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Articles 1 - 9 of 9
Full-Text Articles in Physical Sciences and Mathematics
The Effects Of Legacy Sulphur Deposition On Methylmercury Production In Northern Peatlands; Geochemical And Biological Considerations, Jennifer L. Blythe
The Effects Of Legacy Sulphur Deposition On Methylmercury Production In Northern Peatlands; Geochemical And Biological Considerations, Jennifer L. Blythe
Electronic Thesis and Dissertation Repository
Mercury is a ubiquitous element with a complex geochemical cycle. Aquatic ecosystems such as wetland soils convert inorganic mercury to organic, neurotoxic methylmercury though the activity of sulphate-reducing bacteria (SRB). Sulphate stimulates the activity of SRB, and the production of methylmercury in these environments. My aim was to investigate the effect that legacy sulphate has on Hg methylation in northern peatlands through a laboratory sulphate addition experiment with differentially sulphate-exposed peats and a field study of peatlands subjected to different levels of sulphate. Results from the laboratory study indicate that peatlands in regions of higher atmospheric sulphate deposition show enhanced …
Biogeochemical Response To Vegetation And Hydrologic Change In An Alaskan Boreal Fen Ecosystem, Danielle L. Rupp
Biogeochemical Response To Vegetation And Hydrologic Change In An Alaskan Boreal Fen Ecosystem, Danielle L. Rupp
Dissertations, Master's Theses and Master's Reports
Boreal peatlands store approximately one third of the earth’s terrestrial carbon, locked away in currently waterlogged and frozen conditions. Peatlands of boreal and arctic ecosystems are affected increasingly by shifting hydrology caused by climate change. The consequences of these relatively rapid ecosystem changes on carbon cycling between the landscape and the atmosphere could provide an amplifying feedback to climate warming. Alternatively, the advancement of terrestrial vegetation into once waterlogged soils could uptake carbon as a sink. Previous work suggests that fens will become an increasingly dominant landscape feature in the boreal. However, studies investigating fens, their response to hydrologic and …
Linking Mining Wastewater Discharge To Methylmercury Production In A Sub-Arctic Peatland, Lauren E. Twible
Linking Mining Wastewater Discharge To Methylmercury Production In A Sub-Arctic Peatland, Lauren E. Twible
Electronic Thesis and Dissertation Repository
It is well established that the addition of sulphate (SO42-) to peatlands increases methylmercury (MeHg) concentrations in pore waters via microbial methylation. Less information exists about the effects of different concentrations and sources of SO42- loading on MeHg production in remote, non- SO42- impacted regions like Canada’s north, where increased SO42- loadings come not from the atmosphere, but often from mining waste water and rock tailings. A three year field study (two years of loading; one year of recovery) examined the effects of simulated wastewater (containing 27.2 mg/L SO42- …
Methylmercury Production In Two Northern Fen Peatlands, Mikhail J. Mack
Methylmercury Production In Two Northern Fen Peatlands, Mikhail J. Mack
Electronic Thesis and Dissertation Repository
Northern peatlands provide conditions favourable for sulphate reducing bacteria, microorganisms responsible for producing methylmercury, an aquatic pollutant. An expected climate driven shift from moss- to sedge-dominance may alter mercury biogeochemistry. Observations from a moss-dominated poor fen and sedge-dominated intermediate fen were used to compare methylmercury to assess if contrasting plant communities, nutrients status and/or hydrologic regime control production. Chapter 2 compared porewater methylmercury and ancillary chemistry across two Northern Ontario fens. The lower water table, greater dissolved organic carbon, and lower pH in the poor fen resulted in 3.1 times greater methylmercury. Chapter 3, riparian zones in intermediate fen were …
Evaluating The Biogeochemical Functioning Of A Constructed Fen On The Post-Mining Landscape Of Athabasca Oil Sands Region, Fort Mcmurray, Alberta, Canada, Felix C. Nwaishi
Evaluating The Biogeochemical Functioning Of A Constructed Fen On The Post-Mining Landscape Of Athabasca Oil Sands Region, Fort Mcmurray, Alberta, Canada, Felix C. Nwaishi
Theses and Dissertations (Comprehensive)
