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Articles 1 - 13 of 13
Full-Text Articles in Physical Sciences and Mathematics
Study On Low Voltage Electrodeposition Of Diamond-Like Carbon Film, Li Wang, Min-Xian Wu, Jun Li, Yan-Li Chen, Wen-Chang Wang, Zhi-Dong Chen
Study On Low Voltage Electrodeposition Of Diamond-Like Carbon Film, Li Wang, Min-Xian Wu, Jun Li, Yan-Li Chen, Wen-Chang Wang, Zhi-Dong Chen
Journal of Electrochemistry
Diamond-like carbon (DLC) films are receiving a lot of attention from the scientific community, thanks to the promise of DLC films for applications in microelectronics and optoelectronics. Usually, electrodeposition is the preferred common technique because of low cost, large deposition area and simplicity of the setup. However, when carbon films are electrodeposited on a stainless steel, high cell voltages (≥1000 V) are required owing to the low electric conductivity of the organic solvents. This work has developed a new electrolyte system that could achieve carbon deposition on a stainless steel under a low applied cell voltage. The DLC films were …
Pitting Behaviors Of Passivated And Trans-Passivated 304 Stainless Steel, Jing Shen, Zi-Ming Wang, Da-Jiang Zheng, Guang-Ling Song
Pitting Behaviors Of Passivated And Trans-Passivated 304 Stainless Steel, Jing Shen, Zi-Ming Wang, Da-Jiang Zheng, Guang-Ling Song
Journal of Electrochemistry
In order to further understand the passivation and trans-passivation behaviors of 304 stainless steels, the samples were pretreated under different polarization potentials and their corrosion behaviors were investigated. It was found that the pitting potential of the untreated sample was the same as that of the sample treated with 1.1 V trans-passivation potential, while the pitting potential of the sample treated with 0.5 V passivation treatment was the highest. This observation was further verified by the SKP results. According to SEM observations, the surface of the untreated sample preserved a polishing morphology, while the surface of the 0.5 V passivation …
Pitting Behavior Of Stainless Steel In Simulated Marine Atmosphere Based On Electrochemical Noise, Jun-Hao Deng, Gui Wang, Jie-Zhen Hu, Pei-Chang Deng, Huan-Huan Hu
Pitting Behavior Of Stainless Steel In Simulated Marine Atmosphere Based On Electrochemical Noise, Jun-Hao Deng, Gui Wang, Jie-Zhen Hu, Pei-Chang Deng, Huan-Huan Hu
Journal of Electrochemistry
A measurement system for detecting the atmospheric corrosion of stainless steels was built based on electrochemical noise technology. The electrochemical noise data have been collected for 304 stainless steels which were exposed to the simulated marine atmospheric environment. The pitting behaviors of 304 stainless steels were studied by analyzing the electrochemical noise results with the time domain spectrogram, statistic, frequency domain spectrogram and shot noise theory. Meanwhile, potentiodynamic polarization and morphological analysis were also used as assistant measurements. It has shown that the 304 stainless steel in the whole wet-dry cycle could be divided into three stages, including passivation stage, …
The Characteristic On Propagation Of Fatigue Pre-Cracking 304ss During Ssrt With En And Skp, Ru Zhao, Shi-Zhe Song, Zheng Zhang
The Characteristic On Propagation Of Fatigue Pre-Cracking 304ss During Ssrt With En And Skp, Ru Zhao, Shi-Zhe Song, Zheng Zhang
Journal of Electrochemistry
This work focuses on the characteristic of electrochemical noise obtaining from 304SS with fatigue pre-cracking 1.002 mm in 4 mol/L NaCl +0.01mol/L Na2S2O3 solutions during SSRT,with time and frequency domain analysis showed the cracking propagated,which was also confirmed by the morphology observations.Moreover,the characteristics of surface morphology image and Volta potential distribution over the surface have been studied before and after the experiments with Kelvin probe.Both the Kelvin and EN can get the same judgment that the cracking propagated after the experiments.
