tampa Graduate Theses and Dissertations

Globally, there is still a large number of people without access to safe drinking water; a known health risk. In rural areas of countries like Peru, when potable water systems are built the responsibility for maintaining these systems is given to volunteer water committees. Despite its prevalence as a management model, there is a consensus that community management alone cannot ensure sustainable water service. Therefore, the overall goal of this research is to assess the sustainability of community-managed water systems in rural areas of the department of Amazonas, Peru. Specifically, this research examines two mechanisms that have been shown to …

Elution Tailing Of Nonaqueous Phase Liquids In Porous Media, Louisa Orr

Civil and Environmental Engineering Undergraduate Honors Theses

A variety of porous media were studied to characterize contaminant dispersion over time. This work looked at a compilation of previously published studies to investigate the dependence of long term elution tailing trends on particular soil characteristics. Recession curve analysis was conducted on existing dispersed contaminant literature, to yield the low-concentration recession constant (K). The R² values correlating the soil properties to contaminant concentration ranged from 0.12494 to 0.95429. The low-concentration recession constant (K) values ranged from 0.9745407 0.9999988. The relationship between K and the soil properties porosity, organic carbon, and fines fraction is increasing. Bulk density and the …

Quantifying Pollutant Removal Rates Of Bioretention Basins As A Stormwater Best Management Practice, Evan Nathanial Waagen

Civil & Environmental Engineering Theses & Dissertations

Water pollution is an ongoing problem that can be attributed to human activities. As world population increases and countries become more developed, this problem intensifies. Fortunately, the causes and solutions of water pollution are documented and have been implemented with various levels of success. These solutions, or Best Management Practices (BMPs), vary in type and function and remove pollutants from runoff prior to it reaching rivers, lakes, and other bodies of water. This study investigates bioretention basins, a specific group of BMPs, and presents analysis and prediction of their performance, of which our knowledge is incomplete in the existing literature. …

Study On Ship Emissions And Countermeasures In Shanghai Port, Yunfeng Zhang

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Models And Policies Of Port Carbon Emission Reduction: A Case Study Of The Port Of Dalian, Jiaqiong Zhao

World Maritime University Dissertations

No abstract provided.

Aluminosilicate Dissolution And Silicate Carbonation During Geologic Co2 Sequestration, Yujia Min

McKelvey School of Engineering Theses & Dissertations

Geologic CO2 sequestration (GCS) is considered a promising method to reduce anthropogenic CO2 emission. Assessing the supercritical CO2 (scCO2)¬–gas or liquid phase water (g, l)–mineral interactions is critical to evaluating the viability of GCS processes. This work contributes to our understanding of geochemical reactions at CO2¬–water (g, l)–mineral interfaces, by investigating the dissolution of aluminosilicates in CO2-acidified water (l). Plagioclase and biotite were chosen as model minerals in reservoir rock and caprock, respectively. To elucidate the effects of brine chemistry, first, the influences of cations in brine including Na, Ca, and K, have been investigated. In addition to the cations, …

Window Inserts And The People Adopting Them: Building Sustainable Communities In Maine, Daniel Sean Mistro

Electronic Theses and Dissertations

Residents of Maine face a large monetary expense to heat their homes in the winter. In Maine it takes 540 gallons of heating oil each year to heat a typical home [1]. Interior window inserts may be a practical solution to improve comfort, save money, and consume less environmentally harmful fossil fuels during cold winter months. The window inserts discussed in this paper are custom measured to fit into a window and consist of a wooden frame that is wrapped in two layers of polyolefin film and weather stripped for a snug fit. Commercial inserts cost $20-$36/square foot, or approximately …

On The Ramberg-Osgood Stress-Strain Model And Large Deformations Of Cantilever Beams, Ronald J. Giardina Jr

University of New Orleans Theses and Dissertations

In this thesis the Ramberg-Osgood nonlinear model for describing the behavior of many different materials is investigated. A brief overview of the model as it is currently used in the literature is undertaken and several misunderstandings and possible pitfalls in its application is pointed out, especially as it pertains to more recent approaches to finding solutions involving the model. There is an investigation of the displacement of a cantilever beam under a combined loading consisting of a distributed load across the entire length of the beam and a point load at its end and new solutions to this problem are …

Soil-Structure Interaction Effects On The Seismic Response Of Low-Rise Eccentrically Braced Frames, Luis Gerardo Buitrago Goyez

Graduate Theses and Dissertations

The importance of soil-structure interaction (SSI) effects on the seismic response of

buildings has been long recognized and has been researched for over 40 years. However, SSI

analysis has only been applied in a few building projects because the fixed base condition is

considered to provide a conservative estimation for the response of buildings under seismic loads.

