Physical Sciences and Mathematics Commons^™

Protocol For Fabricating Electroless Nickel Immersion Gold Strain Sensors On Nitrile Butadiene Rubber Gloves For Wearable Electronics, Sara S. Mechael, Yunyun Wu, Yiting Chen, Tricia Breen Carmichael

Chemistry and Biochemistry Publications

This protocol describes the fabrication of patterned conductive gold films on nitrile butadiene rubber (NBR) gloves for wearable strain sensors using electroless nickel immersion gold (ENIG) plating, a solution-based metallization technique. The resulting NBR/ENIG films are strain sensitive; resistance measurements of a patterned sensing array can be used to map human hand motions. This protocol also describes challenges related to the ENIG process and troubleshooting steps to achieve conformal gold films for strain sensing over a large working range. For complete details on the use and execution of this protocol, please refer to Mechael et al. (2021).

Analysis Of Ritalin Addiction And Recovery From Both A Physical And Psychological Lens, Nicole Madrigal, Tyler Marshall

Fall Showcase for Research and Creative Inquiry

We will investigate the physical impacts, both short and long-term effects, of substance use. In doing so, we will frame an argument for the substance's addictive properties as it relates to both its physically addictive and sociological addictive properties. In doing so, a stronger understanding of how an individual can move through the stages of substance use, to abuse, and finally addiction will be reviewed. We will then address current treatment strategies for the substance and how they address or fail to address both the physical and sociological impacts of its use.

Analysis Of Fluoxetine (Prozac) Addiction And Recovery From Both A Physical And Psychological Lens, Kristen Dobek, Hannah Couch

Fall Showcase for Research and Creative Inquiry

We will investigate the physical impacts both short and long term effects of of substance use. In doing so we will frame an argument for the substance's addictive properties as it relates to both its physically addictive and sociological addictive properties. In doing, so a stronger understanding of how an individual can move through the stages of substance use, to abuse, and finally addiction will be reviewed. We will then address current treatment strategies for the substance and how they address or fail to address both the physical and sociological impacts of its use.

Analysis Of Oxycontin Addiction And Recovery From Both A Physical And Psychological Lens, Meagan Munley, Carrie Flickinger

Fall Showcase for Research and Creative Inquiry

We will investigate the physical impacts both short and long term effects of of substance use. In doing so we will frame an argument for the substance's addictive properties as it relates to both its physically addictive and sociological addictive properties. In doing, so a stronger understanding of how an individual can move through the stages of substance use, to abuse, and finally addiction will be reviewed. We will then address current treatment strategies for the substance and how they address or fail to address both the physical and sociological impacts of its use.

So, You Want To Take Zoloft (Sertraline)?: A Biological & Psychological Analysis, Hailey Lux, Mackenzie Harry

Fall Showcase for Research and Creative Inquiry

A lot of individuals around the world suffer with panic disorders, post-traumatic stress disorder (PTSD), obsessive compulsive disorder (OCD). One drug that has been found to significantly decrease these feelings of stress is Sertraline. Sertraline has been proven to increase quality of life among individuals with certain mental health disorders. In addition, it is commonly known as Zoloft and is prescribed to individuals by doctors and psychiatrist. However, we will be talking about how in extreme causes sertraline could become addictive and have withdrawal side effects. Furthermore, during this poster presentation we will be discussing how sertraline is not an …

Statistical Potentials For Rna-Protein Interactions Optimized By Cma-Es, Takayuki Kimura, Nobuaki Yasuo, Masakazu Sekijima, Brooke Lustig

Faculty Research, Scholarly, and Creative Activity

Characterizing RNA-protein interactions remains an important endeavor, complicated by the difficulty in obtaining the relevant structures. Evaluating model structures via statistical potentials is in principle straight-forward and effective. However, given the relatively small size of the existing learning set of RNA-protein complexes optimization of such potentials continues to be problematic. Notably, interaction-based statistical potentials have problems in addressing large RNA-protein complexes. In this study, we adopted a novel strategy with covariance matrix adaptation (CMA-ES) to calculate statistical potentials, successfully identifying native docking poses.

