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Full-Text Articles in Physical Sciences and Mathematics
Optimization Of Simple And Inexpensive Paper-Based Assay For Lead, Kyla Dewittie, Sagar S. Patel
Optimization Of Simple And Inexpensive Paper-Based Assay For Lead, Kyla Dewittie, Sagar S. Patel
Summer Scholarship, Creative Arts and Research Projects (SCARP)
The Environmental Protection Agency (EPA) guidelines state that lead is a toxic metal that humans should not be exposed to in any amount. Due to corrosion of water pipes, lead can enter drinking water and be consumed by millions of people. As a group, we decided to reduce this issue by creating a simple and inexpensive paper-based test to detect lead(II) in water. The signal for this test results from encapsulating a phenanthroline-based probe in synthesized polymer nanoparticles. This test will display a colorimetric change, turning from yellow to bright orange if lead(II) is present in the water system. In …
Green Chemistry: Progress And Barriers, Sarah A. Green
Green Chemistry: Progress And Barriers, Sarah A. Green
Michigan Tech Publications
Green chemistry can advance both the health of the environment and the primary objectives of the chemical enterprise: to understand the behavior of chemical substances and to use that knowledge to make useful substances. We expect chemical research and manufacturing to be done in a manner that preserves the health and safety of workers; green chemistry extends that expectation to encompass the health and safety of the planet. While green chemistry may currently be treated as an independent branch of research, it should, like safety, eventually become integral to all chemistry activities. While enormous progress has been made in shifting …
Dinosolve: A Protein Disulfide Bonding Prediction Server Using Context-Based Features To Enhance Prediction Accuracy, Ashraf Yaseen, Yaohang Li
Dinosolve: A Protein Disulfide Bonding Prediction Server Using Context-Based Features To Enhance Prediction Accuracy, Ashraf Yaseen, Yaohang Li
Computer Science Faculty Publications
Background: Disulfide bonds play an important role in protein folding and structure stability. Accurately predicting disulfide bonds from protein sequences is important for modeling the structural and functional characteristics of many proteins.
Methods: In this work, we introduce an approach of enhancing disulfide bonding prediction accuracy by taking advantage of context-based features. We firstly derive the first-order and second-order mean-force potentials according to the amino acid environment around the cysteine residues from large number of cysteine samples. The mean-force potentials are integrated as context-based scores to estimate the favorability of a cysteine residue in disulfide bonding state as well as …
Highly Visible Light Active Tio2-Xnx Heterojunction Photocatalysts, Vinodkumar Etacheri, Michael Seery, Steven Hinder, Suresh Pillai
Highly Visible Light Active Tio2-Xnx Heterojunction Photocatalysts, Vinodkumar Etacheri, Michael Seery, Steven Hinder, Suresh Pillai
Articles
Nitrogen doped anatase-rutile heterojunctions are successfully synthesized through an ethylene-diaminetetraacetic acid (EDTA) modified sol-gel process.An FT-IR study of EDTA modified TiO2 gel confirms the existence of an ionic intermediate (as indicated by a Δν value of 233 cm-1).Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and Raman spectroscopy are employed to study the phase evolution, phase purity, and crystallite size of samples. Formations of O-Ti-N and N-Ti-N bonds in calcined samples are confirmed using XPS and FT-IR spectro- scopy. AllEDTAmodified samples show significantly higher visible light photocatalytic activity than the unmodified sample. The most active nitrogen doped heterojunction obtained at 400C …
Silver Doped Titanium Dioxide Nanomaterials For Enhanced Visible Light Photocatalysis, Michael Seery, Reena George, Suresh Pillai, Patrick Floris
Silver Doped Titanium Dioxide Nanomaterials For Enhanced Visible Light Photocatalysis, Michael Seery, Reena George, Suresh Pillai, Patrick Floris
Articles
This paper presents a systematic study on two different preparation methods for titanium dioxide with silver. The silver can be incorporated by irradiating the reaction mixture during preparation to reduce silver ion to silver metal or by direct calcination of the sol–gel material to decompose silver nitrate to silver. Of the two methods, we found the latter produces a more effective photocatalytic material (6–50% improvement in catalytic efficiency), which is attributed to the fact that the silver is homogeneously dispersed throughout the material. The efficiency of the materials were examined using a Q-Sun solar simulator (visible light) and in Dublin …
Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan
Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan
KWRRI Research Reports
The purpose of this project was to explore the advantages and/or limitations of high-energy radiation treatment as a method for degrading organic pollutants, particularly aryl halides, in an aqueous medium. We have done analyses of 60Co-irradiated samples and kinetic studies using pulsed electron beams. For aryl halides containing no more than two fused rings, the main products detected are those of simple halogen replacement by hydrogen, although the amount of aryl halide destroyed was always greater than the total amount of products detected. To accomplish halogen replacement by H, the reaction solvent may not be pure water but must …