Physical Sciences and Mathematics Commons^™

Development Of A Novel Ionic Liquid-Coated Adsorbent For Treating Emerging Contaminants In Recycled Water On The International Space Station, Madeline Carroll, Gabson Baguma, Savanna Vacek

Undergraduate Research Symposium Posters

Synthesize at least 3 biobased ionic liquids. Optimize method for conducting liquid-liquid extractions. Analyze and quantify how much DMSO2 is removed by the ionic liquids. Coat biochar with the most effective biobased ionic liquids.

Groundwater Remediation Using Modified Biochar, Kers Ung-Watson, Ismail Abdulraheem, Nikki Tibayan, Suraj Pochampally

Undergraduate Research Symposium Posters

Biochar, a lightweight black residue made of carbon, has proved to be an effective adsorbent to remove TCE from groundwater. Not only is it an economical substitute for conventional adsorbents but it can be created by using a variety of organic materials. For this project, it will rely on walnut shell feedstock to create biochar as this had the best ability to adsorb TCE.

Trapping And Cooling Of Ca+ For Cold Ion-Radical Collisions, Bernardo Gutierrez

Undergraduate Research Symposium Posters

Free radicals are molecules that contain an unpaired valence electron which induces high reactivity. Ion radical reactions are typically exothermic and have low (or zero) activation energy. It is for these reasons that ion-radical reactions are believed to dominate in interstellar clouds where temperatures hover around 3-10K. State-to-state measurements require precision control of both reactants.

Characterization Of The Isothermal Titration Calorimetry Single Injection Method Using T4 Polynucleotide Kinase As A Model System For Kinases, Rebecca Chaehee Lim

UNLV Theses, Dissertations, Professional Papers, and Capstones

Kinases are an important class of enzymes involved in the regulation of different cellular processes. The dysfunctional activity, either hyperactivity or inactivity, of kinases has been associated with many types of diseases, making kinases a major therapeutic target. As of 2020, more than 80 kinase inhibitors have been FDA-approved and have revolutionized the treatment for progressive disorders such as cancers and Alzheimer's diseases. However, there is always the possibility of developing severe side effects or resistance to drugs so the search for new therapeutics must continue with efficiency and accuracy.Isothermal titration calorimetry (ITC) is a state-of-the-art technique specialized in detecting …

What Can General Chemistry Students Learn From External Representations Of Acid- Base Titrations?, Nicole Baldwin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Laboratory activities are a prevalent and essential part of chemistry learning because of their potential to help students develop problem solving abilities, visualize chemistry concepts learned in lecture, and gain practical skills. However, learning in the laboratory environment is not without its challenges. For example, cookbook-style chemistry laboratories can promote superficial learning, and cognitive overload can result from the study of new concepts and the use of new procedures in this environment. Multiple pedagogies and supports have been developed to address challenges such as these. The current research focuses upon external representations that are commonly used to support learning in …

Dissolution And Electrochemical Recovery Of Uo2, Uo3, And U3o8 In Ionic Liquids, Katherine Iolani Thornock Luebke

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research explores a novel method of increasing the solubility of uranium oxides and other actinide oxides in room temperature ionic liquids (IL) using direct dissolution. The goal is to further expand our knowledge of actinide dissolution and possible nuclear fuel cycle material applications using ionic liquids. The novelty of the methods is focused on the use of oxidizing gas generated using air passed through an ozone generator. While examples of dissolution exist in IL using acidic functionalized ionic liquids, the solubility of all possible oxide species was not demonstrated. Also, the addition of aqueous acid to IL containing actinide …

The Dissolution And Recovery Of Critical Materials (Li2co3 And Uf6) From Ionic Liquid, Cassara Higgins

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lithium and uranium are critical materials in both the energy industry and for national security. Lithium is necessary for the next generation of batteries and 6Li is valuable for the production of tritium necessary for both fusion energy and to maintain our nuclear stockpiles. Uranium is a fuel source or precursor fuel source for commercially operating nuclear fission power. The monitoring of uranium hexafluoride (UF6) enrichment at foreign facilities is important for the monitoring of nuclear safeguards and enforcement of non-proliferation treaties. Recovery methods for lithium at the end of life of batteries are necessary to ensure abundance of the …

