Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 3 of 3

Full-Text Articles in Physical Sciences and Mathematics

Synthesis Of Polymers Featuring Novel Diphosphines, Eleanor Tennyson Aug 2009

Synthesis Of Polymers Featuring Novel Diphosphines, Eleanor Tennyson

All Theses

This report details the synthesis of functionalized platinum-based metallopolymers featuring m-terphenyl-scaffolded and light-harvesting phosphine ligands. Substituents placed on both the phosphine and pendant alkynyl units can enhance the optical activity of the metallopolymers depending on their inherent properties. The presence of the platinum metal atom can be exploited to increase conductivity of the molecule and promises to be a unique and valuable modification for polymers to be used in light emitting diodes and photovoltaics. Light-harvesting phosphines prepared in the course of the metallopolymer development have also been used to prepare luminescent polyelectrolytes that prove valuable for well-defined composite film formation …


Phenomenological Investigation Of The Effectiveness Of A Cooperative Problem-Based Laboratory And A Metacognitive Problem-Solving Exercise, Todd Gatlin Aug 2009

Phenomenological Investigation Of The Effectiveness Of A Cooperative Problem-Based Laboratory And A Metacognitive Problem-Solving Exercise, Todd Gatlin

All Theses

Problem-solving has been described by many as the most important goal of chemistry teaching and learning. Solving real problems requires not only cognitive abilities but also a regulation of those abilities-metacognition. In fact, metacognition is recognized as having considerable impact on problem-solving success and learning. Recent research focused on the development of interventions designed to enhance the use of metacognition. The main objective of this study was to determine 'how' and 'why' two interventions were effective in increasing students' metacognitive use, and problem-solving abilities. Therefore, this study represents the qualitative portion of a sequential explanatory mixed-methods study; Qualitative evidence was …


Specific And Non-Specific Binding Of Proteins And Nucleic Acids On Chemically Modified Reticulated Vitreous Carbon Electrodes, Hemangi Shedge May 2009

Specific And Non-Specific Binding Of Proteins And Nucleic Acids On Chemically Modified Reticulated Vitreous Carbon Electrodes, Hemangi Shedge

All Theses

Proteins and nucleic acids play major roles in many important biological processes. Specific and rapid detection of these biomolecules is important for early and precise diagnosis of various genetic diseases and other medical conditions. However, accurate and inexpensive detection of proteins and nucleic acids has always been a challenge. One of the obstacles is their non-specific adsorption on the sensor surface which leads to the conformational changes in the proteins, sometimes causing their denaturation. The non-specific adsorption on the surface also leads to sensor fouling which induces changes in the availability of active sensor surface for detection of analytes and …