Physical Sciences and Mathematics Commons^™

Mass Spectra Correlations And The Appearance Potentials Of The Major Tobacco Alkaloids, William Frederick Kuhn

Master's Theses

The main objectives of this investigation were three­ fold: (1) to design and fabricate a heated inlet system for the mass spectrometer; (2) to obtain the mass spectra of the major tobacco alkaloids under normal operating conditions; and ( 3) to determine the ionization potentials of the alkaloids as well as the appearance potentials of some of the major fragment ions derived from the alkaloids.

The mass spectrometer is designed to analyze only materials in the vapor state . Since some materials do not exert sufficient vapor pressure at room temperature under reduced pressure to be analyzed directly, it is …

Characterization And Determination Of Aldehydes By The Ultraviolet Spectral Changes Resulting From Acetal Formation, Edwin Patrick Crowell

Master's Theses

Aldehydes are a very important group of organic compounds because they have been round to contribute t the flavor and odor of many foods and plants . To the organic chemist, aldehydes are important because of their reactivity and interesting chemistry.

Because aldehydes are so prevalent in natural products and because they have . wide use in industrial and synthetic chemistry, their analytical chemistry is extensive . Despite this, there is still a need for rapid, simple, and general procedure for characterization or aldehydes that is not subject to extensive interferences.

The primary purpose of this study was to develop …

Low Temperature Infrared Cell And Its Application In Isoprene And Nitrogen Dioxide Reaction Studies, Gunars Vilcins

Master's Theses

The purpose of this research was to explore the application of low temperature infrared spectroscopy to the study of several chemical problems. In particular the following items were investigated:

1. The design, manufacture, and operation of a low temperature optical cell suitable for infrared spectroscopic studies or gas-solid samples at liquid nitrogen temperature (-196°c) and above.

2. The recording and study of the infrared spectra or nitrogen dioxide and isoprene at 25°c and at lower temperatures.

3. A preliminary study of the reaction between nitrogen dioxide and isoprene at various temperatures using infrared techniques.

In recent years infrared studies have …