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Full-Text Articles in Physical Sciences and Mathematics

Modeling Groundwater Flow And Contaminant Transporting Fractured Aquifers, Jason M. Bordas Mar 2005

Modeling Groundwater Flow And Contaminant Transporting Fractured Aquifers, Jason M. Bordas

Theses and Dissertations

The hybrid discrete fracture network/equivalent porous medium (DFN/EPM) model was selected for analysis and application to simulate a contaminated site in this study. The DFN/EPM was selected because it appeared to have the potential to aid decision making by remedial project managers at contaminated DoD fractured aquifer sites. This model can use data that are typically available at a site while incorporating the important processes relevant to describing contaminant transport in a fractured medium. The model was applied to simulate the operation of a pump-and-treat remedial action at a trichloroethene-contaminated fractured aquifer at Pease AFB. The model was able to …


Validation Of An Innovative Groundwater Contaminant Flux Measurement Method, Seh J. Kim Mar 2005

Validation Of An Innovative Groundwater Contaminant Flux Measurement Method, Seh J. Kim

Theses and Dissertations

The ability to measure groundwater contaminant flux is increasingly being recognized as crucial in order to prioritize contaminated site cleanups, estimate the efficiency of remediation technologies, measure rates of natural attenuation, and apply proper source terms to model groundwater contaminant transport. An innovative mass flux measurement method using horizontal flow treatment wells (HFTWs) was developed recently to compensate for the disadvantages of other flux measurement methods that are being used. Flux measurement methods can be categorized as either point methods or integral methods. As the name suggests, point methods measure flux at a specific point or points in the subsurface. …


Modeling Application Of Hydrogen Release Compound To Effect In Situ Bioremediation Of Chlorinated Solvent-Contaminated Groundwater, Ryan C. Wood Mar 2005

Modeling Application Of Hydrogen Release Compound To Effect In Situ Bioremediation Of Chlorinated Solvent-Contaminated Groundwater, Ryan C. Wood

Theses and Dissertations

This study investigates how application of Hydrogen Release Compound (HRC) might be implemented to remediate a site contaminated with tetrachloroethene (PCE) or its daughter products, under varying site conditions. The 3-D reactive transport model RT3D was coupled with a dual-Monod biodegradation submodel to simulate the effect of the hydrogen generated by HRC on accelerating the biodegradation of dissolved chlorinated solvents. Varying site conditions and injection well configurations were investigated to determine the effect of these environmental and design conditions on overall treatment efficiency. The model was applied to data obtained at a chlorinated solvent contaminated site at Vandenberg AFB, where …


An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney Mar 2005

An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney

Theses and Dissertations

In this study, application of a catalytic reactor to facilitate chemical reduction of perchlorate was investigated. Palladium-coated pellets were used as the catalyst, and formic acid was used as the reductant. Reactor performance was evaluated under a variety of operating conditions (influent pH, reductant concentration, residence time). Very little perchlorate reduction was observed under any operating condition. At best, approximately 8% perchlorate reduction was observed. This small reduction efficiency is clearly not sufficient for environmental treatment applications. Perchlorate strongly adsorbed to the catalyst at low pH (3 - 3.3). At higher pH (4 - 10), little adsorption was observed. This …