Physical Sciences and Mathematics Commons^™

Determination Of The Internal Rotational Energy Of Gaseous 1,2-Dichloroethane In An Argon Matrix Using Fourier Transform Spectroscopy, Susan Lynn Clarke

Chemistry & Biochemistry Theses & Dissertations

A sample cell and delivery system for rapid matrix isolation of gas mixtures at constant gas temperature was designed and evaluated. The rotational energy differences of 1,2-dichlorosthane and of its deuterium compound wars then determined to test this technique.

The rotational energy barriers calculated from Boltzman plots of ths gases at different temperatures were; 1.21 + 0.38 keel/mole, 1.33 + 0.70 Real/mole, and 1.12 + 0.45 kcal/mole for the CH2 wagging„ C-Cl stretching and CD₂ wagging modes respectively. These values were in good agreement with previously published values.

These results allowed evaluation of this apparatus and experimental design and …

Characterization Of Trihalomethane Formation From Proteins In Chlorinated Water, Robert Aaron Kravitz

Chemistry & Biochemistry Theses & Dissertations

Traditionally humates have been considered the most significant precursor in the formation of trihalomethanes in finished drinking water. This study investigates another potential precursor, namely proteins. The chlorination of aqueous protein solutions yields significant levels of trihalomethanes in terms of the maximum contaminant level (MCL) of 0.100 mg/L imposed by the USEPA. Molar yields for several proteins were determined. The average yield per unit of organic carbon was 0.5% as compared to 0.8% for a humic acid studied. A model protein, bovine serum albumin, was studied extensively to ascertain the effects of total organic carbon, chlorine dose, and time on …

Investigation Of Matrix Effects On The Furnace Atomic Absorption Signals Of Chromium, Nickel And Selenium, Susan Marie Viet

Chemistry & Biochemistry Theses & Dissertations

The flameless atomic absorption signals of chromium, nickel and selenium are subject to matrix interferences arising from inorganic salts and anions commonly found in urine. The effects of such salts on the atomic absorption signals were investigated using Polarized Zeeman Effect background correction in conjunction with a detector/readout system capable of resolving absorbance signals in 18 msec readings. Both optical temperature control and current temperature control were employed for each analysis. Peak area, peak height, peak shape and appearance time were compared for matrix-free standards and matrix-containing standards.

The influence of the inorganic salts on the metal analyses was found …

Mass Spectrometric Studies Of Oxygen Isotope Exchange Reactions With Oxide Surfaces, Gayle J. Allen

Chemistry & Biochemistry Theses & Dissertations

Isotopic exchange reactions with the surface of amorphous silica and crystalline quartz were studied mass spectrometrically. A mixture of approximately 2%18_o2 in neon was used as the test gas, and was passed over the surface of the oxides. Measurements were taken as a function of temperature and residence time, for kinetic studies.

These studies clearly show a second order rate law for the surfaces examined. The rate constant on amorphous silica was 2.2xl0²L/mol/sec. The energy of activation was 35.3 kcal/mol and the frequency factor was l.35xl0⁹L/mol/sec. On the crystalline quartz the rate constant was 2.0xl0 …