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Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Significance Of Polycyclic Aromatic Hydrocarbons (Pahs) And Petroleum Biomarker Compounds In Contaminated Passaic River Sediments, Michael A. Kruge
Significance Of Polycyclic Aromatic Hydrocarbons (Pahs) And Petroleum Biomarker Compounds In Contaminated Passaic River Sediments, Michael A. Kruge
Department of Earth and Environmental Studies Faculty Scholarship and Creative Works
The lower Passaic River (northeastern New Jersey) flows through one of the most densely populated regions of the United States. The area’s long history of industrial activity is reflected in the complex and variable hydrocarbon composition of the river sediments. Sediments from river bottom grab samples at Newark and a 30 cm deep core at Kearny were subjected to thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). This technique offers a practical alternative for rapid, inexpensive analysis, simply employing milligram quantities of dry, disaggregated sediment, avoiding the use of hazardous organic solvents. For each sample, a total of 181 hydrocarbons and organosulfur compounds …
The Role Of Enzyme Dynamics And Tunnelling In Catalysing Hydride Transfer: Studies Of Distal Mutants Of Dihydrofolate Reductase, Lin Wang, Nina Goodey, Stephen J. Benkovic, Amnon Kohen
The Role Of Enzyme Dynamics And Tunnelling In Catalysing Hydride Transfer: Studies Of Distal Mutants Of Dihydrofolate Reductase, Lin Wang, Nina Goodey, Stephen J. Benkovic, Amnon Kohen
Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works
Residues M42 and G121 of Escherichia coli dihydrofolate reductase (ecDHFR) are on opposite sides of the catalytic centre (15 and 19 Å away from it, respectively). Theoretical studies have suggested that these distal residues might be part of a dynamics network coupled to the reaction catalysed at the active site. The ecDHFR mutant G121V has been extensively studied and appeared to have a significant effect on rate, but only a mild effect on the nature of H-transfer. The present work examines the effect of M42W on the physical nature of the catalysed hydride transfer step. Intrinsic kinetic isotope effects (KIEs), …
Properties Of New York/New Jersey Harbor Sediments, K. W. Jones, Huan Feng, E. A. Stren, U. Neuhäusler, J. Osán, N. Marinkovic, Z. Song
Properties Of New York/New Jersey Harbor Sediments, K. W. Jones, Huan Feng, E. A. Stren, U. Neuhäusler, J. Osán, N. Marinkovic, Z. Song
Department of Earth and Environmental Studies Faculty Scholarship and Creative Works
Sediments found in waterways around the world may contain toxic compounds of anthropogeilic origin that can harm the environment and human health. As a result, it is often necessary to remove them and find disposal methods that are environmentally and economically acceptable. Here, we report on results obtained in an experimental program to characterize the nature of the sediment contamination. The objective was to gain a better understanding of the properties of the sediments to develop better methods for understanding the fate and transport of the contaminants and for improving methods for their removal from the sediments. Our investigations made …