3d-Printable And Open-Source Modular Smartphone Visible Spectrophotometer, Brandon Winters, Nick Banfield, Cassandra Dixon, Anna Swensen, Dakota Holman, Braxton Fillbrown

Chemistry Faculty Publications

The past four decades have brought significant and increasingly rapid changes to the world of instrument design, fabrication, and availability due to the emergence of 3D printing, open-source code and equipment, and low-cost electronics. These, along with other technological advances represent a nexus in time ripe for the wide-spread production and availability of low-cost sophisticated scientific equipment. To that end, the design of a 3D printable and open-source, modular spectrometer is described. This specific instrument is distinctly different from others that have been reported in recent years in that it was designed outside of the “black box” paradigm of …

Physical Chemistry, Ruth E. Stark

Open Educational Resources

This is a provisional syllabus for Physical Chemistry I (Thermodynamics), to be taught using an OER Textmap in Fall, 2021.

The Coordination Chemistry Of The Rhodizonate Dianion And Its Decomposition Products, Joshua A. Silverman

FIU Electronic Theses and Dissertations

The rhodizonate dianion is of importance for forensic testing, specifically with regard to the sodium rhodizonate test for lead in gunpowder residues. In an effort to understand this test from a chemical perspective, the coordination of rhodizonate and its decomposition products, croconate and oxalate, with several metals has been investigated with a variety of structural and spectroscopic methods.

FT-IR data of the three sequential steps of the sodium rhodizonate test show coordination between Pb(II) atoms, tartrate anions, and rhodizonate dianions, with the tartrate being substituted for Cl^- once a 5% HCl solution is added to produce the confirmatory blue-purple …

Lanthanide Interactions With Ligands And Biomolecules: Spectroscopic And Extraction Studies, Setareh Sakhdari

FIU Electronic Theses and Dissertations

Lanthanides (Ln), also known as rare earth metals, have been utilized for industrial and biological purposes and are commonly encountered in the 3+ oxidation state as Ln³⁺. The presence of Ln in spent nuclear fuel introduces problems during the transmutation and partitioning of actinides (An) due to the Ln high neutron cross-sections. Therefore, designing ligands for Ln³⁺ complexation, can be helpful for their separation from An³⁺ in nuclear technology. Also, the biomimetic roles of Ln³⁺ could be suitable for studying the biological macromolecules, such as the Ca²⁺-binding EF-hand proteins that are otherwise inaccessible …

The Synthesis Of Photoswitchable Triptan Derivatives, Chelsea Sainsbury

Honors College

Serotonin has various functions throughout the body and directly effects many neurological diseases/disorders, like depression, that are linked to the dysregulation of serotonin. Triptans are indole containing drugs that bind to a subset of serotonin receptors (5-HT1Band 5-HT1D) and are used to treat migraines. In this project, the synthesis of anindole intermediate is attempted. Ideally, an azobenzene would have been added to the 5th position (replacing the primary amine). Azobenzenes are compounds composed of 2 benzene rings connected by a nitrogen-nitrogen double bond that can switch between cis and trans conformations by absorbing different wavelengths of light. The transformation of …

The Analysis Of Heavy Metals In Samples Of Honey Using X-Ray Fluorescence And Anodic Stripping Voltammetry, Mia Arrieta, Kaleigh Beale

Spring Showcase for Research and Creative Inquiry

A daunting reality is haunting scientists as Colony Collapse Disorder (CCD) is declining bee population in the United States (1). A concrete conclusion as to why CCD is happening remains unclear but extensive research and studies are leaning towards a toxic component in honey to bees called hydroxymethylfurfural (HMF) (1). HMF has been a culprit in question for a while but researchers are still on the fence as to whether it should be concluded as such. It is theorized that HMF is formed in very warm temperatures and catalyzed by a metal in honey; manganese (1). Manganese is one of …

Chemistry Meets Art: Instrumental Analysis At The Lcva, James Rakes, Mia Arrieta, Kaleigh Beale, Adonel Grubb

Spring Showcase for Research and Creative Inquiry

This project is an ongoing collaboration between the Longwood chemistry program and the Longwood Center for the Visual Arts. The demonstration shows the capabilities of the X-ray fluorescence spectrophotometer as a non-destructive elemental analysis technique. Our class visited the LCVA to analyze several pieces in their art collections. We were able to utilize the XRF instrument to analyze the elemental composition of glass and metal, painted pottery and porcelain, oil paintings, and metals. This project lays the groundwork for further research using X-ray fluorescence for non-destructive chemical analysis.

