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The Electrochemical Oxidation Of Substituted Catechols, Michael D. Ryan, Alice Yueh, Wen-Yu Chen
The Electrochemical Oxidation Of Substituted Catechols, Michael D. Ryan, Alice Yueh, Wen-Yu Chen
Chemistry Faculty Research and Publications
The oxidation of substituted catechols was studied by cyclic voltammetry, chronoamperometry, rotating ring‐disk electrode, and coulometry. The results showed that the quinones that were formed from the oxidation of substituted catechols reacted with the basic forms of the starting material to yield the dimeric product. These products were generally unstable and rapidly polymerized or underwent some other irreversible reaction to form an electroinactive product. For 3,4‐dihydroxyacetophenone and propriophenone, the intermediate was stable long enough to be observed in cyclic voltammetry. The rate of the coupling reaction was found to correlate well with the Hammett ρ‐σ parameters and indicated that there …