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Synthesis, Molecular Structure, And 1h Nmr Analysis Of Bis(Tetraphenylcyclopentadienyl)Ruthenium(Ii), Michael P. Castellani, John M. Wright, Steven J. Gelb, Arnold L. Rheingold, William C. Trogler
Synthesis, Molecular Structure, And 1h Nmr Analysis Of Bis(Tetraphenylcyclopentadienyl)Ruthenium(Ii), Michael P. Castellani, John M. Wright, Steven J. Gelb, Arnold L. Rheingold, William C. Trogler
Michael P. Castellani
Reaction of [Ru(p-cymene)Cl2]2 with K(η5-C5HPh4) in refluxing diglyme yields (η5-C5Ph4)2Ru in ca 50% yield. The complex was not susceptible to oxidation or reduction. (C5HPH4)2Ru crystallizes in the triclinic P1 space group with a = 8.549(4), b = 10.793(4), c = 12.842(5) Å, α = 65.98(3), β = 73.10(3), γ = 83.49(3)° and Z = 1. The least-squares data refined to R(F) = 3.53% and R(wF = 3.82% for the …