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Physical Sciences and Mathematics Commons

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Chemistry

UNLV Theses, Dissertations, Professional Papers, and Capstones

Theses/Dissertations

2018

Plutonium

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Full-Text Articles in Physical Sciences and Mathematics

Solvent Extraction And Extraction Chromatography Of Homologs And Pseudohomologs Of Rutherfordium Using Teha And Tehp, Jeffrey Rolfes May 2018

Solvent Extraction And Extraction Chromatography Of Homologs And Pseudohomologs Of Rutherfordium Using Teha And Tehp, Jeffrey Rolfes

UNLV Theses, Dissertations, Professional Papers, and Capstones

Studies of the chemical properties of the heaviest elements have always been difficult due to the short half-lives and low cross sections involved. To solve this problem, atom-at-a-time methods are necessary to determine the properties of these short-lived isotopes. Extremely fast kinetics for the chemical reactions studied (on the same order as the nuclide’s half-life) are required, and the system should have the potential for automation. Solvent extraction, with its selectivity and quick kinetics, has historically been used for these investigations into characteristics of super heavy elements. Another technique, extraction chromatography, offers potentially a way of investigating rutherfordium’s properties, without …