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Full-Text Articles in Physical Sciences and Mathematics
Kinetics Of Ion-Induced Nucleation In A Vapor-Gas Mixture, Sergey P. Fisenko, David B. Kane, M. Samy El-Shall
Kinetics Of Ion-Induced Nucleation In A Vapor-Gas Mixture, Sergey P. Fisenko, David B. Kane, M. Samy El-Shall
Chemistry Publications
A general solution for the steady-state ion-induced nucleation kinetics has been derived, considering the differences between ion-induced nucleation and homogeneous nucleation. This solution includes a new effect for nucleation kinetics, the interaction of charged clusters with vapor molecules. Analytical expressions for the ion-induced nucleation rate have been obtained for the limiting cases of high and low thermodynamic barriers. The physical explanation of the so-called sign effect is proposed based on multipole expansion of an electric field of the cluster ion. This theory gives good agreement with experiments and is used to elucidate experimentally observed phenomena.
The Effect Of Carrier Gas Pressure On Vapor Phase Nucleation Experiments Using A Thermal Diffusion Cloud Chamber, D. Kane, S. P. Fisenko, M. Rusyniak, M. S. El-Shall
The Effect Of Carrier Gas Pressure On Vapor Phase Nucleation Experiments Using A Thermal Diffusion Cloud Chamber, D. Kane, S. P. Fisenko, M. Rusyniak, M. S. El-Shall
Chemistry Publications
Recent measurements of critical supersaturations for the vapor phase homogeneous nucleation of several substances using a diffusion cloud chamber technique exhibit a dependence on the pressure of the carrier gas used in the experiments. A model of droplet growth and motion in a diffusion cloud chamber, combined with the density and temperature profiles of the chamber is presented to explain the pressure dependent results. The model demonstrates that at higher carrier gas pressures the growth of the droplets is retarded and the optical scattering signal from the particles is reduced. It is concluded that the observed effect may not result …