Physical Sciences and Mathematics Commons^™

A Study Of The Products Of The Reaction Between Stannous And Arsenate Ions In Silicic Acid Gels, Frank K. Thompson

University of the Pacific Theses and Dissertations

The fact that characteristic crystalline products result upon the diffusion of arsenate ions into silicic acid gel which has been impregnated with stannous ions has been known by the Pacific Chemistry Department for some time. The optimum conditions with regards to heat and hydrogen ion concentration have been determined. The purpose of this investigation was to study the products of the reaction. First to determine whether or not the silicic acid itself combined with the stannous and arsenate. ions in the formation of the crystalline product, and second to determine its chemical composition.

Reactions Between The Stannous And Arsenate Ions In Silicic Acid Gels, Willard Merle Farr

University of the Pacific Theses and Dissertations

Observation of crystal growths resulting from the chemical interaction of stannous chloride and sodium arsenate in silicic acid gels revealed the following very interesting fact. Gels identical in every respect except acidity, contained crystal growths varying greatly in appearance.

The purpose of this investigation was, therefore, to allow stannous and arsenate ion to combine in a series of accurately prepared gels, identical in all respects except the acid content, and to observe the effect upon crystal growth of: (1) varying the acid concentration; and (2) varying the kind of acid