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Physical Sciences and Mathematics Commons

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Chemistry

Chinese Chemical Society | Xiamen University

2010

Protein

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Full-Text Articles in Physical Sciences and Mathematics

Electrochemical Behavior Of Kaempferide Interaction With Protein, Li-Qing Lin, Xin-Hua Lin, Jing-Hua Chen, Li-Ying Huang, Yin-Huan Liu, Guang-Wen Li May 2010

Electrochemical Behavior Of Kaempferide Interaction With Protein, Li-Qing Lin, Xin-Hua Lin, Jing-Hua Chen, Li-Ying Huang, Yin-Huan Liu, Guang-Wen Li

Journal of Electrochemistry

The electrochemical behavior of kaempferide at activated GCE and the interaction of kaempferide with human serum albumin( HSA) were investigated by cyclic voltammetry. A differential pulse voltammetric method has been proposed for the determination of the HSA with kaempferide. In pH 4. 5 phosphate buffer solutions ( PBS) kaempferide can react with HSA to form an electrochemically non-active supermolecular complex at activated GCE,resulting in the decrease of oxidation peak ( at 0. 468 V) without the change of peak potential. The decrease of the peak current is proportional to HSA concentration in the range of 0. 05 ~ 0. 25 …