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Full-Text Articles in Physical Sciences and Mathematics
Reactivity Of Phenyldi(2-Thienyl)Phosphine Towards Group 7 Metal Carbonyls: Carbon–Phosphorus Bond Activation, Shishir Ghosh, Alok K. Das, Noorjahan Begum, Daniel T. Haworth, Sergey Lindeman, James R. Gardinier, Tasneem A. Siddiquee, Dennis W. Bennett, Ebbe Nordlander, Graeme Hogarth, Shariff E. Kabir
Reactivity Of Phenyldi(2-Thienyl)Phosphine Towards Group 7 Metal Carbonyls: Carbon–Phosphorus Bond Activation, Shishir Ghosh, Alok K. Das, Noorjahan Begum, Daniel T. Haworth, Sergey Lindeman, James R. Gardinier, Tasneem A. Siddiquee, Dennis W. Bennett, Ebbe Nordlander, Graeme Hogarth, Shariff E. Kabir
Chemistry Faculty Research and Publications
Addition of phenyldi(2-thienyl)phosphine (PPhTh2) to [Re2(CO)10−n(NCMe)n] (n = 1, 2) affords the substitution products [Re2(CO)10−n(PhPTh2)n] (1, 2) together with small amounts of fac-[ClRe(CO)3(PPhTh2)2] (3) (n = 2). Reaction of [Re2(CO)10] with PPhTh2in refluxing xylene affords a mixture which includes 2, [Re2(CO)7(PPhTh2)(μ-PPhTh)(μ-H)] (4), [Re2(CO)7(PPhTh2)(μ-PPhTh)(μ-η1,κ1(S)-C4H3S)] (5) and …