Physical Sciences and Mathematics Commons^™

Ion‐Pair Theory Of Concentrated Electrolytes. Iv. Ion Atmosphere Charge Distribution, Frank Stillinger, Ronald White

Center for Advanced Mineral and Metallurgical Processing (CAMP)

Arguments are presented indicating that the large‐size limiting behavior of the ion‐pair size distribution is qualitatively the same both with, and without, Coulomb interactions between ions. This in turn implies that the static dielectric response function ε0 / ε(k) derived in the preceding paper is nonanalytic at k = 0. The specific singular behavior of this response requires a branch cut along the imaginary k axis. It furthermore induces an r−8 tail in the ion atmosphere charge distribution at finite electrolyte concentration.