This assumption of a fixed base condition adopted by practitioners is not always conservative or

cost-effective, especially for rigid buildings over soft soils. Additionally, for the case of ductile

steel frames with eccentric configurations, the influence of SSI on their seismic performance has …

Laboratory Resistivity Measurements For Soil Characterization, Behdad Mofarraj Kouchaki

Graduate Theses and Dissertations

Field based electrical resistivity measurements, such as electrical resistivity tomography (ERT) and capacitively coupled resistivity (CCR), are geophysical methods that offer a non-destructive and rapid means to collect continuous data. As such, ERT and CCR are becoming increasingly popular tools for geotechnical engineers; however, it is challenging to derive geotechnical information such as soil type, density, and water content from the data. A laboratory geophysical investigation was carried out to gain a better understanding of the parameters that affect the electrical resistivity of soils and devise a relationship between resistivity and soil type or classification. In this study, a soil …

Geophysical Assessment Of Kinion Lake Dam, Tim Allen Moody

Graduate Theses and Dissertations

Geophysical methods including Capacitively-Coupled Resistivity (CCR), Electrical Resistivity Tomography/Imaging (ERT/ERI), Multichannel Analysis of Surface Waves (MASW) with Love and Rayleigh waves and a Full-Waveform Inversion (FWI) were performed on Kinion Lake Dam, an earth-filled embankment dam that has historically experienced significant seepage and internal erosion issues. Surveys were completed along the crest and downstream toe of the dam. Results from the surveys indicate that each method is capable of resolving the bedrock depth within 1-2 m of locations shown on previous drilling logs, though some discrepancies between the methods exist. A weathered bedrock layer is believed to have led to …

Remote Sensing Of The Environmental Impacts Of Utility-Scale Solar Energy Plants, Mohammad Masih Edalat

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solar energy has many environmental benefits compared with fossil fuels but solar farming can have environmental impacts especially during construction and development. Thus, in order to enhance environmental sustainability, it is imperative to understand the environmental impacts of utility-scale solar energy (USSE) plants. During recent decades, remote sensing techniques and geographic information systems have become standard techniques in environmental applications. In this study, the environmental impacts of USSE plants are investigated by analyzing changes to land surface characteristics using remote sensing. The surface characteristics studied include land cover, land surface temperature, and hydrological response whereas changes are mapped by comparing …

Development Of Lower Rio Grande River Water Quality Transportation Numerical Model For Bi-National River Management, Jose O. Gonzalez

Theses and Dissertations

Traditionally, water quality modelling has focused on modelling individual water bodies. However, water quality management problems must be analyzed at the larger scale to include influences from various water bodies that are interconnected. This paper provides a study on the hydrologic and quality transportation calculation by developing a hydrodynamic (unsteady state) channel routing model using a water-balanced approach. A one dimension Lagrangian river model was developed and applied to the 210 plus miles for the lower Rio Grande River Basin from the Falcon Dam to the head water of Brownsville that pours onto the Gulf of Mexico. This model can …

A Statistical Investigation Of Lower Columbia River Water Temperature, 1915-2003, Corina Christina Mae Overman

Civil and Environmental Engineering Undergraduate Honors Theses

The Columbia River is home to anadromous salmon populations that migrate upriver every year to spawn. These fish require cool water temperatures (T_w) to survive. In recent years, high summer T_w in the Columbia River has caused increased mortality of salmon. Different possible explanations for increased T_w include climate change, deforestation, and decreased summertime streamflow (Q) due to dams. In this study, robust linear regression models of T_w based on air temperature (T_a) and Q were developed to examine the change in T_w over time. The data was …

Pore Resolved Simulations Of Char Particle Gasification, Greg Hingwah Fong

Master's Theses (2009 -)

Coal is a significant source of energy in today’s world and many studies have been conducted in order to better understand and optimize its use. To address greenhouse effects associated with coal combustion, cleaner methods for harnessing its energy are being explored. One such method is gasification, a process which converts coal into syngas, a mixture consisting primarily of H2 and CO. Syngas can be used to generate electricity or to produce hydrocarbons that can be used as fuels. To better understand and optimize the process, simulations can be used to study the gasification of individual porous char particles that …