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Chemistry

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2012

Porphyrin assembly

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Facile Synthesis Of A Flexible Tethered Porphyrin Dimer That Preferentially Complexes Fullerene C70, Charles Michael Drain Jan 2012

Facile Synthesis Of A Flexible Tethered Porphyrin Dimer That Preferentially Complexes Fullerene C70, Charles Michael Drain

Charles Michael Drain

A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C70 over C60 in toluene solution. The complex forms stable aggregates when cast on glass