Physical Sciences and Mathematics Commons^™

Topographic Influences On Trends And Cycles In Nutrient Export From Forested Catchments On The Precambrian Shield, Samson G. Mengistu

Electronic Thesis and Dissertation Repository

This dissertation explored topographic controls on spatial and temporal patterns in water yield and nutrient (carbon, nitrogen and phosphorus) export from forested headwater catchments in the Turkey Lakes Watershed in central Ontario, where other factors contributing to differences in water yield and nutrient export, including climate, geology, forest, and soils, are relatively constant. Topographic characteristics, including (a) hydrological flushing potential (expansion of water table into nitrate-N producing areas); (b) hydrological storage potential (area of wetlands, which can alternatively allow water and nutrients to bypass wetlands when storage capacity is filled with water or to trap them when not filled); and …

Characterization Of Novel Ichnofossils In Meteorite Impact Glass From The Ries Impact Structure, Germany, Haley M. Sapers

Electronic Thesis and Dissertation Repository

The initial catastrophic biological effects of hypervelocity impacts are well established. However, a growing body of evidence suggests that meteorite impact events have beneficial effects for microbial life. This, in turn, has led many to suggest that impact craters may have been important habitats for life on early Earth. Any large meteorite impact into a water-rich target on a solid planetary body has the potential to generate hydrothermal systems. Impact-generated hydrothermal systems expand the potential environments for microbial colonization to environments without endogenous volcanic heat sources to drive hydrothermal activity. Examination of impact glass from the Ries impact structure, Germany, …

Bacterial Communities And Their Influence On The Formation And Development Of Potholes In Sandstone Surfaces Of The Semi-Arid Colorado Plateau, Kebbi A. Hughes

Electronic Thesis and Dissertation Repository

Potholes are weathering features, of various sizes and shapes, which are found in exposed rock surfaces that lack vegetative and soil cover. Biofilms associated with the ephemeral aquatic pothole environments of the Colorado Plateau were examined as initial and intermediate stages of colonisation of arid, oligotrophic rock surfaces.

Imaging of the interface between pothole biofilms and their host rock revealed features of biological weathering; chiefly, the breakdown of silicate minerals and precipitation of clay and carbonate minerals. High pH measured in pothole water reflected deposition of secondary carbonate minerals at some locations and indicated the development of high pH microenvironments …

The Weathering Of Platinum From Nuggets And Platinum Immobilisation By Cupriavidus Metallidurans, Sean Gordon Campbell

Electronic Thesis and Dissertation Repository

Two studies were conducted to investigate the biogeochemistry of platinum. In the first project, platinum nuggets were examined to evaluate mineral dissolution-precipitation processes occurring at the nugget-‘soil solution’ interface. The presence of dissolution ‘pits’, cavities, and striations as well as acicular, iron oxides coating the grain surface evidence that this interface is an important site of mechanical and chemical weathering. Element mapping revealed that structural and chemical signatures can be linked to morphological features on the grain surface. In the second study, the soil bacterium Cupriavidus metallidurans was reacted with aqueous platinum chloride and rapidly immobilised platinum. XANES/EXAFS analysis of …

Reconstructing Fire Severity From The Oxygen-Isotope Compositions Of Plant Char, Michael W. Hamilton

Electronic Thesis and Dissertation Repository

This study assessed whether variations in the oxygen-isotope compositions of char formed from biomass burning could be related to burning severity. Ground samples of oak (Quercus alba), pine (Pinus resinosa), and grass (Andropogon gerardii) were charred for 5 and 30 minutes at constant temperatures between 200 and 900°C under oxygenated versus anaerobic conditions. Char oxygen-isotope values became progressively depleted of ¹⁸O by up to 25.8‰ for wood and 16.5‰ for grass as temperature, duration of burning, and amount of oxygen increased. The primary reason for the decrease in oxygen-isotope values is the loss …

A Geobiological Investigation Of The Mazon Creek Concretions Of Northeastern Illinois, Mechanisms Of Formation And Diagenesis, Andrea S. Fernandes

Electronic Thesis and Dissertation Repository

Siderite concretions from the mid-Pennsylvanian Francis Creek Shale of the Mazon Creek area, in northeastern Illinois, contain exceptionally preserved soft-tissue fossils. Scanning electron microscopy, energy dispersive spectroscopy, time of flight-secondary ion mass spectrometry and micro-x-ray diffraction on polychaete worm, jellyfish and holothurian samples highlighted detrital clay and quartz grains in siderite cement. The worm and jellyfish are pyritised and surrounded by pyrite halos, whereas the holothurian is preserved as a weathered impression. Specimens possessed either microbial textures or framboidal pyrite, in carbon-enriched zones. The carbon-enriched zones contained organic compounds, indicating that extensive degradation associated with high temperature diagenesis did not …