Chemical Analysis Of An Herbal Opioid, Lauren Johnson

Spring Showcase for Research and Creative Inquiry

Different chromatography techniques were used to analyze the concentration of an active component, mitragynine, in kratom samples. The analysis also compared three different extraction methods, one using ultrasonification, the other two using a commercial at home espresso maker. Using gas chromatography mass spectrometry, and high performance liquid chromatography, comparisons between key compounds in the substances were determined and concentrations of mitragynine within the samples were calculated.

Cis-Trans Isomerism In Single Molecule Electronic Devices, Tinsae Alem

Spring Showcase for Research and Creative Inquiry

We investigated the switching properties of cis-trans isomers of azobenzene for single molecule electronics. Although the cis-trans isomerization leads to structural changes within the molecule, the current flow is found to depend mainly on the relative position of the electrodes. The on/off ratio was determined to measure the performance of these isomers as switches. Different cis-trans isomers were studied to compare results.

Water Quality Assessment Of Farmville, Va, Meghan Hall

Spring Showcase for Research and Creative Inquiry

In Farmville, some people drink tap water, but others choose only to drink filtered or bottled water. Some blame this on taste, and others say the mineral content affects their skin from sinks and showers. I propose to conduct an analysis of water hardness and chloride, nitrate, and lead levels of water from various sources in Farmville, Virginia. To measure each parameter, an EDTA titration was carried out to test for water hardness, anodic stripping voltammetry was conducted to detect lead, ion-selective electrode was used to measure chloride, and a modified Griess reaction was carried out to measure nitrate levels. …

A Non-Destructive Analytical Technique Used For Analyzing A Variety Of Glassware Samples In Hopes To Determine Their Elemental Composition Based Off Their Qualitative And Quantitative Data Results., Angela Scarpa

Spring Showcase for Research and Creative Inquiry

In this study, XRF analysis was used to examine and identify specific glassware samples, exported from remote locations, in hopes to determine any correlation between the glass samples being tested. During experimentation, there were 41 glass samples and 3 glass standards that were examined and quantitatively analyzed to determine the elemental compositions of all samples. To ensure optimal sensitivity of these different materials, four methods were utilized to confirm accurate data is collected and to improve all quantitative data results. These four methods contain distinct experimental factors and were purposely selected due to their specific current, voltage, filter, time, and …

Alternative View Of Oxygen Reduction On Porous Carbon Electrocatalysts: The Substance Of Complex Oxygen-Surface Interactions, Giacomo De Falco, Marc Florent, Jacek Jagiello, Yongqiang Cheng, Luke L. Daemen, Anibal J. Ramirez-Cuesta, Teresa J. Bandosz

Publications and Research

Electrochemical oxygen reduction reaction (ORR) is an important energy-related process requiring alternative catalysts to expensive platinum-based ones. Although recently some advancements in carbon catalysts have been reported, there is still a lack of understanding which surface features might enhance their efficiency for ORR. Through a detailed study of oxygen adsorption on carbon molecular sieves and using inelastic neutron scattering, we demonstrated here that the extent of oxygen adsorption/interactions with surface is an important parameter affecting ORR. It was found that both the strength of O2 physical adsorption in small pores and its specific interactions with surface ether functionalities in the …

Substituent Effects On The Solubility And Electronic Properties Of The Cyanine Dye Cy5: Density Functional And Time-Dependent Density Functional Theory Calculations, Austin Biaggne, William B. Knowlton, Bernard Yurke, Jeunghoon Lee, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

The aggregation ability and exciton dynamics of dyes are largely affected by properties of the dye monomers. To facilitate aggregation and improve excitonic function, dyes can be engineered with substituents to exhibit optimal key properties, such as hydrophobicity, static dipole moment differences, and transition dipole moments. To determine how electron donating (D) and electron withdrawing (W) substituents impact the solvation, static dipole moments, and transition dipole moments of the pentamethine indocyanine dye Cy5, density functional theory (DFT) and time-dependent (TD-) DFT calculations were performed. The inclusion of substituents had large effects on the solvation energy of Cy5, with pairs of …

