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Probing The Capabilities Of Copper Complexes With Nitrogen And Sulfur Containing Macrocyclic Ligands As Aziridination Catalysts, Jonathan Natkin
Probing The Capabilities Of Copper Complexes With Nitrogen And Sulfur Containing Macrocyclic Ligands As Aziridination Catalysts, Jonathan Natkin
Honors Theses
Aziridines are three-membered rings containing one nitrogen atom. They are useful as synthetic intermediates in many organic reactions. Much work has been devoted to synthesizing their analogs, cyclopropanes and epoxides, but little work has been done on the aziridination reaction. This study endeavored to probe the efficiencies of novel copper aziridination catalysts with N3 and S3 macrocyclic ligands compared to an NS2 analog for the reaction with the nitrene precursor (N-(paratosylsulfonyl) imino)phenyliodinane, PhINTs, and the olefin styrene. The nitrogen containing catalyst complex gave higher yields than the sulfur containing catalyst complex. Both ligands were found to decrease the yield of …