Physical Sciences and Mathematics Commons^™

Studies Of The Relationship Between The Structure And Properties Of Interfacial Thin Films, Mark Anderson

Mark R. Anderson

No abstract is available at this time.

Ab Initio And 1H Nmr Study Of The Zn(Ii) Complexes Of A Nido- And A Closo-Carboranylporphyrin, Petia Bobadova-Parvanova, Yuko Oku, Anura Wickramasinghe, Randall W. Hall, Graca H. Vicente

Randall W. Hall

Investigation Of New Chelation Ion Chromatography Procedure To Determine The Surface Composition Of Powdered Metal Oxide Samples In The Solid State., B. Peebles, Michael Setter

Michael P. Setter

Numerous tests have been conducted on the feasibility of characterizing the surfaces of metal oxide powders using HPLC. An in-line filter housing was modified to serve as a sample chamber to replace the sample loop. A gradient pump was used to gradually increase eluent acidity to find the conditions at which the surface of a metal oxide powder began to dissolve. The theoretical masses of surface monolayers of metal oxide powders were compared with the experimentally determined masses of dissolved material thought to be from the surface to test whether surface and bulk dissolution phenomena in acidic conditions are separable …

Rotational Analysis Of Ftir Spectra From Cigarette Smoke.Pdf, Alan Ford, William A. Burns, Scott Reeve

Scott Reeve

No abstract provided.

Food Based Approaches For A Healthy Nutrition In Africa, Mamoudou Hama Dicko

Pr. Mamoudou H. DICKO, PhD

The latest estimates of the FAO demonstrate the problems of the fight against hunger. These problems are manifested by the ever-increasing number of chronically undernourished people worldwide. Their numbers during the 1999-2001 period were estimated at about 840 million of which 798 million live in developing countries. Sub-Saharan Africa alone represented 198 million of those. In this part of Africa the prevalence of undernourishment ranges from 5-34%, causing growth retardation and insufficient weight gain among one third of the children under five years of age and resulting in a mortality of 5-15% among these children. Malnutrition resulting from undernourishment is …

Studies Toward Understanding The Relationship Between Molecular Structure And Macroscopic Properties Of Interfaces, Mark Anderson

Mark R. Anderson

No abstract is currently available.

Tools And Strategies For Processing Diffusion-Ordered 2d Nmr Spectroscopy (Dosy) Of A Broad, Featureless Resonance: An Application To Methylaluminoxane (Mao), Jan Lasse Eilertsen, Randall W. Hall, Larry S. Simeral, Leslie G. Butler

Randall W. Hall

Triethylammonium Tetraphenylborate Dichloromethane Solvate, Daron E. Janzen, Kent R. Mann

Daron E Janzen, Ph.D.

No abstract provided.

Infrared Laser Spectroscopy Of Jet Cooled Cobalt Tricarbonyl, Kyle Trauth, William A. Burns, Ginger Berry, Scott Reeve

Scott Reeve

No abstract provided.

Hypothetical Thermodynamic Properties: The Boiling And Critical Temperatures Of Polyethylene And Polytetrafluoroethylene, James S. Chickos

James Chickos

No abstract provided.

Diethylaluminum Chloride Mediated Vinylsilane Synthesis: Comparison Of Different Solvent Systems., Man Lung Kwan, Merle Battiste, Megan Macala, Sylvia Aybar, Nicholas James, Joseph Haoui

Man Lung Desmond Kwan

Aromatic ketones were converted to one-carbon elongated-vinylsilanes in a convenient one-pot operation via the Peterson protocol. Reactions were conducted in two different solvents for comparison: pentane and triethylamine. Results indicate that triethylamine appeared to be a more suitable solvent for such a transformation producing vinylsilanes with great chemo- and stereo-selectivity than pentane.