Improving Conceptual Understanding Of Gas Behavior Through The Use Of Screencasts And Simulations, Brianna L. Martinez, Ryan D. Sweeder, Jessica Vandenplas, Deborah Herrington

Peer Reviewed Articles

Engagement with particle-level simulations can help students visualize the motion and interactions of gas particles, thus helping them develop a more scientifically accurate mental model. Such engagement outside of class prior to formal instruction can help meet the needs of students from diverse backgrounds and provide instructors with a common experience upon which to build with further instruction. Yet, even with well-designed scaffolds, students may not attend to the most salient aspects of the simulation. In this case, a screencast where an instructor provides narrated use of the simulation and points students towards the important observations may provide additional benefits. …

Optimization Of Simple And Inexpensive Paper-Based Assay For Lead, Kyla Dewittie, Sagar S. Patel

Summer Scholarship, Creative Arts and Research Projects (SCARP)

The Environmental Protection Agency (EPA) guidelines state that lead is a toxic metal that humans should not be exposed to in any amount. Due to corrosion of water pipes, lead can enter drinking water and be consumed by millions of people. As a group, we decided to reduce this issue by creating a simple and inexpensive paper-based test to detect lead(II) in water. The signal for this test results from encapsulating a phenanthroline-based probe in synthesized polymer nanoparticles. This test will display a colorimetric change, turning from yellow to bright orange if lead(II) is present in the water system. In …

Computational Analysis Beyond The Monomer Frontier Orbitals For Photovoltaic Donor-Polymer Candidates, Mitchell E. Lahm, Megan M. Niblock, John M. Migliore, Kendra M. Mckenzie, Hans P. Lüthi, Rollin A. King

Chemistry Faculty Publications

Scharber et al. proposed an efficiency model for organic photovoltaic cells based on the orbital energies of the monomers of the donor- and acceptor- polymers [Advanced Materials 18 (2006) 789–794]. We report theoretical extensions of this approach. First, the frontier-orbital energies and electronic spectra of n-length oligomers (n = 1 − 5) of 3-butylthiophene have been determined. The results show reasonable convergence with respect to system size at the point of a trimer with alkyl end caps. The HOMO-LUMO gap well matches computed excitation energies. Second, the structures and electronic spectra of dimers formed by three different monomers, with various …

Degradation Of Natural And Synthetic Fibers In Various Aqueous Environments, Jaylin Bryant

Honors Scholars Collaborative Projects

Fabrics are one variant of polymers, macromolecules that form the foundation of our society. They consist of small subunits called monomers, which are covalently bonded together and layered over each other through intermolecular attractions. There are natural fabrics, such as cotton and silk, and synthetic fabrics like polyester and rayon. Scientists in forensic taphonomy study postmortem changes made to human remains, which can also include clothes found at the scene. In this study, the degradation rates of four white fabrics (cotton, polyester, rayon, and silk) were observed in various aqueous environments (pure, chlorinated, sea, and lake) in order to observe …

In Depth Characterisation Of The Biomolecular Coronas Of Polymer Coated Inorganic Nanoparticles With Differential Centrifugal Sedimentation, André Perez-Potti, Hender Lopez, Beatriz Pelaz, Abuelmagd Abdelmonem, Mahmoud G. Soliman, Ingmar Schoen, Philip M. Kelly, Kenneth A. Dawson, Wolfgang J. Parak, Zeljka Krpetic, Marco P. Monopoli

Articles

Advances in nanofabrication methods have enabled the tailoring of new strategies towards the controlled production of nanoparticles with attractive applications in healthcare. In many cases, their characterisation remains a big challenge, particularly for small-sized functional nanoparticles of 5 nm diameter or smaller, where current particle sizing techniques struggle to provide the required sensitivity and accuracy. There is a clear need for the development of new reliable characterisation approaches for the physico-chemical characterisation of nanoparticles with significant accuracy, particularly for the analysis of the particles in the presence of complex biological fluids. Herein, we show that the Differential Centrifugal Sedimentation can …