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Physical Sciences and Mathematics Commons

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Chemistry

Honors Theses

University of Richmond

Nanoparticles

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Full-Text Articles in Physical Sciences and Mathematics

Optical Properties Of Multilayer-Polyelectrolyte Films With Incorporated Gold Nanomaterials (Solid Nanoparticles And Hollow Nanoshells), Robert Watson Day Apr 2009

Optical Properties Of Multilayer-Polyelectrolyte Films With Incorporated Gold Nanomaterials (Solid Nanoparticles And Hollow Nanoshells), Robert Watson Day

Honors Theses

The growth of various multilayer‐polymer multilayer‐nanoparticle films was successfully achieved. Multilayer‐polymer multilayer‐nanoparticle films with 1, 3, and 5 polymer layers between nanoparticle layers exhibit significantly different optical properties due to the differences in magnitude of particle plasmon coupling. These film systems were also successfully extended to hollow gold nanoshells, which have significantly enhanced optical properties in comparison to solid gold nanoparticles of similar sizes. A proposal for utilizing this increased sensitivity of the gold nanoshells to explore the ‘microenvironments’ for optimizing potential sensing applications is also presented.