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Articles 1 - 5 of 5
Full-Text Articles in Physical Sciences and Mathematics
Novel Techniques For Enhancing Sensitivity In Static Headspace, Nicholas Snow, G.P Bullock
Novel Techniques For Enhancing Sensitivity In Static Headspace, Nicholas Snow, G.P Bullock
Nicholas A Snow
No abstract provided.
Experimental Manipulation Of Interfacial Molecular Assemblies, Mark Anderson
Experimental Manipulation Of Interfacial Molecular Assemblies, Mark Anderson
Mark R. Anderson
No abstract currently available.
The Effect Of Ion-Pairing On The Open Circuit Potential Of 3-Mercaptoproprionic Acid Modified Gold Electrodes, Mark Anderson, Alice Harper
The Effect Of Ion-Pairing On The Open Circuit Potential Of 3-Mercaptoproprionic Acid Modified Gold Electrodes, Mark Anderson, Alice Harper
Mark R. Anderson
Open circuit potential (OCP) measurement is used to monitor the charge of a monolayer of 3-mercaptopropionic acid. OCP is determined by the concentrations of the reduced and oxidized forms of a redox couple in the solution adjacent to the modified interface. OCP values were monitored in the presence of the one-electron redox couple Fe(CN)63-/4- as a function of solution pH. The OCP measured at basic pHs was different from the acidic OCP due to differences in electrostatic interactions between the interface and the redox species as described by the Nernst equation. The influence of ion-pairing with the monolayer is studied …
Synthesis And Characterization Of Allylic Dinuclear Molybdenum Complexes With Bridging Oxygen And Sulfur Containing Ligands., Mazin Shatnawi, Samer Tanash, Saleem Al-Ahmad, Paul Challen, Gerald Henkel
Synthesis And Characterization Of Allylic Dinuclear Molybdenum Complexes With Bridging Oxygen And Sulfur Containing Ligands., Mazin Shatnawi, Samer Tanash, Saleem Al-Ahmad, Paul Challen, Gerald Henkel
Paul R. Challen
No abstract provided.
Bismuth Compounds In Organic Synthesis: Synthesis Of Dioxanes, Dioxepines, And Dioxolanes Catalyzed By Bismuth(Iii) Triflate, Ram Mohan, Daniel Podgorski, Scott Krabbe, Long Le, Paul Sierszulski
Bismuth Compounds In Organic Synthesis: Synthesis Of Dioxanes, Dioxepines, And Dioxolanes Catalyzed By Bismuth(Iii) Triflate, Ram Mohan, Daniel Podgorski, Scott Krabbe, Long Le, Paul Sierszulski
Ram S. Mohan
A simple method for the synthesis of l,3-dioxolanes from carbonyl compounds has been developed using l,2-bis(trimethylsilyloxy) ethane in the presence of bismuth (III) triflate as a catalyst. The bismuth(III) triflate catalyzed synthesis of a range of dioxanes and dioxepines has also been developed. In these latter cases, the carbonyl compound is treated with a diol, and triethyl orthoformate is used as a water scavenger. All these methods avoid the use of a Dean-Stark trap.