Solvent-Free Conversion Of Alpha-Naphthaldehyde To 1-Naphthoic Acid And 1-Naphthalenemethanol: Application Of The Cannizzaro Reaction, John Esteb, Keith Gligorich, Stacy O'Reilly, Jeremy Richter

John Esteb

The Cannizzaro reaction is routinely covered in organic textbooks, but owing to the shortage of suitable procedures for the undergraduate teaching laboratory, this reaction is seldom performed in a first-year organic chemistry class. In this experiment, powdered potassium hydroxide and α-naphthaldehyde are heated under solvent-free conditions to produce 1-naphthoic acid and 1-naphthalenemethanol in 86% and 79% yields, respectively. The solvent-free nature of this procedure greatly reduces the quantity of waste generated by students relative to the typical solvent-based method of preparation. Note:Link is to the article in a subscription database available to users affiliated with Butler University. Appropriate login information …

Lactone Synthesis Via Biotransformations Of -Hydroxyamides, Thomas Goyne, Stephen Taylor, Carrie Arnold, Aaron Gerds, Nathan Ide, Keri Law, Dale Kling, Matthew Pridgeon, Lloyd Simons, James Vyvyan, Jennifer Yamaoka, Min-Ken Liao

Thomas Goyne

No abstract provided.

Cautionary Comments (Author Response), John Esteb, Anne Wilson

John Esteb

Reply to concerns about a safety factor in the paper, “A Solvent-Free Oxidation of Alcohols in an Organic Laboratory."

Note:Link is to the article in a subscription database available to users affiliated with Butler University. Appropriate login information will be required for access. Users not affiliated with Butler University should contact their local librarian for assistance in locating a copy of this article.

Simple Epoxide Formation For The Organic Laboratory Using Oxone, John Esteb

John Esteb

We present an epoxide formation experiment for a second-semester organic chemistry laboratory. This oxidation utilizes Oxone, a commercially available oxidizing agent, in the industrially relevant process of epoxide formation. The oxidant performing the oxidation is dimethyldioxirane, which is formed in situ. This experiment demonstrates a simple synthesis of an epoxide and formation of a secondary oxidizing agent.

Note:Link is to the article in a subscription database available to users affiliated with Butler University. Appropriate login information will be required for access. Users not affiliated with Butler University should contact their local librarian for assistance in locating a copy of …

Environment-Friendly Organic Synthesis Using Bismuth Compounds. Bismuth Triflate Catalyzed Synthesis Of Substituted 3,4-Dihydro-2h-L-Benzopyrans, Ram S. Mohan, Mai P. Nguyen, Joshua N. Arnold, Katherine E. Peterson

Ram S. Mohan

Bismuth Compounds In Organic Synthesis. Bismuth Nitrate Catalyzed Chemoselective Synthesis Of Acylals From Aromatic Aldehydes, Ram S. Mohan, David H. Aggen, Joshua N. Arnold, Patrick D. Hayes, Nathaniel J. Smoter

Ram S. Mohan

Vapor Pressures And Vaporization Enthalpies Of The N-Alkanes From C21 To C30 At T ) 298.15 K By Correlation Gas Chromatography, James S. Chickos, William Hanshaw

James Chickos

No abstract provided.

Synthesis And Characterization Of A Novel 32-Membered Unsymmetrical Dinucleating [N12] Macrocycle: Preparation Of Bimetallic Complexes M2lx2(Clo4)2 (M = Zn, Cd Or Hg; X = Cl, Ncs Or No3), Z. A. Siddiqi Dr, Mohammad Mansoob Khan Dr

Dr. Mohammad Mansoob Khan

The condensation reaction of N-acetylaniline with 1,3-diaminopropane in 2 : 1 mole ratio under reflux condition generates an intermediate species having C55N bonds. The in situ reaction of the intermediate with HCHO and 1,3-diaminopropane in the presence of perchloric acid results in an off-white solid product. Analytical, FAB mass, IR, 1H NMR and electronic spectral data of this solid are consistent with the formation of the dihydroperchlorate salt of an unsymmetrical 32-membered [N12] macrocycle [L.2HClO4] via a capping mechanism of the intermediate species. Reactions of [L 2HClO4] with Group 12 metal salts, MX2, and their precursors, [M(Ph3P)2Cl2], produce bimetallic complexes …