Discussion On Factors Of Unstable 304 Stainless Steel Stress Corrosion Cracking, Xin-Sheng Zhang, Chun-Chun Xu, Gang Hu
Discussion On Factors Of Unstable 304 Stainless Steel Stress Corrosion Cracking, Xin-Sheng Zhang, Chun-Chun Xu, Gang Hu
Journal of Electrochemistry
The 304 stainless steels were stretched at low temperatures to get different martensite phase transformation.Ferrmagnetometer was used to measure the martensite phase content. It was found that the dislocation density of 304 stainless sted was increased unavoidably with increase of deformation.Transmission electron microscope (TEM) was used to study the distribution of the dislocation.The influence of microstructure change on SCC of 304 stainless steel was discussed by slow strain rate testing (SSRT) in 42% MgCl 2 boiling solution,metallurgical microscope and scanning electron microscope (SEM).The results showed that martensite phase and dislocation flaw act together on the SCC susceptibility of 304 stainless …
Effect Of Dissolved Oxygen On The Corrosion Behavior Of Coalesced Copper And Stainless Steel-206 In Acetic Solutions, Rong-Zong Hu, Xiong-Cao Zhao, Yu-Hua Weng, Chang-Jian Lin
Effect Of Dissolved Oxygen On The Corrosion Behavior Of Coalesced Copper And Stainless Steel-206 In Acetic Solutions, Rong-Zong Hu, Xiong-Cao Zhao, Yu-Hua Weng, Chang-Jian Lin
Journal of Electrochemistry
Linear sweeping technique and dissolving oxygen sensor were used to study the effect of dissolved oxygen and relating factors on the corrosion behavior of coalesced copper and stainless steel-206 in acetic solutions. It was found: 1. The existing of dissolved oxygen is one of the important factors, which strongly influenced the corrosion behavior of coalesced copper and stainless steel-206 in acetic solution. 2. The existing of dissolved oxygen is benefitial to the preventing stainless steel-206 from corrosion in acetic solutions, but damage to the preventing coalesced copper from corrosion. 3. At the high temperature since the dissolved oxygen was escaping …
Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jinping Xiong
Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jinping Xiong
Journal of Electrochemistry
The electrochemical behavior of 1Cr18 stainless steel had been studied using a reciprocating triboelectrochemical equipment under friction in 0.2 mol/L H2SO4 solution with and without addition of thiourea, the frictionized surface of 1Cr18 stainless steel had been examined by the SEM, XPS and IR. The results showed that the loss rate of 1Cr18 stainless steel in the solution could be reduced by addition of thiourea. The adsorption of thiourea on the surface of 1Cr18 stainless steel prohibited the oxidization of Cr3+ to form Cr() and formation of passive film consisting of CrO42- or/and Cr(), and make the passive range to …
Study On Steel Corrosion In Simulated Biofilm Environment In Seawater, Qingfei Wang, Jing Sui, Runxi Su, Deying Kong, Shizhe Song
Study On Steel Corrosion In Simulated Biofilm Environment In Seawater, Qingfei Wang, Jing Sui, Runxi Su, Deying Kong, Shizhe Song
Journal of Electrochemistry
Biofilm is one of the main factors that influence metal corrosion in seawater environment. According to the structure and property of biofilm, a natural biopolymeric gel,calcium alginate(an extracellular biopolymer containing carboxylate functional groups) can deposite on metal surfaces to form films. Corrosion behavior of alloyed steel E 2, 10CrMoAl and 18_8 stainless steel were studied in simulated biofilm environment by various electrochemical methods,including measurements of the corrosion potential,polarization curves,galvanic current and electrochemical impedance.The results show that such an approach is informative to reveal “how” and “to what extent” biofilm can influence the metal corrosion process.
