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Chemistry

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Selected Works

2014

Electrochemically active biofilm

Articles 1 - 3 of 3

Full-Text Articles in Physical Sciences and Mathematics

Electrochemically Active Biofilm Assisted Synthesis Of Ag@Ceo2 Nanocomposites For Antimicrobial Activity, Photocatalysis And Photoelectrodes, Mohammad Mansoob Khan Dr, S. A. Ansari, J. H. Lee, M. O. Ansari, J Lee, M. H. Cho Sep 2014

Electrochemically Active Biofilm Assisted Synthesis Of Ag@Ceo2 Nanocomposites For Antimicrobial Activity, Photocatalysis And Photoelectrodes, Mohammad Mansoob Khan Dr, S. A. Ansari, J. H. Lee, M. O. Ansari, J Lee, M. H. Cho

Dr. Mohammad Mansoob Khan

Ag@CeO2 nanocomposites were synthesized by a biogenic and green approach using electrochemically active biofilms (EABs) as a reducing tool. The as-synthesized Ag@CeO2 nanocomposites were characterized and used in antimicrobial, visible light photocatalytic and photoelectrode studies. The Ag@CeO2 nanocomposites showed effective and efficient bactericidal activities and survival test against Escherichia coli O157:H7, and Pseudomonas aeruginosa. The as-synthesized Ag@CeO2 nanocomposites also exhibited enhanced visible light photocatalytic degradation of 4-nitrophenol and methylene blue than pure CeO2. A photocatalytic investigation showed that the Ag@CeO2 nanocomposites possessed excellent visible light photocatalytic activities compared to pure CeO2. Electrochemical impedance spectroscopy and photocurrent measurements showed that the …


Visible Light-Driven Photocatalytic And Photoelectrochemical Studies Of Ag-Sno2 Nanocomposites Synthesized Using An Electrochemically Active Biofilm, Mohammad Mansoob Khan Dr, S. A. Ansari, M. O. Ansari, J. Lee, M. H. Cho Jun 2014

Visible Light-Driven Photocatalytic And Photoelectrochemical Studies Of Ag-Sno2 Nanocomposites Synthesized Using An Electrochemically Active Biofilm, Mohammad Mansoob Khan Dr, S. A. Ansari, M. O. Ansari, J. Lee, M. H. Cho

Dr. Mohammad Mansoob Khan

Ag-SnO2 nanocomposites (1 mM and 3 mM) were synthesized in water at room temperature using an electrochemically active biofilm. The resulting nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, diffuse reflectance spectroscopy, photoluminescence spectroscopy and X-ray photoelectron spectroscopy. The Ag-SnO2 nanocomposites exhibited enhanced photocatalytic activity under visible light irradiation for the degradation of methyl orange, methylene blue, 4-nitrophenol and 2-chlorophenol compared with pure SnO2 nanostructures. Photoelectrochemical measurements, such as electrochemical impedance spectroscopy, linear scan voltammetry and differential pulse voltammetry in the dark and under visible light irradiation, further supported the visible light activity of the Ag-SnO2 nanocomposites. These results …


Band Gap Engineering Of Ceo2 Nanostructure Using An Electrochemically Active Biofilm For Visible Light Applications, S A. Ansari, Mohammad Mansoob Khan Dr, M. O. Ansari, J. Lee, M. H. Cho Apr 2014

Band Gap Engineering Of Ceo2 Nanostructure Using An Electrochemically Active Biofilm For Visible Light Applications, S A. Ansari, Mohammad Mansoob Khan Dr, M. O. Ansari, J. Lee, M. H. Cho

Dr. Mohammad Mansoob Khan

Narrowing the optical band gap of cerium oxide (CeO2) nanostructures is essential for visible light applications. This paper reports a green approach to enhance the visible light photocatalytic activity of pure CeO2 nanostructures (p-CeO2) through defect-induced band gap narrowing using an electrochemically active biofilm (EAB). X-ray diffraction, UV-visible diffuse reflectance/absorption spectroscopy, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, Raman spectroscopy, photoluminescence spectroscopy and high resolution transmission electron microscopy confirmed the defect-induced band gap narrowing of the CeO2 nanostructure (m-CeO2). The structural, optical, photocatalytic and photoelectrochemical properties also revealed the presence of structural defects caused by the reduction of Ce4+ to …