Peatlands have a unique biogeochemical function, characterized by an imbalance between the rates of biomass accumulation and decomposition. These characteristics facilitate the ability of peatlands to support the sequestration of nutrients and carbon. In disturbed peatlands, these functions are compromised. Thus, reclamation targets amongst other key functions, the recovery of biogeochemical functioning. These functions could serve as a measure of recovery to conditions that are present in natural analogues. This thesis examines the recovery of microbially-mediated nutrient transformation processes in a fen peatland that was constructed on a post-mining landscape in the Athabasca oil sands region, Fort McMurray, Alberta. The …
The Role Of Amino Acids In The Nitrogen Cycle Of Peatlands, Tia Scarpelli
The Role Of Amino Acids In The Nitrogen Cycle Of Peatlands, Tia Scarpelli
Dissertations, Master's Theses and Master's Reports
Future release of carbon from peatlands in response to climate change may be impacted by nitrogen limitation. The current study considers the role of amino acids as a nitrogen source in peatlands. The total free amino acid (TFAA) concentration for peats ranged from 0-2.3 µM, and leucine was the primary contributor. The dominance of sedge or ericaceous shrub plant types did not significantly impact the TFAA pool. Ammonium concentrations were much greater than TFAA and nitrate concentrations. TFAA concentrations were greatest in spring and least in fall. The springtime maxima and summer decrease in concentrations were simulated in a modeling …
The Relative Importance Of Methanogenesis In The Decomposition Of Organic Matter In Northern Peatlands, J. Elizabeth Corbett, Malak M. Tfaily, David J. Burdige, Paul H. Glaser, Jeffrey P. Chanton
The Relative Importance Of Methanogenesis In The Decomposition Of Organic Matter In Northern Peatlands, J. Elizabeth Corbett, Malak M. Tfaily, David J. Burdige, Paul H. Glaser, Jeffrey P. Chanton
OES Faculty Publications
Using an isotope-mass balance approach and assuming the equimolar production of CO2 and CH4 from methanogenesis (e.g., anaerobic decomposition of cellulose), we calculate that the proportion of total CO2 production from methanogenesis varies from 37 to 83% across a variety of northern peatlands. In a relative sense, methanogenesis was a more important pathway for decomposition in bogs (80 ± 13% of CO2 production) than in fens (64 ± 5.7% of CO2 production), but because fens contain more labile substrates they may support higher CH4 production overall. The concentration of CO2 produced from methanogenesis (CO …
Peatland-Stream Hydrological And Biogeochemical Connectivity In The James Bay Lowland, Ontario, Meghan Kline
Peatland-Stream Hydrological And Biogeochemical Connectivity In The James Bay Lowland, Ontario, Meghan Kline
Electronic Thesis and Dissertation Repository
The Hudson-James Bay Lowlands are the second largest peatland dominated area on the planet, and are expected to be particularly vulnerable to future climate change. Changes in climate will affect peatland hydrology and biogeochemistry, impacting the aquatic ecosystems this region supports, however there is limited information about the hydrology and biogeochemistry of this landscape under current conditions. This thesis focuses on assessing the nature of hydrological and biogeochemical connectivity between a fen and 2nd order channel in the Central James Bay Lowland, Ontario. Specifically the study focuses on the role of preferential hydrological flowpaths in the riparian area, such …
Surface Production Fuels Deep Heterotrophic Respiration In Northern Peatlands, J. Elizabeth Corbett, David J. Burdige, Malak M. Tfaily, Angela R. Dial, William T. Cooper, Paul H. Glaser, Jeffrey P. Chanton
Surface Production Fuels Deep Heterotrophic Respiration In Northern Peatlands, J. Elizabeth Corbett, David J. Burdige, Malak M. Tfaily, Angela R. Dial, William T. Cooper, Paul H. Glaser, Jeffrey P. Chanton
OES Faculty Publications
Multiple analyses of dissolved organic carbon (DOC) from pore waters were conducted to define the processes that govern carbon balance in peatlands: (1) source, reactivity, and transport of DOC with respect to vegetation, peat, and age of carbon substrate, (2) reactivity of DOC with respect to molecular size, and (3) lability to photoxidation of surficial DOC. We found that surface organic production fuels heterotrophic respiration at depth in advection-dominated peatlands, especially in fens. Fen DOC was Δ14Cenriched relative to the surrounding fen peat, and fen respiration products were similar to this enriched DOC indicating that DOC was the …