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Physical Sciences and Mathematics Commons™
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Full-Text Articles in Physical Sciences and Mathematics
Potential Impact Of Northern Resource Development On Aquatic Biota: Toxicity Of Chromium And Rare Earth Element Processing Reagent, So Yeon Choi
Theses and Dissertations (Comprehensive)
Chromite and rare earth element development was identified in the 2015 Canadian Federal budget as a significant opportunity, however, key data gaps exist regarding the environmental concerns related to these resource developments. Chromium is essential in the production of stainless steel, and no suitable substitute is known. Rare earth elements (REEs) are a series of metals that are composed of 15 lanthanides, as well as scandium and yttrium. Uses for REEs range from electronic devices (i.e. cell phones, computers, televisions) to magnets and controlling nuclear reactors. While commercial production of REEs signify a great economic opportunity for Canada, key data …
Influence Of Ligand Complexation On Nickel Toxicity, Speciation And Bioavailability In Marine Waters, Samantha Sherman
Influence Of Ligand Complexation On Nickel Toxicity, Speciation And Bioavailability In Marine Waters, Samantha Sherman
Theses and Dissertations (Comprehensive)
Currently there are no site-specific bioavailability-based prediction models for assessing the impacts of nickel (Ni) in marine environments although there are indications that these may be warranted. The aim of this research was to characterize the complexation of Ni in relation to toxicity and speciation. Various complexing ligands were used, and it was predicted that the binding affinity (logKf) of ligands would be inversely correlated to toxicity based on dissolved Ni concentrations ([NiD]) but that on a free ion concentration ([Ni2+]) basis, toxicity would not vary. A two-phased approach was used; the first was a proof of principle where synthetic …