Electrochemical Study Of The Corrosion Behavior Of Coalesced Copper And Sw-206 Stainless Steel In The Acetic-Acid Solution, Rongzong Hu, Changjian Lin, Jianguang Tan
Electrochemical Study Of The Corrosion Behavior Of Coalesced Copper And Sw-206 Stainless Steel In The Acetic-Acid Solution, Rongzong Hu, Changjian Lin, Jianguang Tan
Journal of Electrochemistry
In order to provide a theoretic and experimental consideration for the material selection and anit-corrosion in the petrochemical industries the corrosion behavior of coalesced copper and sw-206 stainless steel in the acetic acid solution was studied by electrochemical impedance spectroscopy and polarization techniques. The effects of the temperature,acetic acid concentration and solubilized oxygen in the acetic acid solution on the corrosion process of this two metals were analyzed. It was found that these effects obviously accelerate corrosion process for the coalesced copper,but no apparent influnce for the sw-206 stainless steel.In the the acetic acid solution,containing water and oxygen were beneficial …
A Photoelectrochemical Investigation Of A.C.Modulated Passive Films On 304 Stainless Steel In Weak-Alkaline And Neutral Solution, Tianbao Du, Chunan Cao, Jiakang Yu, Haichao Lin
A Photoelectrochemical Investigation Of A.C.Modulated Passive Films On 304 Stainless Steel In Weak-Alkaline And Neutral Solution, Tianbao Du, Chunan Cao, Jiakang Yu, Haichao Lin
Journal of Electrochemistry
A photoelectrochemical investigation has been carried out on AISI 304 stainlesssteeI AV modulated passive film in 0.1mol/L Na_2B_4O_7 and 0.5 mol/L Na_2SO_4 solution.Photocurrentcurve depends on the potential、passive condition and testing solutions. The results of the measurementsindicate that the photoresponse is determined by the defects in the electronic structure of the films whenthe defects lead to localized states in the bandgap region. It is concluded that the passive film on AISI304 stainless steel is in a highly disordered amorphous state.
Electrochemical Behaviors Of The Loaded Stainless Steel In Dilute Thiosulphate Solution, Changjian Lin, Zude Feng, Fuling Lin, Fayang Wang, Jianguang Tang, Yuanhui Wang
Electrochemical Behaviors Of The Loaded Stainless Steel In Dilute Thiosulphate Solution, Changjian Lin, Zude Feng, Fuling Lin, Fayang Wang, Jianguang Tang, Yuanhui Wang
Journal of Electrochemistry
The electrochemical behavior of l8/8 stainless steel in dilute thiosulphate solutionduring strained loading was studied by various electrochemical techniques and scanning electronmicroscope.It is evidenced that the corrosion activity of stainless steel increased with strained loading.The dynamic process of repassivation ,which may datermine the initiation ,the cease and developmentof the stress corrosion cracking for stainless steel ,was strongly influenced by both electrochemical andloading conditions. Pitting corrosion may locate preferentially on the sites which was suffered mostloading.The propagation of pitting corrosion of stainless steel may induce stress corrosion crakingunder certain conditions.
A Sutface-Enhanced Raman Spectroscopic Study On The Inhibition Mechanism Of Bmat On Stainless Steel In Hydrochloric Acid Solutions, Yinghua Zha, Baoming Wei
A Sutface-Enhanced Raman Spectroscopic Study On The Inhibition Mechanism Of Bmat On Stainless Steel In Hydrochloric Acid Solutions, Yinghua Zha, Baoming Wei
Journal of Electrochemistry
The absorbtion of some nitrogen and sulfur compounds such as BMAT on 18-8stainless steel(SS)in 0.5% HCl were investigated by surface enhanced Raman scattering(SERS)spectroscopy.The SERS spectra of BMAT adsorbed on SS were measured using a SS electredepositedwith discontin uous silvet micro-islands.The results show that the inhibitor,BMAT,is chemisorbed onthe SS surface through the N atom. Under the influence of π-electron interaction ,BMAT can beadsorbed on SS surface at an angle. The allyls in BMAT molecules play the role of steric hindrance inthe inbibition effect.
Studies Of The Black Molybdate Conversion Film On Stainless Steel, Jingli Fang, Liuqin Liuqin, Keping Han, Yaohui Chen
Studies Of The Black Molybdate Conversion Film On Stainless Steel, Jingli Fang, Liuqin Liuqin, Keping Han, Yaohui Chen
Journal of Electrochemistry
A black conversion film was formed on stainless steel with cathodicelectrodeposition method from a molybdate-phosphate solution. This film displayed goodthemcotability. The results of XPS and AES analysis showed that the thickness of the film was 820 nmand that Mo existed as Mo(Ⅵ)in the surface of the film,while existed as Mo(Ⅵ)and Mo(Ⅳ)in theinternal layer of the film. The relative atomic percent content(A,C.% of the film obtained from theelemental composition constant region of the depth profile curves by AES was O 50.9%,Mo 29.4%,P12.6%and Fe 7.1%respectively.The cyclevoltammetric oxluation peak also showed that Mo(Ⅳ)existed in the internal layer of the film.