Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Tetrazoline Chemistry, Norman Wallace Rokke
Tetrazoline Chemistry, Norman Wallace Rokke
Electronic Theses and Dissertations
It was of interest to investigate the chemistry of some tetrazolines since they might be sources of heteroatomic analogues of trimethylenemethane. In addition, they might provide alternate means of synthesis of small ring compounds such as diaziridinones and diaziridineimines. New compounds which were prepared are 1-(2,6-dimethylphenyl) tetrazoline-5-one, 1-(2,6-dimethylphenyl)-4-methyltetrazoline-5-one, l-phenyl-4-methyl-5-iminotetrazoline, l-phenyl-4-methyl-5- methyliminotetrazoline, and l-phenyl-4-methyl-5-methyliminotetrazoline methiodide. The mass spectra of the tetrazolines investigated are characterized by ring fragmentations which are helpful in determining their structure. In addition, fragmentation represents one of the few examples of a retro-1,3-dipolar cycloaddition reaction initiated by electron impact. The monosubstituted tetrazolines are thermally unstable. The course of …
Nucleophilic Substitution At Phosphorus: Phosphate Thioesters, Ronnie L. Wilde
Nucleophilic Substitution At Phosphorus: Phosphate Thioesters, Ronnie L. Wilde
Electronic Theses and Dissertations
It was my objective to try to determine the mechanism of nucleophilic substitution at phosphorus in monothiophosphate triesters and to apply what I learn to the other phosphate systems. I also tried to obtain more data to show that the Lewis acid-base type complex through the phosphoryl oxygen is existent and does influence the reaction.
Interactions Of Rhenium(V) Chloride And Oxotrichlorobis(Triphenlyphosphine)Rhenium(V) With Selected Solvents, Paul Luther Holm
Interactions Of Rhenium(V) Chloride And Oxotrichlorobis(Triphenlyphosphine)Rhenium(V) With Selected Solvents, Paul Luther Holm
Electronic Theses and Dissertations
The purpose of this study was to examine the solution interactions of rhenium(V) chloride and oxotrichlorobis(triphenylphosphine)rhenium(V) in a continuation of studies of rhenium(V) chemistry. These goals were accomplished using vacuum line and Schlenk tube techniques. As a result of this work, rhenium(V) chloride was found to dissolve with reaction in 1, 4-dioxane, diethyl ether and acetone. There was only a very small amount of rhenium(V) chloride which dissolved in carbon tetrachloride, chloroform and cyclohexane. Part of what did dissolve was shown by electronic and infrared spectroscopy to be oxotetrachlororhenium(VI) which was present as an impurity in small amounts. Oxotetrachlororhenium(VI) reacts …