Revisiting The Chemistry Of Uranium And Rhenium Fluorides: Implication To Fuel Cycle And Nuclear Forensics Science, James Amos-Aimé Louis-Jean

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluorine plays a major role in the nuclear industry where F2(g) and HF(g) are critical to the preparation of UF6 and UF4. These materials are prepared for uranium enrichment to increase the isotopic concentration of 235U. During separation efforts, the isotope 99Tc (a high yield fission product, 6.1% from 235U) is extracted along with uranium and can be converted to binary technetium fluorides (i.e., TcF4, TcF6) during re-enrichment of used uranium material. This provides a route for 99Tc to reenter the reactor environment and affect the nuclear properties of fuel pellets made with reprocessed uranium. The objective of this work …

Low-Cost Adsorbent For Disinfection Byproduct Removal From Drinking Water, Savanna Vacek, Suraj Pochampally

Undergraduate Research Symposium Posters

Disinfection byproducts (DBPs) are harmful contaminants that are unintentionally created in disinfected water after chlorination. Activated carbon, often expensive and difficult to acquire in low-income and rural areas, has previously been used to remove DBPs from drinking water. Biochar is made from agricultural waste (i.e. feedstock) and has been identified as a low-cost yet effective adsorbent to remote contaminants from drinking water. This work focuses on the efficacy of biochar and activated carbon to remove DBPs from drinking water for the purpose of treating drinking water after emergency chlorination. This study has the potential to help water distributors and disadvantaged …

Identification Of Lipid Species: Potential Biomarkers For Early Detection Of Hepatocellular Carcinoma, Kit Yee Leung, Kaylee Freitas

Undergraduate Research Symposium Posters

Hepatocellular carcinoma (HCC) is the most common type of liver cancer. HCC is associated with cirrhosis. Poor survival rate of HCC is due to diagnosis of HCC at late stage.

Biochar Hydrophilicity Characterization By A Smartphone-Based Apparatus: Design, Construction, And Measurement Calibration, Emma Letourneau, Suraj Pochampally

Undergraduate Research Symposium Posters

Water contact angles are used to determine hydrophilicity, which is a material's attraction to water. A water contact angle of greater than 90 degrees indicates a hydrophobic material that repels water, whereas a contact angle of less than 90 degrees indicates a hydrophilic material [Fig. 1]. Water contact angles are measured through a goniometer, which can cost between $2000 to $10,000.

Biochar is a porous carbon material created from biological waste products, that is pyrolyzed (i.e. burned) in a low-oxygen, high heat environment. Biochar can be used to remove contaminants from water and remediate soil while reusing waste, making it …

Synthesis Of Modified Walnut Shell Biochar And Material Characterization In Ground Water Treatment, Maaike Parajes, Suraj Pochampally

Undergraduate Research Symposium Posters

Biochar (BC) is a carbon-rich material synthesized from the pyrolysis of biomasses and developed to remove soil and wastewater contaminants. The pyrolysis process involves thermally decomposing the organic materials in the absence of oxygen. Biochar has the potential to be an eco-friendly and effective adsorbent for heavy metals and toxic organic compounds. An adsorbent is a material that attracts other substances on its surface, chemically and physically. Walnut shells were chosen for the biochar modification to improve the surface morphology, pore structure, and adsorption capability.

An Approach For Material Model Identification Of A Composite Coating Using Micro-Indentation And Multi-Scale Simulations, Pouya Shojaei, Riccardo Scazzosi, Mohamed Trabia, Brendan O’Toole, Marco Giglio, Xing Zhang, Yiliang Liao, Andrea Manes

Mechanical Engineering Faculty Research

While deposited thin film coatings can help enhance surface characteristics such as hardness and friction, their effective incorporation in product design is restricted by the limited understand-ing of their mechanical behavior. To address this, an approach combining micro-indentation and meso/micro-scale simulations was proposed. In this approach, micro-indentation testing was conducted on both the coating and the substrate. A meso-scale uniaxial compression finite element model was developed to obtain a material model of the coating. This material model was incorporated within an axisymmetric micro-scale model of the coating to simulate the indentation. The proposed approach was applied to a Ti/SiC metal …