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Chemistry

Honors Theses

2017

Doping kinetics

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Kinetic Study Of Conjugated Polymer Packing And Agglomeration, Skye R. Travis May 2017

Kinetic Study Of Conjugated Polymer Packing And Agglomeration, Skye R. Travis

Honors Theses

Although organic electronic materials are flexible, cheap to fabricate, and molecularly tunable, their performance has generally been less efficient than that of their inorganic counterparts. Chemical doping has been attempted as a method to increase the efficiency of organic materials. During this process, an organic material, typically a conjugated polymer, is exposed to an oxidant/reductant, called a dopant. Electron transfer between host polymer and dopant molecules increases the charge carrier density in the doped host material, making it a more efficient conductor. The effects of doping using 2,3,5,6-tetrafluoro-tetracyanoquinodimethane (F4TCNQ) on low molecular weight poly(3-hexylthiophene-2,5-diyl) (LMW P3HT) in varying ratios of …