Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Exploring The Silent Aspect Of Carbon Nanopores, Teresa J. Bandosz
Exploring The Silent Aspect Of Carbon Nanopores, Teresa J. Bandosz
Publications and Research
Recently, owing to the discovery of graphene, porous carbons experienced a revitalization in their explorations. However, nowadays, the focus is more on search for suitable energy advancing catalysts sensing, energy storage or thermal/light absorbing features than on separations. In many of these processes, adsorption, although not emphasized sufficiently, can be a significant step. It can just provide a surface accumulation of molecules used in other application-driving chemical or physical phenomena or can be even an additional mechanism adding to the efficiency of the overall performance. However, that aspect of confined molecules in pores and their involvement in the overall performance …
Tio2/S-Doped Carbons Hybrids: Analysis Of Their Interfacial And Surface Features, Teresa Bandosz, Alfonso Policicchio, Marc Florent, Po S. Poon, Juan Matos
Tio2/S-Doped Carbons Hybrids: Analysis Of Their Interfacial And Surface Features, Teresa Bandosz, Alfonso Policicchio, Marc Florent, Po S. Poon, Juan Matos
Publications and Research
Hybrids containing approximately equal amounts of P25 TiO2 and S-doped porous carbons were prepared using a water-based slurry mixing method. The materials were extensively characterized by adsorption of nitrogen, potentiometric titration, thermal analysis in air and in helium, XRD, XPS and SEM. The collected results showed the significant blockage of carbon micropores by TiO2 particles deposited on their outer surface. The formation of a new interface, especially for the S-rich samples, might also contribute to the porosity alteration. Analysis of surface chemistry suggested the presence of Ti-S bonds with an involvement of sulfur from thiophenic species in the carbon phase. …
Efficient Air Desulfurization Catalysts Derived From Pig Manure Liquefaction Char, Rajiv Wallace, Sundaramurthy Suresh, Elham H. Fini, Teresa Bandosz
Efficient Air Desulfurization Catalysts Derived From Pig Manure Liquefaction Char, Rajiv Wallace, Sundaramurthy Suresh, Elham H. Fini, Teresa Bandosz
Publications and Research
Biochar from the liquefaction of pig manure was used as a precursor of H2S desulfurization adsorbents. In its inorganic matter, it contains marked quantities of calcium, magnesium and iron, which are known as hydrogen sulfide oxidation catalysts. The char was used either as-received or mixed with 10% nanographite. The latter was added to increase both the content of the carbon phase and conductivity. ZnCl2 in two different ratios of char to an activation agent (1:1 and 1:2) was used to create the porosity in the carbon phase. The content of the later was between 18–45%. The activated samples adsorbed 144 …