Physical Sciences and Mathematics Commons^™

An Analysis Of The Oil Of Echinocystis Fabacea Seeds, Francis Warren Sayre

University of the Pacific Theses and Dissertations

Echinocystis fabaceae, commonly called “Man Root” because of the peculiar shape of the root, not unlike that of a man, finds abundant occurrence in the central valleys of California. This plant, a member of the wild cucumber family, is of particular interest because it is an oilseed plant. The variety agrestis is especially common around Stockton. Other varieties are found throughout the Sacramento and San Joaquin Valleys and in the Coast Range Mountains.

Oils have played an important part throughout history and are continuing to do so in our present economy. An investigation of the oils of Echinocystis fabaceae seeds …

Intermediate Compounds In The Synthesis Of Lignin, Paul Spencer Gakle

University of the Pacific Theses and Dissertations

The synthesis of a keto-aldehyde from salicylaldehyde and benzaldehyde was attempted. The first step was to protect the carbonyl with a non-reactive group.

The bisulfite addition product and the 2,4-dinitrophenylhydrazone of salicylaldehyde were prepared. The methyl acetal, the sodium bisulfite addition product, and the 2,4-dinitrophenylhydrazone of benzaldehyde were also prepared.

The bisulfite addition of both aldehydes was found to be too unstable in the presence of aldehyde was recovered in each case. The methyl acetyl chloride also decomposed. This necessitated finding a more stable group to protect the aldehyde.

The 2,4-dinitrophenylhydrazone was unaffected by treatment with anhydrous aluminum chloride in …